Li-ion batteries are provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and at least one hydrofluoric acid neutralizing agent incorporated into the anode or the separator. Li-ion batteries are also provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, and a separator electrically separating the anode and the cathode, where the electrolyte may be formed from a mixture of an imide salt and at least one salt selected from the group consisting of LiPF.sub.6, LiBF.sub.4, and LiClO.sub.4. Li-ion battery anodes are also provided that include an active material core and a protective coating at least partially encasing the active material core, where the protective coating comprises a material that is resistant to hydrofluoric acid permeation.

The present application relates to an anode active material and an anode, an electrochemical device and an electronic device using same. Specifically, the present application provides an anode active material, including a lithiated silicon-oxygen material and a coating layer, where there is at least a Si—O-M bond between the coating layer and the lithiated silicon-oxygen material, where M is selected from one or more of an aluminum element, a boron element and a phosphorus element. The anode active material of the present application has high stability and is suitable for aqueous processing to be prepared into an anode.

A secondary battery includes: a positive electrode having a positive-electrode current collector and a positive-electrode active-material layer; a negative electrode having a negative-electrode current collector and a negative-electrode active-material layer; a electrolyte; and an insulating tape covering a portion of the positive electrode. Furthermore, the positive-electrode current collector has an exposed section that the positive-electrode active-material layer is not disposed. In addition, at least a portion of the exposed section is covered with the insulating tape; the insulating tape has a substrate material layer and an adhesive layer; and the adhesive layer includes an adhesive agent and an insulating inorganic material.

Novel pulsed aluminum batteries (PAlBs), including power output regulated systems, have been developed. PAlBs comprise an aluminum anode, a cathode, and a complex electrolyte containing bases, facilitating and stabilizing agents, and may contain internal oxidizers. The aluminum anode comprises technical grade or recycled aluminum. The cathode may comprise copper, nickel, or platinum. Bases may comprise sodium or potassium hydroxide. Facilitating and stabilizing agents may comprise sodium and lithium chlorides or sulfates. Internal oxidizers may comprise sodium hypochlorite. Frequency of electric pulses in novel PAlBs can be controlled by electric or chemical means. PAlBs can be used as components of backup power systems, in unmanned aerial vehicles (UAVs), and in autonomous self-powered electrochemical computing systems and sensors.

According to one embodiment, there is provided an active material represented by a general formula Li.sub.x(Ni.sub.aCo.sub.bMn.sub.cM.sub.d).sub.1−s(Nb.sub.1−tTa.sub.t).sub.sO.sub.2. Here, M is at least one selected from the group consisting of Li, Ca, Mg, Al, Ti, V, Cr, Zr, Mo, Hf, and W, and 1.0≤x≤1.3, 0≤a≤0.9, 0≤b≤1.0, 0≤c≤0.8, 0≤d≤0.5, a+b+c+d=1, 0.005≤s≤0.3, and 0.0005≤t≤0.1 are satisfied.

According to one embodiment, there is provided an active material represented by a general formula Li.sub.x(Ni.sub.aCo.sub.bMn.sub.cM.sub.d).sub.1−s(Nb.sub.1−tTa.sub.t).sub.sO.sub.2. Here, M is at least one selected from the group consisting of Li, Ca, Mg, Al, Ti, V, Cr, Zr, Mo, Hf, and W, and 1.0≤x≤1.3, 0≤a≤0.9, 0≤b≤1.0, 0≤c≤0.8, 0≤d≤0.5, a+b+c+d=1, 0.005≤s≤0.3, and 0.0005≤t≤0.1 are satisfied.

A method for producing a negative electrode for magnesium secondary batteries includes: providing a current collector having an underlying layer including a metal having a higher ionization tendency than magnesium, where the underlying layer is formed on a surface of the current collector; and forming a negative electrode active material layer including a magnesium layer on the current collector by a chemical plating method using the underlying layer as a base material.

A method for producing a negative electrode for magnesium secondary batteries includes: providing a current collector having an underlying layer including a metal having a higher ionization tendency than magnesium, where the underlying layer is formed on a surface of the current collector; and forming a negative electrode active material layer including a magnesium layer on the current collector by a chemical plating method using the underlying layer as a base material.

Li-ion batteries are provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and at least one hydrofluoric acid neutralizing agent incorporated into the anode or the separator. Li-ion batteries are also provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, and a separator electrically separating the anode and the cathode, where the electrolyte may be formed from a mixture of an imide salt and at least one salt selected from the group consisting of LiPF.sub.6, LiBF.sub.4, and LiClO.sub.4. Li-ion battery anodes are also provided that include an active material core and a protective coating at least partially encasing the active material core, where the protective coating comprises a material that is resistant to hydrofluoric acid permeation.

A metal-ion secondary battery is provided. The metal-ion secondary battery includes a positive electrode. The positive electrode includes at least one current-collecting layer and at least one active layer, wherein the current-collecting layer and the active layer are mutually stacked, and the current-collecting layer has at least one first through-hole.