A method for creating a metal-carbon composite. In one embodiment, the method includes the steps of providing a polymer Schiff base transition metal .[.film.]. .Iadd.complex .Iaddend.precursor .Iadd.film .Iaddend.having a chemical structure of the formula [M(Schiff)].sub.n and a recurring unit and a transition metal selected from the group consisting of nickel, palladium, platinum, cobalt, copper, iron; Schiff is a tetradentate Schiff base ligand selected from the group consisting of Salen (residue of bis(salicylaldehyde)-ethylenediamine), Saltmen (residue of bis(salicylaldehyde)-tetramethylethylenediamine, Salphen (residue of bis-(salicylaldehyde)-o-phenylenediamine), a substituent in a Schiff base is selected from the group consisting of H—, and carbon-containing substituents, preferably CH.sub.3—, C.sub.2H.sub.5—, CH.sub.3O—, C.sub.2H.sub.5O—, and Y is a bridge in a Schiff base depositing the polymer Schiff base transition metal precursor film onto a support substrate; and heating the polymer Schiff base transition metal .Iadd.complex .Iaddend.precursor film and support substrate in a furnace in an inert atmosphere.

A method and system for creating low corrosion passivation layer on an anode in a metal-air cell comprise asserting high negative potential and low drawn current density on the cell after its operational parameters have stabilized after the cell has been powered-on. As a result the H.sub.2 evolution rate momentarily raises and then drops sharply, thereby causing the creation of a passivation layer on the face of the anode.

A method and system for creating low corrosion passivation layer on an anode in a metal-air cell comprise asserting high negative potential and low drawn current density on the cell after its operational parameters have stabilized after the cell has been powered-on. As a result the H.sub.2 evolution rate momentarily raises and then drops sharply, thereby causing the creation of a passivation layer on the face of the anode.

A reference electrode for a lithium-ion battery cell in the form of a porous ultrathin film that is fabricated from aluminum or an aluminum alloy is described. The aluminum layer is conductive and functions as a current collector for the reference electrode. The alloying elements may include but not limited to one or more of copper, zinc, silver, gold, titanium, chrome, rare earth metals, etc., to achieve target values for electrical, mechanical and chemical properties. Also disclosed is an electrochemical battery cell having an anode, a cathode, and a reference electrode, wherein the reference electrode is interposed between the anode and the cathode, wherein the reference electrode is an electrode layer that is arranged on a current collector, and wherein the current collector is fabricated from an aluminum alloy.

A battery, having polyvalent aluminum metal as the electrochemically active anode material and also including a solid ionically conducting polymer material.

Embodiments of the present invention provide a cathode active material for a lithium secondary battery. The cathode active material for a lithium secondary battery includes lithium-transition metal composite oxide particles, and a coating formed on each of the lithium-transition metal composite oxide particles. The coating includes a lithium-sulfur compound and a metal hydroxide. A residual lithium on a surface of the cathode active material is sufficiently removed to improve an ionic conductivity and low-resistance.

A conductive composite structure having a metal substrate and a conductive film on a surface of the metal substrate, the conductive film including a layered material of one or plural layers; the one or plural layers being a layer body represented by M.sub.mX.sub.n, where M is at least one metal of Group 3, 4, 5, 6 or 7; X is a carbon atom, a nitrogen atom, or a combination thereof; n is not less than 1 and not more than 4; and m is more than n but not more than 5, and a modifier or terminal T exists on a surface of the layer body; and a residue derived from an organic compound having a hydroxyl group, a carbonyl group, or a combination thereof and having 2 to 8 carbon atoms, is bonded to each of the surface of the metal substrate and a surface of the layer body.

A secondary battery and a method for making the same are disclosed. The secondary battery includes a battery negative electrode, an electrolyte liquid, a diaphragm and a battery positive electrode. The battery negative electrode includes a negative electrode current collector, which also acts as a negative electrode active material. The electrolyte liquid includes an electrolyte and a solvent, the electrolyte being a lithium salt. The battery positive electrode includes a positive electrode current collector and a positive electrode active material layer, which includes a positive electrode active material capable of reversibly de-intercalating lithium ions.

Disclosed herein is a lithium ion battery which operates stably at high temperatures. The battery disclosed herein has a chemical composition amenable to long-term operation at elevated temperatures and employs a lithium-based cathode, a silicon-based anode, and a piperidinium-based electrolyte solution.

According to one embodiment, an electrode group is provided. The electrode group includes a positive electrode that includes a lithium composite oxide LiM.sub.xMn.sub.2-xO.sub.4 (0<x≤0.5, M is at least one selected from a group consisting of Ni, Cr, Fe, Cu, Co, Mg, and Mo) as a positive electrode active material, a negative electrode that includes a negative electrode active material, a composite electrolyte layer that includes at least one of a solid electrolyte and an inorganic compound containing alumina, and a separator. The composite electrolyte layer and the separator are arranged between the positive electrode and the negative electrode. A density of the composite electrolyte layer is in the range of 1.0 g/cc and 2.2 g/cc.