There is provided an electrode layer for an all-solid state battery, which contains an electrode active material and a sulfide solid electrolyte, where the sulfide solid electrolyte has an average particle diameter of less than 1 .Math.m and the electrode layer contains an imidazoline-based dispersion material.

The present invention relates to a positive electrode active material, wherein the positive electrode active material is a lithium transition metal oxide including a first doping element (A) and a second doping element (B), wherein the first doping element is one or more selected from the group consisting of Zr, La, Ce, Nb, Gd, Y, Sc, Ge, Ba, Sn, Sr, Cr, Mg, Sb, Bi, Zn, and Yb, the second doping element is one or more selected from the group consisting of Al, Ta, Mn, Se, Be, As, Mo, V, W, Si, and Co, and a weight ratio (A/B ratio) of the first doping element to the second doping element is 0.5 to 5.

In one embodiment, the present disclosure relates to a method of preparing a positive electrode active material, which includes mixing a nickel cobalt manganese hydroxide precursor containing nickel in an amount of 60 mol % or more based on a total number of moles of transition metals in the precursor, a lithium-containing raw material, and a doping raw material represented by Formula 2 (set forth herein), and sintering the mixture to prepare a positive electrode active material represented by Formula 1 (set forth herein).

Provided is a current collector electrode sheet (10) including a slurry application area (11) formed by intermittently applying and drying a slurry containing an active material and a non-application area (12), on both surfaces of a metal foil (9), in which the application area (11) and the non-application area (12) are alternately formed in a winding direction of the metal foil (9) having a strip shape, and, in a compression step of continuously compressing the slurry application area (11) and the non-application area (12) using a pair of compression rollers in a thickness direction of the current collector electrode sheet (10), an area which is not compressed by the compression rollers, is present in a tailing portion (14) at a terminal end (13) of each application area (11).

Provided is a current collector electrode sheet (10) including a slurry application area (11) formed by intermittently applying and drying a slurry containing an active material and a non-application area (12), on both surfaces of a metal foil (9), in which the application area (11) and the non-application area (12) are alternately formed in a winding direction of the metal foil (9) having a strip shape, and, in a compression step of continuously compressing the slurry application area (11) and the non-application area (12) using a pair of compression rollers in a thickness direction of the current collector electrode sheet (10), an area which is not compressed by the compression rollers, is present in a tailing portion (14) at a terminal end (13) of each application area (11).

Single, internally adjustable modular battery systems are provided, for handling power delivery from and to various power systems such as electric vehicles, photovoltaic systems, solar systems, grid-scale battery energy storage systems, home energy storage systems and power walls. Batteries comprise a main fast-charging lithium ion battery (FC), configured to deliver power to the electric vehicle, a supercapacitor-emulating fast-charging lithium ion battery (SCeFC), configured to receive power and deliver power to the FC and/or to the EV and to operate at high rates within a limited operation range of state of charge (SoC), respective module management systems, and a control unit. Both the FC and the SCeFC have anodes based on the same anode active material and the control unit is configured to manage the FC and the SCeFC and manage power delivery to and from the power system(s), to optimize the operation of the FC.

In the present disclosure, a positive electrode layer used in an all-solid-state battery includes a positive electrode active material, a sulfide solid electrolyte, and a coated sulfide solid electrolyte having a coating layer covering a surface of the sulfide solid electrolyte and containing a metal sulfate, and in an S2p spectrum obtained by X-ray photoelectron spectroscopy (XPS) on the coated sulfide solid electrolyte, a ratio (P2/P1) of an intensity P2 of a peak appearing near 163 eV to an intensity P1 of a peak appearing near 167 eV is 0.15 or more and less than 0.36, thereby solving the above problem.

In the present disclosure, a positive electrode layer used in an all-solid-state battery includes a positive electrode active material, a sulfide solid electrolyte, and a coated sulfide solid electrolyte having a coating layer covering a surface of the sulfide solid electrolyte and containing a metal sulfate, and in an S2p spectrum obtained by X-ray photoelectron spectroscopy (XPS) on the coated sulfide solid electrolyte, a ratio (P2/P1) of an intensity P2 of a peak appearing near 163 eV to an intensity P1 of a peak appearing near 167 eV is 0.15 or more and less than 0.36, thereby solving the above problem.

The present disclosure provides a non-aqueous electrolyte including an additive for a non-aqueous electrolyte represented by the following Chemical Formula 1:

##STR00001## wherein, A ring may be a cyclic phosphate group having 2 or 3 carbon atoms, R may be an alkylene group or alkenylene group having 1 to 5 carbon atoms, and X may be a perfluoroalkyl group having 1 to 5 carbon atoms.

The present disclosure provides a non-aqueous electrolyte including an additive for a non-aqueous electrolyte represented by the following Chemical Formula 1:

##STR00001## wherein, A ring may be a cyclic phosphate group having 2 or 3 carbon atoms, R may be an alkylene group or alkenylene group having 1 to 5 carbon atoms, and X may be a perfluoroalkyl group having 1 to 5 carbon atoms.