A high voltage metal-free battery comprising a cathode comprising a cathode electroactive material, wherein the cathode electroactive material comprises at least one of an organic compound, an oxide, a hydroxide, an oxyhydroxide, a sulfide, and combinations thereof; an anode comprising an anode electroactive material, wherein the anode electroactive material comprises at least one of an organic compound, an oxide, a hydroxide, an oxyhydroxide, a sulfide, and combinations thereof; a catholyte in contact with the cathode, wherein the catholyte is not in contact with the anode; and an anolyte in contact with the anode, wherein the anolyte is not in contact with the cathode. The catholyte has a pH of less than 4, and the anolyte has a pH of greater than 10. The battery comprises a separator, wherein the separator has ion-selective properties.

A high voltage metal-free battery comprising a cathode comprising a cathode electroactive material, wherein the cathode electroactive material comprises at least one of an organic compound, an oxide, a hydroxide, an oxyhydroxide, a sulfide, and combinations thereof; an anode comprising an anode electroactive material, wherein the anode electroactive material comprises at least one of an organic compound, an oxide, a hydroxide, an oxyhydroxide, a sulfide, and combinations thereof; a catholyte in contact with the cathode, wherein the catholyte is not in contact with the anode; and an anolyte in contact with the anode, wherein the anolyte is not in contact with the cathode. The catholyte has a pH of less than 4, and the anolyte has a pH of greater than 10. The battery comprises a separator, wherein the separator has ion-selective properties.

A method of forming an LMNO cathode with electrolytic manganese dioxide includes dissolving metallic manganese in acid to create a dissolved manganese solution, disposing the solution within an electrolytic cell including an electrolytic cell anode and an electrolytic cell cathode, and applying a current between the cell anode and the cell cathode to the solution. Applying the current forms an MnO.sub.2 deposit upon the cell anode. The method further includes harvesting the deposit, creating a manganese precursor by neutralizing the deposit and grinding the deposit to form an MnO.sub.2 powder, and mixing the manganese precursor with a nickel precursor and a lithium precursor to create a mixture. The method further includes calcining the mixture to create an LMNO powder and coating a current collector with the LMNO powder to thereby form the LMNO cathode. The method may include testing the cathode electrode in an electrochemical pouch format cell.

A biodegradable solid aqueous electrolyte composition, an electrochemical device incorporating the electrolyte composition, and methods for the same are provided. The electrolyte composition may include a hydrogel of a copolymer and a salt dispersed in the hydrogel. The copolymer may include at least two polycaprolactone chains attached to a polymeric center block. The electrochemical device may include an anode, a cathode, and the electrolyte composition disposed between the anode and the cathode. The electrolyte composition may include a crosslinked, biodegradable polymeric material that is radiatively curable prior to being crosslinked.

A rechargeable manganese battery includes: (1) a first electrode including a porous, conductive support; (2) a second electrode including a catalyst support and a catalyst disposed over the catalyst support; and (3) an electrolyte disposed between the first electrode and the second electrode to support reversible precipitation and dissolution of manganese at the first electrode and reversible evolution and oxidation of hydrogen at the second electrode.

A rechargeable manganese battery includes: (1) a first electrode including a porous, conductive support; (2) a second electrode including a catalyst support and a catalyst disposed over the catalyst support; and (3) an electrolyte disposed between the first electrode and the second electrode to support reversible precipitation and dissolution of manganese at the first electrode and reversible evolution and oxidation of hydrogen at the second electrode.

An electrolyte composition comprising: a) a solvent comprising: a mixture of at least two saturated cyclic carbonates, at least one of these saturated cyclic carbonates being fluorinated, at least one ether, said at least one saturated cyclic carbonate representing at most 1.5% by weight of the solvent, said at least one ether representing at least 40% by weight of the solvent; b) at least one lithium salt other than lithium difluorophosphate; c) lithium difluorophosphate in an amount representing from 0.1 to 1% by weight relative to the sum of weight of the solvent and weight of said at least one lithium salt.

The use of this composition in an electrochemical cell comprising a lithium anode allows increased performance of the cell when it is discharged under a strong current at low temperature, and limited self-discharging when in operation at ambient temperature.

Provided are a zinc ion battery positive electrode material, a preparation method therefor, and an application thereof. The preparation method for the zinc ion battery positive electrode material includes: performing a sintering treatment on manganese carbonate to obtain the zinc ion battery positive electrode material. In this method, through a heat treatment of manganese carbonate, a zinc ion battery positive electrode material with high performance can be obtained. In addition, the method requires low raw material and simple preparation processes, and thus it is suitable for industrial production.

Provided are a zinc ion battery positive electrode material, a preparation method therefor, and an application thereof. The preparation method for the zinc ion battery positive electrode material includes: performing a sintering treatment on manganese carbonate to obtain the zinc ion battery positive electrode material. In this method, through a heat treatment of manganese carbonate, a zinc ion battery positive electrode material with high performance can be obtained. In addition, the method requires low raw material and simple preparation processes, and thus it is suitable for industrial production.

Provided is a nonaqueous electrolyte secondary battery, in which the capacity retention rate after high temperature storage is high, the gas amount after high temperature storage is suppressed, the resistance after high temperature storage is low, the amount of metal dissolution from a positive electrode is small, and the amount of heat generation at a high temperature is small. A nonaqueous electrolyte secondary battery including a positive electrode with a positive electrode active material capable of absorbing and releasing a metal ion; a negative electrode with a negative electrode active material capable of absorbing and releasing a metal ion; and a nonaqueous electrolyte solution; wherein the positive electrode active material includes a lithium transition metal compound, and the positive electrode active material includes at least Ni, Mn and Co, wherein the molar ratio of Mn/(Ni+Mn+Co) is larger than 0 and not larger than 0.32, the molar ratio of Ni/(Ni+Mn+Co) is 0.45 or more, the plate density of the positive electrode is 3.0 g/cm.sup.3 or more; and the nonaqueous electrolyte solution includes a monofluorophosphate and/or a difluorophosphate.