A green secondary electrode includes a conductive substrate, active material and material additives in direct contact with the conductive substrate, and a combination of vinyl acetate-ethylene and methylcellulose-based additive binding the conductive substrate, active materials, and material additives together. The green secondary electrode may be a positive electrode or a negative electrode.

The inventive concept discloses a method for preparing a cathode active material containing a lithium manganese oxide exhibiting a reversible phase transition, and exhibiting electrochemical characteristics of the lithium manganese oxide through the reversible phase transition including (A) synthesizing a sodium manganese oxide using a manganese precursor, and (B) reacting the sodium manganese oxide with a lithium precursor to synthesize the lithium manganese oxide, or including (C) directly synthesizing the lithium manganese oxide.

The present disclosure describes a metal-ion rechargeable battery that includes a metal (such as zinc, aluminum, potassium, sodium, lithium, or lithium-alloys) anode coated with at least one layer of a two-dimensional (2D) transition metal dichalcogenide (TMD) material. The at least one layer of the 2D TMD material, such as molybdenum disulfide (MoS.sub.2), may be deposited on the metal electrode using electrochemical deposition. The battery may also include a carbon material cathode coated with at least one layer of manganese dioxide (MnO.sub.2) or another electrode material. A method of forming such a battery is also described. Batteries that include metal anodes with 2D TMD material coating may have reduced series resistance, exhibit excellent reversible specific capacity, and have stable performance over many cycles with little to no dendrite formation on the metal anodes.

The present disclosure describes a metal-ion rechargeable battery that includes a metal (such as zinc, aluminum, potassium, sodium, lithium, or lithium-alloys) anode coated with at least one layer of a two-dimensional (2D) transition metal dichalcogenide (TMD) material. The at least one layer of the 2D TMD material, such as molybdenum disulfide (MoS.sub.2), may be deposited on the metal electrode using electrochemical deposition. The battery may also include a carbon material cathode coated with at least one layer of manganese dioxide (MnO.sub.2) or another electrode material. A method of forming such a battery is also described. Batteries that include metal anodes with 2D TMD material coating may have reduced series resistance, exhibit excellent reversible specific capacity, and have stable performance over many cycles with little to no dendrite formation on the metal anodes.

Zinc ion battery systems and methods for battery regeneration are disclosed. The Zinc ion battery system includes a battery including a plurality of cells, each cell including a cathode comprising cathode electrode materials disposed on a current collector, an anode comprising anode electrode materials disposed on a current collector, a separator or spacer disposed between the cathode and the anode, an electrolyte to fill the battery in the spaces between electrodes and an electrolyte circulation system.

An electrochemical voltage source has an anode containing lithium, a cathode containing manganese oxide, and a housing. The cathode and the anode are arranged in an interior of the housing and are arranged opposite one another. An electrolyte reservoir in the form of a compressible storage body, which receives an electrolyte, is arranged between the anode and the cathode. The storage body has a first side resting against an end face of the cathode and a second side, which faces away from the first side, and rests against an end face of the anode. The cathode experiences an increase in volume when the voltage source is discharged. The anode experiences a decrease in volume during the discharge. During the discharge, the absolute value of the volume increase of the cathode is at least as great as the absolute value of the volume decrease of the anode.

An electrochemical voltage source has an anode containing lithium, a cathode containing manganese oxide, and a housing. The cathode and the anode are arranged in an interior of the housing and are arranged opposite one another. An electrolyte reservoir in the form of a compressible storage body, which receives an electrolyte, is arranged between the anode and the cathode. The storage body has a first side resting against an end face of the cathode and a second side, which faces away from the first side, and rests against an end face of the anode. The cathode experiences an increase in volume when the voltage source is discharged. The anode experiences a decrease in volume during the discharge. During the discharge, the absolute value of the volume increase of the cathode is at least as great as the absolute value of the volume decrease of the anode.

A method of forming a layered manganese dioxide for use in a cathode of a battery comprises disposing a cathode into a housing of an electrochemical cell, disposing an anode into the housing, disposing a polymeric separator between the anode and the cathode such that the anode and the cathode are electrically separated, adding an alkaline electrolyte to the housing, cycling the electrochemical cell into the 2.sup.nd electron capacity of the manganese dioxide, and forming a layered manganese dioxide having a layered manganese dioxide structure with the one or more additives incorporated into the layered manganese dioxide structure. The cathode comprising a cathode material comprising: a manganese dioxide compound, one or more additives selected from the group consisting of bismuth, copper, tin, lead, silver, cobalt, nickel, magnesium, aluminum, potassium, lithium, calcium, gold, antimony, iron, zinc, and combinations thereof, and a conductive carbon.

A method of forming a layered manganese dioxide for use in a cathode of a battery comprises disposing a cathode into a housing of an electrochemical cell, disposing an anode into the housing, disposing a polymeric separator between the anode and the cathode such that the anode and the cathode are electrically separated, adding an alkaline electrolyte to the housing, cycling the electrochemical cell into the 2.sup.nd electron capacity of the manganese dioxide, and forming a layered manganese dioxide having a layered manganese dioxide structure with the one or more additives incorporated into the layered manganese dioxide structure. The cathode comprising a cathode material comprising: a manganese dioxide compound, one or more additives selected from the group consisting of bismuth, copper, tin, lead, silver, cobalt, nickel, magnesium, aluminum, potassium, lithium, calcium, gold, antimony, iron, zinc, and combinations thereof, and a conductive carbon.

Example embodiments of the described technology provide a stretchable electrochemical cell. The electrochemical cell may comprise an anode, a cathode, first and second current collectors electrically coupled to the anode and cathode respectively and a porous separator configured to carry an electrolyte solution. Components of the electrochemical cell may comprise a non-polar polymer or a polymer composition. Two adjacent components may comprise the same non-polar polymer or polymer composition. The electrochemical cell may also comprise an encapsulation at least partially enclosing components of the electrochemical cell.