A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

A method of fabricating a flexible battery comprises forming a first substrate on a first release liner, forming at least one current collector layer on each of the first and second substrate, forming an anode side of the battery by forming an anode on the current collector of the first substrate, forming a cathode side of the battery by forming a cathode on the current collector of the second substrate, depositing electrolyte on one or both of the anode and cathode, adhering and sealing the anode side and cathode side together such that the anode and cathode face one another with the electrolyte In between, and removing the flexible battery from the release liners. The battery may be a primary battery or a secondary battery. The method may be implemented using a roll-to-roll process.

A method of fabricating a flexible battery comprises forming a first substrate on a first release liner, forming at least one current collector layer on each of the first and second substrate, forming an anode side of the battery by forming an anode on the current collector of the first substrate, forming a cathode side of the battery by forming a cathode on the current collector of the second substrate, depositing electrolyte on one or both of the anode and cathode, adhering and sealing the anode side and cathode side together such that the anode and cathode face one another with the electrolyte In between, and removing the flexible battery from the release liners. The battery may be a primary battery or a secondary battery. The method may be implemented using a roll-to-roll process.

Alkaline electrochemical cells are provided, wherein a conductive carbon is included in the cell's cathode in order to decrease resistivity of the cathode, so as to improve the discharge of the cell, particularly in high drain applications. The conductive carbon may comprise carbon nanotubes and/or graphene. Methods for preparing such cells are also provided.

The present invention generally relates to a method for preparing metal oxide nanosheets. In a preferred embodiment, graphene oxide (GO) or graphite oxide is employed as a template or structure directing agent for the formation of the metal oxide nanosheets, wherein the template is mixed with metal oxide precursor to form a metal oxide precursor-bonded template. Subsequently, the metal oxide precursor-bonded template is calcined to form the metal oxide nanosheets. The present invention also relates to a lithium-ion battery anode comprising the metal oxide nanosheets. In a further preferred embodiment, the battery anode may comprise a reduced template, which is reduced graphene oxide (rGO) or reduced graphite oxide.

A printed battery that supplies a transmission and/or reception unit of an RFID tag with an electrical current of at peak ≥ 400 mA includes a layer stack having an anode configured as a layer that contains particulate metallic zinc or a particulate metallic zinc alloy as an active electrode material and a first resilient binder or binder mixture, and a cathode configured as a layer that contains a particulate metal oxide as an active electrode material, at least one conductivity additive to control the electrical conductivity of the cathode, and a second resilient binder or binder mixture, and a separator configured as a layer that electrically insulates the anode and the cathode from one another, a first electrical conductor in direct contact with the anode, and a second electrical conductor in direct contact with the cathode, and a housing that encloses the layer stack.

A printed battery that supplies a transmission and/or reception unit of an RFID tag with an electrical current of at peak ≥ 400 mA includes a layer stack having an anode configured as a layer that contains particulate metallic zinc or a particulate metallic zinc alloy as an active electrode material and a first resilient binder or binder mixture, and a cathode configured as a layer that contains a particulate metal oxide as an active electrode material, at least one conductivity additive to control the electrical conductivity of the cathode, and a second resilient binder or binder mixture, and a separator configured as a layer that electrically insulates the anode and the cathode from one another, a first electrical conductor in direct contact with the anode, and a second electrical conductor in direct contact with the cathode, and a housing that encloses the layer stack.

A preparation method for a high nickel ternary precursor capable of preferential growth of crystal planes by adjusting and controlling the addition amount of seed crystals. The method comprises the following steps: 1) feeding a ternary metal solution into a reaction kettle containing a first base liquid for reaction, and when the particle size reaches 1.5 to 3.0 μm, stopping the feeding, so as to obtain a seed crystal slurry; 2) simultaneously adding the ternary metal solution, a liquid alkali solution, and an ammonia solution in cocurrent flow into a growth kettle containing a second base solution for reaction, when the particle size reaches 6 to 8 μm, adding the seed crystal slurry into the reaction system, and controlling the particle size to be 9.0 to 11.0 μm by adjusting the feed rate of the seed crystal, so as to obtain the target object. In the preparation method, by adding seed crystals continuously, the crystal plane parameters of 001 peak in the prepared ternary precursor material is lower than the crystal plane parameters of 101 peak, facilitating the embedding of Li ions, and effectively improving the performance of a battery prepared by using the material.

A positive electrode active material for a lithium secondary battery comprising a compound represented by Chemical Formula 1 is introduced.

Li.sub.1+mNi.sub.1-w-x-y-zCo.sub.wMn.sub.xM1.sub.yM2.sub.zO.sub.2-pX.sub.p  [Chemical Formula 1] (In the Chemical Formula 1, M1 and M2 are different from each other, and any one element selected from the group consisting of Al, Mg, Zr, Sn, Ca, Ge, Ti, Cr, Fe, Zn, Y, Ba, La, Ce, Sm, Gd, Yb, Sr, Cu and Ga respectively, X is any one element selected from the group consisting of F, N, S, and P, w, x, y, z, p and m are respectively 0.125<w<0.202, 0.153<x<0.225, 0≤y≤0.1, 0≤z≤0.1, 0.34≤w+x≤0.36, 0≤p≤0.1, and −0.1≤m≤0.2.)

A method of operating a battery comprises discharging a cathode comprising manganese dioxide to within a 2.sup.nd electron capacity of the manganese dioxide at a C-rate of equal to or slower than C/10, recharging the battery, and cycling the battery during use a plurality of times. The cathode is in a battery, and the battery comprises the cathode, an anode, a separator disposed between the anode and the cathode, and an electrolyte. The cathode comprises the manganese dioxide and a conductive carbon. The anode comprises: a metal component and a conductive carbon. The metal component can be a metal, metal oxide, or metal hydroxide, and the metal of the metal component can be zinc, lithium, aluminum, magnesium, iron, cadmium and a combination thereof.