Cathode active materials for alkaline cells are disclosed. In particular, the cathode structures encompass conductive carbons introduced to the cathode so as to have a specific spatial orientation and/or a multi-carbon structure. The overall intent is to leverage the conductor(s) provided to the cathode structure to improve electronic and ionic conductance and, by extension, improve battery discharge performance.

Provided are electrochemical cells and methods of manufacturing these cells. An electrochemical cell comprises a positive electrode and an electrolyte layer, printed over the positive electrode. In some examples, each of the positive electrode, electrolyte layer, and negative electrode comprises an ionic liquid enabling ionic transfer. The negative electrode comprises a negative active material layer (e.g., comprising zinc), printed over and directly interfacing the electrolyte layer. The negative electrode also comprises a negative current collector (e.g., copper foil) and a conductive pressure sensitive adhesive layer. The conductive pressure sensitive adhesive layer is disposed between and adhered to, directly interfaces, and provides electronic conductivity between the negative active material layer and the negative current collector. In some examples, the conductive pressure sensitive adhesive layer comprises carbon and/or metal particles (e.g., nickel, copper, indium, and/or silver). Furthermore, the conductive pressure sensitive adhesive layer may comprise an acrylic polymer, encapsulating these particles.

A positive active material for a positive electrode of a battery cell which includes a first component containing Li.sub.2MnO.sub.3, at least a portion of the manganese ions having been replaced by platinum ions and/or chromium ions. A positive electrode of a battery cell which includes a positive material, and a battery cell which includes at least one positive electrode are also described.

Preparation, characterization, and an electrochemical study of Mg.sub.0.1V.sub.2O.sub.5 prepared by a novel sol-gel method with no high-temperature post-processing are disclosed. Cyclic voltammetry showed the material to be quasi-reversible, with improved kinetics in an acetonitrile-, relative to a carbonate-, based electrolyte. Galvanostatic test data under a C/10 discharge showed a delivered capacity >250 mAh/g over several cycles. Based on these results, a magnesium anode battery, as disclosed, would yield an average operating voltage 3.2 Volts with an energy density 800 mWh/g for the cathode material, making the newly synthesized material a viable cathode material for secondary magnesium batteries.

Preparation, characterization, and an electrochemical study of Mg.sub.0.1V.sub.2O.sub.5 prepared by a novel sol-gel method with no high-temperature post-processing are disclosed. Cyclic voltammetry showed the material to be quasi-reversible, with improved kinetics in an acetonitrile-, relative to a carbonate-, based electrolyte. Galvanostatic test data under a C/10 discharge showed a delivered capacity >250 mAh/g over several cycles. Based on these results, a magnesium anode battery, as disclosed, would yield an average operating voltage 3.2 Volts with an energy density 800 mWh/g for the cathode material, making the newly synthesized material a viable cathode material for secondary magnesium batteries.

The present application provides an electrode, an electrochemical device, and an electronic device. The electrode includes: a current collector; a first active material layer including a first active material; and a second active material layer including a second active material; wherein the first active material layer is arranged between the current collector and the second active material layer. The first active material layer is formed on a surface of the current collector, and a particle size of 90% accumulative volume of the first active material is less than 40 m. The active material layer is used in the present application to ensure that the electrochemical device and the electronic device do not generate a short circuit when pressed by an external force, thereby ensuring the mechanical safety performance of the electrochemical device and the electronic device.

The present application provides an electrode, an electrochemical device, and an electronic device. The electrode includes: a current collector; a first active material layer including a first active material; and a second active material layer including a second active material; wherein the first active material layer is arranged between the current collector and the second active material layer. The first active material layer is formed on a surface of the current collector, and a particle size of 90% accumulative volume of the first active material is less than 40 m. The active material layer is used in the present application to ensure that the electrochemical device and the electronic device do not generate a short circuit when pressed by an external force, thereby ensuring the mechanical safety performance of the electrochemical device and the electronic device.

It is an object of the disclosure to provide a novel air secondary battery, air secondary battery system, and vehicle with the mounted air secondary battery system. The air secondary battery of the disclosure comprises, as the negative electrode active material, an oxide that is capable of topotactic insertion and dissociation of oxygen atoms. The air secondary battery system of the disclosure has an air secondary battery and a heat source that supplies heat to the air secondary battery. The vehicle of the disclosure has the air secondary battery system described above mounted in it and uses the electric power provided by the air secondary battery as at least part of its drive power.

It is an object of the disclosure to provide a novel air secondary battery, air secondary battery system, and vehicle with the mounted air secondary battery system. The air secondary battery of the disclosure comprises, as the negative electrode active material, an oxide that is capable of topotactic insertion and dissociation of oxygen atoms. The air secondary battery system of the disclosure has an air secondary battery and a heat source that supplies heat to the air secondary battery. The vehicle of the disclosure has the air secondary battery system described above mounted in it and uses the electric power provided by the air secondary battery as at least part of its drive power.

Provided is a simple, fast, scalable, and environmentally benign method of producing graphene-embraced particles of a battery electrode active material, comprising: a) mixing graphitic material particles and multiple particles of a milling media to form a mixture in an impacting chamber of an energy impacting apparatus; b) operating the energy impacting apparatus with a frequency and an intensity for a length of time sufficient for transferring graphene sheets from the graphitic material to surfaces of milling media particles to produce graphene-embraced milling media particles; c) mixing particles of an active material with graphene-embraced milling media particles in an impacting chamber of an energy impacting apparatus; d) operating the energy impacting apparatus for transferring graphene sheets from the graphene-embraced milling media particles to surfaces of active material particles to produce graphene-embraced electrode active material particles; and e) recovering these graphene-embraced active material particles from the impacting chamber.