A positive active material for an all-solid secondary battery, an all-solid secondary battery including the same, and a method of manufacturing the positive active material for an all-solid secondary battery, the positive active material including a secondary particle including a plurality of primary particles; and a buffer layer on a surface of the secondary particle; wherein the secondary particle includes a nickel lithium transition metal oxide represented by Formula 1, the buffer layer includes a copper compound represented by Formula 2,

Li.sub.aNi.sub.bM.sup.1.sub.cO.sub.2-eA.sub.e  <Formula 1>

Li.sub.xCu.sub.yX.sub.z.  <Formula 2>

A rechargeable manganese battery includes: (1) a first electrode including a porous, conductive support; (2) a second electrode including a catalyst support and a catalyst disposed over the catalyst support; and (3) an electrolyte disposed between the first electrode and the second electrode to support reversible precipitation and dissolution of manganese at the first electrode and reversible evolution and oxidation of hydrogen at the second electrode.

A rechargeable manganese battery includes: (1) a first electrode including a porous, conductive support; (2) a second electrode including a catalyst support and a catalyst disposed over the catalyst support; and (3) an electrolyte disposed between the first electrode and the second electrode to support reversible precipitation and dissolution of manganese at the first electrode and reversible evolution and oxidation of hydrogen at the second electrode.

An electrode includes a current collector; a first active material layer including a first active material; and a second active material layer including a second active material; wherein the first active material layer is arranged between the current collector and the second active material layer. The first active material layer is formed on a surface of the current collector, and a particle size of 90% accumulative volume of the first active material is less than 40 μm. The active material layer is used in the present application to ensure that the electrochemical device and the electronic device do not generate a short circuit when pressed by an external force, thereby ensuring the mechanical safety performance of the electrochemical device and the electronic device.

An electrode includes a current collector; a first active material layer including a first active material; and a second active material layer including a second active material; wherein the first active material layer is arranged between the current collector and the second active material layer. The first active material layer is formed on a surface of the current collector, and a particle size of 90% accumulative volume of the first active material is less than 40 μm. The active material layer is used in the present application to ensure that the electrochemical device and the electronic device do not generate a short circuit when pressed by an external force, thereby ensuring the mechanical safety performance of the electrochemical device and the electronic device.

A lithium primary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode contains a positive electrode material mixture including Li.sub.xMnO.sub.2 where 0 ≤ x ≤ 0.05. The negative electrode contains at least one of metal lithium and a lithium alloy. The non-aqueous electrolyte contains an oxalate borate complex component and a cyclic imide component. In the non-aqueous electrolyte, the concentration of the oxalate borate complex component is 5.5 mass% or less, and the concentration of the cyclic imide component is 1 mass% or less. The mass ratio of the cyclic imide component to the oxalate borate complex component contained in the non-aqueous electrolyte is 0.02 or more and 10 or less.

Battery systems, methods of in-situ grid-scale battery construction, and in-situ battery regeneration methods are disclosed. The battery system features controllable capacity regeneration for grid-scale energy storage. The battery system includes a battery comprising a plurality of cells. Each cell includes a cathode comprising cathode electrode materials disposed on a first current collector, an anode comprising anode electrode materials disposed on a second current collector, a separator or spacer disposed between the cathode and the anode an electrolyte to fill the battery in the spaces between electrodes. The battery system includes a battery system controller, wherein the battery system controller is configured to selectively charge and discharge the battery at a normal cutoff voltage and wherein the battery system controller is further configured to selectively charge and discharge the battery at a capacity regeneration voltage as part of a healing reaction to generate active electrode materials.

An example composition is disclosed. For example, the composition includes a ultra-violet (UV) curable mixture of water, an acid, a phosphine oxide with one or more photoinitiators, a water miscible polymer, a salt, and a neutralizing agent. The composition can be used to form an electrolyte layer that can be cured in the presence of air when printing the thin-film battery.

A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

A positive electrode active material for a non-aqueous electrolyte secondary battery includes LiX, where X represents a halogen atom.