A preparation method for a high nickel ternary precursor capable of preferential growth of crystal planes by adjusting and controlling the addition amount of seed crystals. The method comprises the following steps: 1) feeding a ternary metal solution into a reaction kettle containing a first base liquid for reaction, and when the particle size reaches 1.5 to 3.0 μm, stopping the feeding, so as to obtain a seed crystal slurry; 2) simultaneously adding the ternary metal solution, a liquid alkali solution, and an ammonia solution in cocurrent flow into a growth kettle containing a second base solution for reaction, when the particle size reaches 6 to 8 μm, adding the seed crystal slurry into the reaction system, and controlling the particle size to be 9.0 to 11.0 μm by adjusting the feed rate of the seed crystal, so as to obtain the target object. In the preparation method, by adding seed crystals continuously, the crystal plane parameters of 001 peak in the prepared ternary precursor material is lower than the crystal plane parameters of 101 peak, facilitating the embedding of Li ions, and effectively improving the performance of a battery prepared by using the material.

A method for producing a graphene oxide-based compound for an air electrode of a metal-air battery. A nitrogen and sulfur-based organic compound is added to an aqueous suspension of a graphene oxide. The water of the suspension is evaporated in order to obtain a powder. This powder is heated under an inert atmosphere in order to sublime the organic compound and stimulate the incorporation of nitrogen from the organic compound into the graphitic sites of the graphene oxide. The nitrogen and sulfur-doped graphene oxide is added to a second aqueous suspension comprising a cobalt nitrate-based compound. This second suspension is heated in order to form nanoparticles of cobalt oxide at the surface of at least one nitrogen and sulfur-doped graphene oxide sheet.

A method for producing a graphene oxide-based compound for an air electrode of a metal-air battery. A nitrogen and sulfur-based organic compound is added to an aqueous suspension of a graphene oxide. The water of the suspension is evaporated in order to obtain a powder. This powder is heated under an inert atmosphere in order to sublime the organic compound and stimulate the incorporation of nitrogen from the organic compound into the graphitic sites of the graphene oxide. The nitrogen and sulfur-doped graphene oxide is added to a second aqueous suspension comprising a cobalt nitrate-based compound. This second suspension is heated in order to form nanoparticles of cobalt oxide at the surface of at least one nitrogen and sulfur-doped graphene oxide sheet.

A rechargeable battery includes an iron electrode comprising carbonyl iron composition dispersed over a fibrous electrically conductive substrate. The carbonyl iron composition includes carbonyl iron and at least one additive. A counter-electrode is spaced from the iron electrode. An electrolyte is in contact with the iron electrode and the counter-electrode such that during discharge. Iron in the iron electrode is oxidized with reduction occurring at the counter-electrode such that an electric potential develops. During charging, iron oxides and hydroxides in the iron electrode are reduced with oxidation occurring at the counter-electrode (i.e., a nickel electrode or an air electrode).

There is provided a plate for a battery stack including: a plate-shaped terminal to which an electric wire is connected; and a plate-shaped housing having an accommodating recess where the terminal is accommodated. The accommodating recess includes a retaining hole, and the terminal includes a connection portion that is electrically connected to a counterpart member, and a retaining piece that is inserted into the retaining hole and locked to the retaining hole.

The present application relates to a cathode material and an electrochemical device comprising the same. In particular, the present application relates to a cathode material having a surface heterophasic structure, wherein the cathode material includes a lithium cobalt oxide and an oxide of cobalt, wherein a Raman spectrum of the cathode material has characteristic peaks in the range of about 470 cm.sup.−1 to about 530 cm.sup.−1, about 560 cm.sup.−1 to about 630 cm.sup.−1 and about 650 cm.sup.−1 to about 750 cm.sup.−1, and wherein the surface heterophasic structure of the cathode material includes the lithium cobalt oxide and the oxide of cobalt. The electrochemical device using the cathode material having a surface heterophasic structure of the present application can exhibit excellent cycle performance and thermal stability.

A cobalt oxide for a lithium secondary battery, a method of preparing the cobalt oxide; a lithium cobalt oxide for a lithium secondary battery formed from the cobalt oxide; and a lithium secondary battery having a positive electrode including the lithium cobalt oxide, the cobalt oxide having a tap density of about 2.8 g/cc to about 3.0 g/cc, and an intensity ratio of about 0.8 to about 1.2 of a second peak at 2θ of about 31.3±1° to a first peak at 2θ of about 19±1° in X-ray diffraction spectra, as analyzed by X-ray diffraction.

A cobalt oxide for a lithium secondary battery, a method of preparing the cobalt oxide; a lithium cobalt oxide for a lithium secondary battery formed from the cobalt oxide; and a lithium secondary battery having a positive electrode including the lithium cobalt oxide, the cobalt oxide having a tap density of about 2.8 g/cc to about 3.0 g/cc, and an intensity ratio of about 0.8 to about 1.2 of a second peak at 2θ of about 31.3±1° to a first peak at 2θ of about 19±1° in X-ray diffraction spectra, as analyzed by X-ray diffraction.

Provided is a high quality and high performance nickel-iron battery comprising an iron electrode which is prepared by a continuous process. The process comprises preparing a formulation comprising an iron active material and a binder, and continuously coating a continuous substrate material on at least one side with the formulation. The coated continuous substrate material is dried, compacted and blanked. In one embodiment, the iron electrode comprises a PVA binder.

A positive electrode active material that is used in a high-temperature operation type lithium ion solid secondary battery, wherein the positive electrode active material is made of oxide particles, which contains a first transition element and does not include an alkali metal.