Disclosed herein relates to a positive electrode for a lithium secondary battery and a lithium secondary battery including the same, and since the positive electrode contains a first positive electrode active material including an iron phosphate compound and a second positive electrode active material including a lithium composite metal oxide in a multi-layered positive electrode mixture layer, it is possible to display a large voltage deviation for each state of charge (SOC) of a secondary battery. Therefore, when applying a secondary battery, there is an advantage in that the state of charge (SOC) can be easily estimated and/or measured with high reliability. In addition, since the positive electrode for a lithium secondary battery contains a small amount of lithium composite metal oxide in the first positive electrode mixture layer adjacent to a positive electrode current collector among the plurality of positive electrode mixture layers, heat generated by the lithium composite metal oxide can be easily released to the outside, so there is an effect of further improving the safety of the secondary battery.

A secondary battery comprising a metallic lithium negative electrode and having a coulombic efficiency. The secondary battery of the present disclosure comprises a positive electrode active material layer, a solid electrolyte layer, and a negative electrode active material layer, wherein the negative electrode active material layer comprises a first substance and a second substance, wherein the first substance is at least one of an alloy of Li and an element X and a compound of Li and the element X; the second substance is at least one of a simple substance of a metal element M, an alloy of Li and the metal element M, and a compound of Li and the metal element M; and a formation energy E.sub.LiX of the first substance is lower than a formation energy E.sub.MX of the compound of the metal element M and the element X.

It is an object of the present invention to provide a nonaqueous electrolyte secondary battery with improved output characteristics. An example of an embodiment of the present invention provides a nonaqueous electrolyte secondary battery comprising an electrode assembly having a structure in which a positive electrode plate and a negative electrode plate are stacked with a separator therebetween. The positive electrode plate contains a lithium transition metal oxide containing tungsten as a positive electrode active material and also contains a phosphate compound. The negative electrode plate contains a graphitic carbon material and an amorphous/noncrystalline carbon material as negative electrode active materials and includes a coating of tungsten or a tungsten compound on the surface of the amorphous/noncrystalline carbon material.

Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.

Halogen-doped phosphorous nanoparticles and a manufacturing method thereof are provided. The manufacturing method includes a mixing process and a centrifugation or filtration process. The mixing process has the step of mixing a precursor with a reducing agent solution to form a mixed solution, the precursor is a halogen-based phosphide. Then, the mixed solution is centrifuged or filtrated to obtain the halogen-doped phosphorous nanoparticles.

A lithium ion battery component includes a support selected from the group consisting of a current collector, a negative electrode, and a porous polymer separator. A lithium donor is present i) as an additive with a non-lithium active material in a negative electrode on the current collector, or ii) as a coating on at least a portion of the negative electrode, or iii) as a coating on at least a portion of the porous polymer separator. The lithium donor has a formula selected from the group consisting of Li.sub.8-yM.sub.yP.sub.4, wherein M is Fe, V, or Mn and wherein y ranges from 1 to 4; Li.sub.10-yTi.sub.yP.sub.4, wherein y ranges from 1 to 2; Li.sub.xP, wherein 0<x3; and Li.sub.2CuP.

Provided is a lithium ion battery that exhibits a significantly improved specific capacity and much longer charge-discharge cycle life. In one preferred embodiment, the battery comprises a cathode, an anode, an electrolyte in ionic contact with both the cathode and the anode, and an optional separator disposed between the cathode and the anode, wherein, prior to the battery being assembled, the anode comprises (a) an anode active material layer composed of fine particles of a first anode active material having an average size from 1 nm to 10 m, an optional conductive additive, and an optional binder that bonds the fine particles and the conductive additive together to form the anode active material layer having structural integrity and (b) a layer of lithium metal or lithium metal alloy having greater than 80% by weight of lithium therein, wherein the layer of lithium metal or lithium metal alloy is in physical contact with the anode active material layer.

Provided is an alkali metal-sulfur cell comprises: (A) an anode comprising (i) an anode active material layer composed of fine particles of a first anode active material, an optional conductive additive, and an optional binder and, prior to assembly of the cell, (ii) a layer of an alkali metal or alkali metal alloy having greater than 50% by weight of lithium, sodium, or potassium therein, wherein the layer of alkali metal or alkali metal alloy is in physical contact with the anode active material layer; (B) a cathode active material layer and an optional cathode current collector, wherein the cathode active material layer contains multiple particulates of a sulfur-containing material selected from a sulfur-carbon hybrid, sulfur-graphite hybrid, sulfur-graphene hybrid, conducting polymer-sulfur hybrid, metal sulfide, sulfur compound, or a combination thereof; and (C) an electrolyte in ionic contact with the anode active material layer and the cathode active material layer.

An apparatus includes an electrochemical half-cell comprising: an electrolyte, an anode; and an ionomeric barrier positioned between the electrolyte and the anode. The anode may comprise a multi-electron vanadium phosphorous. The electrochemical half-cell is configured to oxidize the vanadium and phosphorous alloy to release electrons. A method of mitigating corrosion in an electrochemical cell includes disposing an ionomeric barrier in a path of electrolyte or ion flow to an anode and mitigating anion accumulation on the surface of the anode.

Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.