The present application relates to an anode active material and an anode, an electrochemical device and an electronic device using same. Specifically, the present application provides an anode active material, including a lithiated silicon-oxygen material and a coating layer, where there is at least a SiO-M bond between the coating layer and the lithiated silicon-oxygen material, where M is selected from one or more of an aluminum element, a boron element and a phosphorus element. The anode active material of the present application has high stability and is suitable for aqueous processing to be prepared into an anode.

This disclosure relates to a rechargeable battery cell comprising an active metal, at least one positive electrode, at least one negative electrode, a housing and an electrolyte, the positive electrode being designed as a high-voltage electrode and the electrolyte being based on SO.sub.2 and at least one first conducting salt having the formula (I), ##STR00001##
M being a metal selected from the group formed by alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements, and aluminum; x being an integer from 1 to 3; the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 being selected independently of one another from the group formed by C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.10 alkenyl, C.sub.2-C.sub.10 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl and C.sub.5-C.sub.14 heteroaryl; and Z being aluminum or boron.

A composite cathode active material includes a secondary particle; and a coating on a surface of the secondary particle, wherein the secondary particle comprises a plurality of primary particles, and the plurality of primary particles include a lithium nickel transition metal oxide having a layered crystal structure; and a grain boundary between primary particles of the plurality of primary particles, the grain boundary including a lithium metal oxide having a crystal structure different from the lithium nickel transition metal oxide having a layered crystal structure, wherein the coating on the surface of the secondary particle includes a metal oxide including cobalt, and a Group 2 element, a Group 12 element, a Group 13 element, or a combination thereof

An electrode unit for an electrochemical device, comprising (i) a solid electrolyte which divides a space for molten cathode material, selected from the group consisting of elemental sulfur and polysulfide of the alkali metal anode material, and a space for molten alkali metal anode material, and (ii) a porous solid state electrode directly adjacent to the solid electrolyte within the space for the cathode material, with a non-electron-conducting intermediate layer S present between the solid state electrode and the solid electrolyte, wherein this intermediate layer S has a thickness in the range from 0.5 to 5 mm and, before the first charge of the electrochemical device, has been impregnated fully with a polysulfide composition, comprising (A) pure polysulfides Met.sub.2S.sub.x with Met=alkali metal of the alkali metal anode material selected from lithium, sodium, potassium, and x is dependent on the alkali metal and is 2, 3, 4 or 5 for Na and is 2, 3, 4, 5, 6, 7, 8 for Li and is 2, 3, 4, 5, 6 for K, or (B) mixtures of the polysulfides of one and the same alkali metal from (A) with one another.

Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.

A method for preparing iron phosphide (FeP), a positive electrode of a lithium secondary battery including iron phosphide (FeP), for instance, prepared using the method, and a lithium secondary battery including the same. In the lithium secondary battery including the positive electrode using iron phosphide (FeP), the iron phosphide (FeP) adsorbs lithium polysulfide (LiPS) produced during a charge and discharge process of the lithium secondary battery, which is effective in increasing charge and discharge efficiency and enhancing lifetime properties of the battery.

An all solid battery includes: a solid electrolyte layer of which a main component is phosphoric acid salt-based solid electrolyte; a positive electrode layer that is formed on a first main face of the solid electrolyte layer; and a negative electrode layer that is formed on a second main face of the solid electrolyte layer, wherein the positive electrode layer includes a positive electrode active material and a solid electrolyte, wherein a discharge capacity of the solid electrolyte of the positive electrode layer is 20% to 50% on a presumption that a discharge capacity of the positive electrode active material is 100%.

A positive electrode active material for a battery, the positive electrode active material comprising a compound having a crystal structure of space group Fm-3m and represented by composition formula (1): Li.sub.xMe1.sub.Me2.sub.O.sub.2 . . . (1). In the formula, Me1 represents one or more elements selected from the group consisting of Mn, Ni, Co, Fe, Al, Sn, Cu, Nb, Mo, Bi, Ti, V, Cr, Y, Zr, Zn, Na, K, Ca, Mg, Pt, Au, Ag, Ru, Ta, W, La, Ce, Pr, Sm, Eu, Dy, and Er, Me2 represents one or more elements selected from the group consisting of B, Si, and P, and the following conditions are met: 0<; 0<; +=y; 0.5x/y3.0; and 1.5x+y2.3.

Provided is an alkali metal-sulfur cell comprises: (A) an anode comprising (i) an anode active material layer composed of fine particles of a first anode active material, an optional conductive additive, and an optional binder and, prior to assembly of the cell, (ii) a layer of an alkali metal or alkali metal alloy having greater than 50% by weight of lithium, sodium, or potassium therein, wherein the layer of alkali metal or alkali metal alloy is in physical contact with the anode active material layer; (B) a cathode active material layer and an optional cathode current collector, wherein the cathode active material layer contains multiple particulates of a sulfur-containing material selected from a sulfur-carbon hybrid, sulfur-graphite hybrid, sulfur-graphene hybrid, conducting polymer-sulfur hybrid, metal sulfide, sulfur compound, or a combination thereof; and (C) an electrolyte in ionic contact with the anode active material layer and the cathode active material layer.

Provided are a nonaqueous electrolyte energy storage device having high capacity retention ratio after charge-discharge cycles at a high temperature of about 45 C., and a method for producing such a nonaqueous electrolyte energy storage device. One aspect of the present invention is a nonaqueous electrolyte energy storage device including a positive electrode having a positive composite that contains a phosphorus atom and a lithium-transition metal composite oxide containing manganese, wherein, in a spectrum of the positive composite by X-ray photoelectron spectroscopy, a peak position for P2p is observed at 134.7 eV or less. Another aspect of the present invention is a method for producing a nonaqueous electrolyte energy storage device, the method including forming a positive electrode using a positive composite paste that contains a phosphorus oxo acid and a lithium-transition metal composite oxide containing manganese.