The disclosure set forth herein is directed to battery devices and methods therefor. More specifically, embodiments of the instant disclosure provide a battery electrode that comprises both intercalation chemistry material and conversion chemistry material, which can be used in automotive applications. There are other embodiments as well.

A negative electrode active material particle with little deterioration is provided. Alternatively, a novel negative electrode active material particle is provided. Alternatively, a power storage device with little deterioration is provided. Alternatively, a highly safe power storage device is provided. Alternatively, a novel power storage device is provided. The electrode includes an active material and a conductive additive; the active material contains a metal or a compound including one or more elements selected from silicon, tin, gallium, aluminum, germanium, lead, antimony, bismuth, silver, zinc, cadmium, and indium; the conductive additive contains a graphene compound; and the graphene compound contains fluorine.

A negative electrode with little degradation is provided. Alternatively, a novel negative electrode is provided. A secondary battery includes a positive electrode and a negative electrode, and the negative electrode includes a solvent containing fluorine, a current collector, a negative electrode active material, and graphene. The negative electrode further includes a solid electrolyte material and the solid electrolyte material is an oxide. The negative electrode active material may contain fluorine. The secondary battery may include a plurality of electrolytes different from each other. The negative electrode active material is, for example, a material containing one or more elements selected from silicon, tin, gallium, aluminum, germanium, lead, antimony, bismuth, silver, zinc, cadmium, and indium.

A positive electrode material, including a composite material, where the composite material includes a metal fluoride, a molar ratio of fluorine F to metal element M in the metal fluoride is y, and a molar ratio of fluorine F to metal element M in the composite material is z, where y<z≤y+2; and M includes at least one of Al, Cu, Co, Ni, Mn, Fe, or Ag. The positive electrode material in this application has advantages such as wide raw material sources, simple preparation processes, easy to operate, and low production costs. Lithium batteries prepared by using the positive electrode material in this application have increased specific capacity and improved rate performance and cycling performance of the positive electrode material, and good charge and discharge performance.

A positive electrode active material has a small difference in a crystal structure between the charged state and the discharged state. For example, the crystal structure and volume of the positive electrode active material, which has a layered rock-salt crystal structure in the discharged state and a pseudo-spinel crystal structure in the charged state at a high voltage of approximately 4.6 V, are less likely to be changed by charging and discharging as compared with those of a known positive electrode active material. In order to form the positive electrode active material having the pseudo-spinel crystal structure in the charged state, it is preferable that a halogen source such as a fluorine and a magnesium source be mixed with particles of a composite oxide containing lithium, a transition metal, and oxygen, which is synthesized in advance, and then the mixture be heated at an appropriate temperature for an appropriate time.

A Li or Li-ion or Na or Na-ion battery cell is provided that comprises anode and cathode electrodes, a separator, and a solid electrolyte. The separator electrically separates the anode and the cathode. The solid electrolyte ionically couples the anode and the cathode. The solid electrolyte also comprises a melt-infiltration solid electrolyte composition that is disposed at least partially in at least one of the electrodes or in the separator.

A negative electrode for a lithium secondary battery, in which a LiF layer comprising amorphous LiF in an amount of 30 mol % or more is formed on a negative electrode active material layer comprising a carbon-based active material, a lithium secondary battery comprising the same, and a preparation method thereof.

An electrochemical energy storage device is described. The electrochemical energy storage device comprises: a first electrode comprising a transition metal fluoride; a second electrode; and an electrolyte comprising an ionic liquid. An electrode for the electrochemical energy storage device and a method of preparing the electrode are also described.

An irreversible additive includes an oxide having a trigonal crystal structure and represented by Formula 1, and a coating layer positioned on a surface of the oxide and including a compound represented by Formula 2. A positive electrode material including the irreversible additive and a lithium secondary battery including the positive electrode material including the irreversible additive are also provided.

A positive electrode material of the present disclosure includes: a material represented by the following composition formula (1); and a carbon material capable of occluding at least one selected from the group consisting of a simple substance of halogen and a halide, Li.sub.aM.sub.bX.sub.c . . . Formula (1) where a, b, and c are each a value greater than 0, M includes at least one selected from the group consisting of metal elements other than Li and metalloid elements, and X includes a halogen element.