A positive electrode active material includes a plurality of groups of particles. The plurality of groups of particles has a particle diameter of more than or equal to 300 nm and less than or equal to 3 μm. Each of the groups includes two or more particles. The two or more particles are each a lithium-containing complex phosphate including one or more of iron, nickel, manganese, and cobalt. The group of particles includes a first particle and a second particle each having a major diameter and a minor diameter in the upper surface when seen from a predetermined direction. The major diameters of the first and second particles are substantially parallel to each other. The major diameter of the first particle is two to six times larger than the minor diameter of the first particle and the minor diameter of the first particle is more than or equal to 20 nm and less than or equal to 130 nm.

An LiFePO.sub.4 precursor for manufacturing an electrode material of an Li-ion battery and a method for manufacturing the same are disclosed. The LiFePO.sub.4 precursor of the present disclosure can be represented by the following formula (I):
LiFe.sub.(1-a)M.sub.aPO.sub.4  (I)
wherein M and a are defined in the specification, the LiFePO.sub.4 precursor does not have an olivine structure, and the LiFePO.sub.4 precursor is powders constituted by plural flakes.

Development of a flexible battery based on periodate/iodate-zinc system is disclosed. H.sub.3PO.sub.4—KCl dual quasi-solid electrolytes separated by an anion-exchange-membrane maintain the desired pH in electrodes and block unwanted ion movements. Poly(acrylic acid) fortifies the electrodes, enhances electrode flexibility, and avoids the free-flow of liquids. The NaMnIO.sub.6 shows a specific capacity of 650 mAg.sup.−1, approximately 81% of its theoretical capacity even when cells are bent. The overall technology is scalable by printing methods.

An electrochemical cell, including a first electrode, a first volume of electrolyte in contact with the first electrode, a second volume of electrolyte, a first separator positioned between the first volume and the second volume, a second electrode in contact with the second volume, and a third volume of electrolyte. A second separator is positioned between the second volume and the third volume. A lithium reservoir electrode is in contact with the third volume.

An electrochemical cell according to various aspects of the present disclosure includes a positive electrode, a negative electrode, a separator, and an electrolyte. The positive electrode includes a positive electroactive material. The positive electroactive material includes a phospho-olivine compound. The negative electrode includes lithium metal. The separator is between the positive electrode and the negative electrode. The separator is electrically insulating and ionically conductive. The electrolyte includes a ternary salt and a solvent. The ternary salt includes LiPF.sub.6, LiFSI, and LiClO.sub.4.

An electrode precursor or slurry according to various aspects of the present disclosure includes a blended electroactive material and a binder solution. The blended electroactive material includes a first electroactive material and a second electroactive material. The first electroactive material includes nickel. The first electroactive material is selected from the group consisting of LiNi.sub.xCo.sub.yMn.sub.zO.sub.2 where x is greater than 0.6, LiNi.sub.xCo.sub.yAl.sub.zO.sub.2 where x is greater than 0.6, LiNi.sub.xCo.sub.yMn.sub.zAl.sub.αO.sub.2 where x is greater than 0.6, or any combination thereof. The second electroactive material includes a phosphor-olivine compound at less than or equal to about 30 weight percent of the blended electroactive material. The binder solution including a polymeric binder and a solvent including N-methyl-2-pyrrolidone. In various aspects, the present disclosure provides a high-nickel-content positive electrode formed from the slurry. In various aspects, the present disclosure provides an electrochemical cell including the positive electrode and a lithium metal negative electrode.

Provided is a lithium secondary battery including a positive electrode including a positive electrode current collector, and a positive active material layer on the positive electrode current collector; a negative electrode including a negative active material; and an electrolyte solution including a non-aqueous organic solvent, a lithium salt, and an additive, the positive active material layer includes a positive active material and carbon nanotube, an average length of the carbon nanotube is greater than or equal to 1 μm and less than 200 μm, the carbon nanotube is included in an amount of greater than or equal to 0.5 wt % and less than 4 wt % based on the total weight of the positive active material layer, and the additive includes a phosphate-based compound represented by Chemical Formula 1.

A sintered electrode for a battery, the sintered electrode having a first surface positioned to face a current collector and a second surface positioned to face an electrolyte layer, such that the sintered electrode includes: a first phase and a second phase, such that: the first phase has a lithium compound, and the second phase has at least one of a porous structure or solid-state Li-ion conductors, and such that: a thickness of the sintered electrode between the first surface and the second surface ranges between 10 μm and 200 μm.

A prelithiated anode may include a current collector may include a metal oxide layer. Prelithiated anodes may in addition include a lithiated storage layer overlaying the metal oxide layer. The lithiated storage layer may be formed by incorporating lithium into a continuous porous lithium storage layer may include at least 80 atomic % silicon. The lithiated storage layer may include less than 1% by weight of carbon-based binders. The lithiated storage layer may further include lithium in a range of 1% to 90% of a theoretical lithium storage capacity of the continuous porous lithium storage layer. Batteries may include the prelithiated anode.

The present disclosure discloses a cathode composite material for a lithium-ion battery (LIB), and a preparation method thereof. The cathode composite material for an LIB is composed of a lithium-containing matrix and a three-layer coating layer coated on a surface of the matrix, where the three-layer coating layer includes a lithium-deficient matrix material layer, a lithium-deficient lithium cobalt phosphate (LCP) layer, and a cobalt phosphate layer in sequence from inside to outside. The cathode composite material of the present disclosure can reduce the oxidation of a highly-delithiated cathode material to an electrolyte under high voltage, and has a high energy density.