The non-aqueous electrolyte secondary cell according to an embodiment of the present disclosure has a positive electrode, a negative electrode, and a non-aqueous electrolytic solution. The negative electrode has a negative electrode collector and a negative electrode active material layer provided on the negative electrode collector. The negative electrode active material layer contains graphite particles A and graphite particles B as negative electrode active materials. The graphite particles A have an internal void rate of 5% or below. The graphite particles B have an internal void rate of 8 to 20%. When the negative electrode active material layer is halved in the thickness direction, a region on the half closer to the outer surface contains more graphite particles A than a region on the half closer to the negative electrode collector.

Disclosed is a method of fabricating an anode for a lithium-ion battery, including milling a mixture of nano-silicon, one or more carbonaceous materials and one or more solvents, wherein the mixture is retained as a wet slurry during milling. The mixture is carbonised to produce a silicon thinly coated with carbon (Si@C) material. Further milling occurs of a second mixture of the Si@C material, one or more graphite, one or more second carbonaceous materials and one or more second solvents, wherein the second mixture is retained as a second wet slurry during milling. The second mixture is carbonised to produce a Si@C/graphite/carbon material. The anode is formed from the Si@C/graphite/carbon material.

Disclosed is a method of fabricating an anode for a lithium-ion battery, including milling a mixture of nano-silicon, one or more carbonaceous materials and one or more solvents, wherein the mixture is retained as a wet slurry during milling. The mixture is carbonised to produce a silicon thinly coated with carbon (Si@C) material. Further milling occurs of a second mixture of the Si@C material, one or more graphite, one or more second carbonaceous materials and one or more second solvents, wherein the second mixture is retained as a second wet slurry during milling. The second mixture is carbonised to produce a Si@C/graphite/carbon material. The anode is formed from the Si@C/graphite/carbon material.

A negative active material for an all solid-state includes an aggregated material of amorphous carbon having pores therein in which primary particles are aggregated, and metal nanoparticles filling in the pores.

A bilayer-structured silicon carbon composite anode material, a method of preparing the same, and a secondary battery including the same is provided. The method of preparing the anode material includes: drying a first mixture including graphite balls, a nano-silicon slurry, pitch, and flake graphite to prepare a dried product; sintering the dried product to prepare a sintered product including a hard coating layer formed on an outermost surface thereof and containing amorphous hard carbon; mixing the sintered product with a carbon precursor, followed by heat treatment to form a soft coating layer on an outer circumferential surface of the sintered product; and forming a carbon nanotube layer on an outer circumferential surface of the soft coating layer.

A bilayer-structured silicon carbon composite anode material, a method of preparing the same, and a secondary battery including the same is provided. The method of preparing the anode material includes: drying a first mixture including graphite balls, a nano-silicon slurry, pitch, and flake graphite to prepare a dried product; sintering the dried product to prepare a sintered product including a hard coating layer formed on an outermost surface thereof and containing amorphous hard carbon; mixing the sintered product with a carbon precursor, followed by heat treatment to form a soft coating layer on an outer circumferential surface of the sintered product; and forming a carbon nanotube layer on an outer circumferential surface of the soft coating layer.

A method of preparing a lithium metal electrode, wherein the method includes providing a lithium metal strip, and providing a lubricant composition including a fluorine-based solvent and a fluorine-based compound on the lithium metal strip to obtain a coated lithium metal strip; and rolling the coated lithium metal strip to obtain the lithium metal electrode.

Material compositions are provided that may comprise, for example, a vertically aligned carbon nanotube (VACNT) array, a conductive layer, and a carbon interlayer coupling the VACNT array to the conductive layer. Methods of manufacturing are provided. Such methods may comprise, for example, providing a VACNT array, providing a conductive layer, and bonding the VACNT array to the conductive layer via a carbon interlayer.

Material compositions are provided that may comprise, for example, a vertically aligned carbon nanotube (VACNT) array, a conductive layer, and a carbon interlayer coupling the VACNT array to the conductive layer. Methods of manufacturing are provided. Such methods may comprise, for example, providing a VACNT array, providing a conductive layer, and bonding the VACNT array to the conductive layer via a carbon interlayer.

The present disclosure relates to a negative electrode material that may be used as a negative electrode active material. The negative electrode material includes a silicon oxide material containing a metal (M)-silicate and a carbonaceous material. According to an embodiment of the present disclosure, the negative electrode material may include the silicon oxide material containing a metal (M)-silicate and the carbonaceous material mixed with each other at a predetermined ratio. The negative electrode active material according to the present disclosure comprises a composite of a carbonaceous material having a broad particle size distribution with a metal-silicate, and thus provides improved electrical conductivity and life characteristics.