The nonaqueous electrolyte energy storage device according to an aspect of the present invention includes a negative electrode including graphite and graphitizable carbon, in which a ratio of a mass of the graphitizable carbon to a total mass of the graphite and the graphitizable carbon is less than 26% by mass, and a median diameter of the graphitizable carbon is smaller than a median diameter of the graphite.

Negative electrodes for electrochemical cells that cycle lithium ions are provided. The negative electrodes comprise electroactive material particles that exhibit a core-shell structure defining a core made of a lithiated silicon-based material and a shell surrounding the core that is a bi-layer structure including first and second carbon coating layers. An electrical conductivity of the first carbon coating layer is greater than that of the second carbon coating layer. A method of manufacturing a negative electrode material is provided in which a first carbon coating layer is formed on an outer surface of a silicon-based precursor particle. The silicon-based precursor particle is exposed to a lithium source to form a lithiated silicon-based particle having the first carbon coating layer. A second carbon coating layer is formed on the first carbon coating layer over the lithiated silicon-based particle to form an electroactive material particle.

The present disclosure relates to a multilayer electrode and a method of manufacturing the same, and more specifically to a multilayer electrode comprising an electrode collector; and two or more electrode active material layers which are sequentially coated on one surface or both surfaces of the electrode current collector, wherein the electrode active material layers each include a carbon-based material, a binder, and a silicon-based material, wherein in the mutually adjacent electrode active material layers based on the direction of formation of the electrode active material layers, the content of the carbon-based material and the content of the binder in the electrode active material layer located relatively close to the electrode collector are larger than the content of the carbon-based material and the content of the binder in the electrode active material layers located relatively far away from the electrode current collector.

A binder for preparing a positive electrode of a lithium secondary battery, and a method for preparing a positive electrode using the same. The binder includes two or more different lithium-substituted polyacrylic acids with different molecular weights. The lithium-substituted polyacrylic acids include two different lithium-substituted polyacrylic acids differing in weight average molecular weight by 500,000 or more from each other.

An anode material having 0.8≤0.06×(Dv50).sup.2−2.5×Dv50+Dv99≤12 (1); and 1.2≤0.2×Dv50−0.006×(Dv50).sup.2+BET≤5 (2), where Dv50 represents a value in the volume-based particle size distribution of the anode material that is greater than the particle size of 50% of the particles, Dv99 represents a value in the volume-based particle size distribution of the anode material that is greater than the particle size of 99% of the particles, and BET is a specific surface area of the anode material, wherein Dv50 and Dv99 are expressed in μm and BET is expressed in m.sup.2/g. The anode material is capable of significantly improving the rate performance of electrochemical devices.

Provided is a lithium ion battery, comprising a positive electrode containing a positive electrode material layer, a negative electrode and a non-aqueous electrolyte, the layer comprises a positive electrode active material, the material comprises Li.sub.xNi.sub.yCo.sub.zM.sub.1-y-zO.sub.2, M is at least one element selected from Mn and Al, the material is doped or coated with an element E, which is selected from one or more of Ba, Zn, Ti, Mg, Zr, W, Y, Si, Sn, B, Co, and P, a potential range of the positive electrode active material with respect to lithium metal is ≥4.25V; the non-aqueous electrolyte comprises a solvent, an electrolyte salt and an additive, the additive comprises a compound represented by structural formula 1:

##STR00001## the lithium ion battery meets the following requirements:

0.1≤(H/T)×M/1000≤10; and

80≤H≤150,0.005≤T≤0.8,0.05≤M≤3.

The lithium ion battery provided by the application has a lower battery impedance and excellent high-temperature cycle performance.

Energy sources embodying the invention include one or more cells, where each cell includes an electrode (anode or cathode) which is a non-metal and another electrode which is a metal or non-metal, with the electrodes positioned relative to each other to produce a potential differential. The electrodes may be placed in a water solution or kept in air (dry). They may be spaced apart or be in direct contact. A conduction enhancing layer may be placed between the electrodes.

This application discloses a secondary battery and a device containing the secondary battery. A positive active material of the secondary battery includes one or more of lithium nickel cobalt manganese oxide, lithium nickel cobalt aluminum oxide, and a modified material thereof. A negative active material of the secondary battery includes a silicon-oxygen compound and graphite. A separator of the secondary battery includes a substrate and a coating layer. The secondary battery satisfies:

[00001]$7.5\le \frac{3460}{ED}-\left(D50-D_{C}50\times 0.75-\frac{T}{18}\right)\le 11.5,$

where ED≥270 Wh/Kg, 11 μm≤D50≤18.5 μm, 11 μm≤D.sub.C50≤20 μm. The secondary battery according to this application achieves relatively high cycle performance while achieving a relatively high energy density concurrently.

Composite carbon particles including a porous carbon material and a silicon component, the composite carbon particle having an average aspect ratio of 1.25 or less, and a ratio (I.sub.Si/I.sub.G) of a peak intensity (I.sub.Si) in the vicinity of 470 cm.sup.−1 to a peak intensity (I.sub.G) in the vicinity of 1580 cm.sup.−1 as measured by Raman spectroscopy of 0.30 or less, wherein the porous carbon material satisfies V.sub.1/V.sub.0>0.80 and V.sub.2/V.sub.0<0.10, when a total pore volume at a maximum value of a relative pressure P/P.sub.0 is defined as V.sub.0 and P.sub.0 is a saturated vapor pressure, a cumulative pore volume at a relative pressure P/P.sub.0=0.1 is defined as V.sub.1, a cumulative pore volume at a relative pressure P/P.sub.0=10.sup.−7 is defined as V.sub.2 in a nitrogen adsorption test, and has a BET specific surface area of 800 m.sup.2/g or more.

An all-solid-state battery manufacturing apparatus disclosed herein includes a transport apparatus, a press roller, and an adhesive provision apparatus. The transport apparatus transports an active material layer. The press roller has a foil attachment surface, which is a cylindrical surface to which the current collection foil is to be attached. The press roller rotates and moves the current collection foil attached to the foil attachment surface to the surface of the active material layer being transported by the transport apparatus and presses the current collection foil and the active material layer between the press roller and the transport apparatus. The adhesive provision apparatus is provided on a movement path of the current collection foil rotated and moved by the foil attachment surface of the press roller, and provides an adhesive to the current collection foil attached to the press roller.