An object of the present invention is to provide a lithium-ion secondary battery having a large charge and discharge capacity and excellent cycle characteristics irrespective of kind and shape of a current collector. The lithium-ion secondary battery comprises an electrode comprising a primer layer for protecting a current collector and a crosslinking agent layer comprising a compound being capable of crosslinking an aqueous binder contained in the primer layer, the both layers being disposed between a current collector and an active material layer comprising a sulfur-based active material.

Described herein are composite anode compositions comprising silicon for use in an electrochemical cell. The composite anode compositions described herein include silicon as an anode active material having a particle size, crystallite size, and surface area that provide desired electrochemical properties. Further provided herein are electrochemical cells comprising the anode compositions and methods of making the same.

An ultra-fast charging, high-capacity composite material for use with anodes in lithium-ion batteries including a phosphorene layer on a carbon-based negative electrode material. The carbon-based negative electrode material may be activated carbon, graphene, carbon nanotubes, or combinations thereof. The phosphorene layer includes a base layer of black phosphorus upon which is deposited activated carbon having a disclosed range of particle size and surface area. In a second embodiment, the negative electrode material is a composite of activated carbon and black carbon and includes a negative electrode current collector of copper foil. A slurry is made from a carbon-based conductive agent and a binder, and applied to both sides of the copper foil, then heated and compacted with a rolling machine. The anodes thus produced are used in making lithium-ion batteries, capacitors, etc.

What are provided are a positive electrode for a lithium-ion battery capable of suppressing the generation of carbon dioxide while increasing the battery capacity of the lithium-ion battery, a lithium-ion battery and a method for producing a positive electrode for a lithium-ion battery. A positive electrode for a lithium-ion battery having a positive electrode current collector and a positive electrode active material layer, in which the positive electrode active material layer has a positive electrode mixture containing the positive electrode active material, and the positive electrode mixture contains lithium carbonate in a range of 9% by mass or more and 20% by mass or less with respect of the total weight thereof.

The present disclosure relates to a stretchable electrode, a method for preparing the same and a stretchable battery including the stretchable electrode. The stretchable electrode of the present disclosure, which is prepared by crosslinking a hydroxyl-functionalized fluorine-based polymer binder physically using a ketone-based solvent or chemically with a crosslinking agent, has superior stretchability, has improved interfacial adhesivity to an active material through Fenton's oxidation, exhibits improved stability under various mechanical deformations of the electrode such as stretching, etc. and can uniformly maintain the electrical conductivity, battery capacity and charge-discharge performance of the electrode.

In addition, the stretchable battery of the present disclosure, which includes the stretchable electrode, a stretchable current collector, a stretchable separator and a stretchable encapsulant, has improved stretchability and superior battery stability under various deformations due to high degree of freedom of structures and materials. In addition, the stretchable battery of the present disclosure can be prepared as a fiber battery by printing an electrode and a current collector sequentially on both sides of a stretchable fabric, which can be worn, e.g., around sleeves due to superior stretchability and high structural degree of freedom and retains high battery performance and mechanical stability even under mechanical deformation. Therefore, it can be applied to a mobile display for a health monitoring system or a smartwatch.

Methods of forming a composite material film can include providing a mixture comprising a precursor and silane-treated silicon particles. The methods can also include pyrolysing the mixture to convert the precursor into one or more carbon phases to form the composite material film with the silicon particles distributed throughout the composite material film.

There is provided an improved electrochemical energy storage device. The storage device includes using functionalized boron nitride nanoparticles as electroactive materials in the electrodes.

This invention relates to particulate electroactive materials comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework including micropores and optional mesopores having a total volume of at least 0.7 cm.sup.3/g and up to 2 cm.sup.3/g, wherein at least half of the total micropore and mesopore volume is in the form of pores having a diameter of no more than 1.5 nm; and (b) silicon located within the micropores and optional mesopores of the porous carbon framework in a defined amount relative to the total volume of the micropores and optional mesopores.

A sulfur-carbon composite including porous carbon material, and sulfur, wherein at least a portion of an inside and a surface of the porous carbon material coated with the sulfur, the sulfur-carbon composite has a pore volume of 0.180 cm.sup.3/g to 0.300 cm.sup.3/g, and the sulfur-carbon composite has an average pore size of 40.0 nm to 70.0 nm, and a method of manufacturing the same. Also, a method of manufacturing a sulfur-carbon composite, which includes (a) mixing a porous carbon material with sulfur particles, wherein the sulfur particles have a particle size of 1 nm to 1 μm using a Henschel mixer; and (b) drying the resulting mixture of (a).

A porous silicon-containing composite includes: a porous core including a porous silicon composite secondary particle; and a shell on at least one surface of the porous core, the shell including a first graphene, wherein the porous silicon composite secondary particle includes an aggregate of a first primary particle including silicon, a second primary particle including a structure and second graphene on at least one surface of the first primary particle and the second primary particle, and wherein at least one of a shape and a degree of oxidation of the first primary particle and the second primary particle are different. Also an electrode including the porous silicon-containing composite, a lithium battery including the electrode, and a device including the porous silicon-containing composite or the carbon composite.