A secondary battery with favorable cycle performance is provided. Alternatively, a secondary battery with higher capacity is provided. A positive electrode active material layer including a first graphene layer, a second graphene layer, and a positive electrode active material. The first graphene layer includes a first region covering the positive electrode active material. The second graphene layer includes a second region covering the positive electrode active material and a third region overlapping with the first region. The first region includes a plane positioned between the positive electrode active material and the third region and formed of arranged six-membered carbon rings. The positive electrode active material includes a fourth region with a layered rock-salt structure. A lithium layer with a layered rock-salt structure included in the fourth region is substantially perpendicular to the plane formed of six-membered carbon rings and included in the second region.

The present disclosure relates to a method of manufacturing an anode active material for a lithium secondary battery, the method including: mixing earth graphite and pitch coke with each other; preparing a raw material by adding and mixing a binder to the mixture; performing heat treatment on the raw material; graphitizing the heat-treated mixture to obtain a core part; immersing the core part in a hard carbon coating solution; and drying the coating solution in which the core part is immersed to obtain an anode active material.

An electrode plate includes a current collector, a first active substance layer, a second active substance layer, and an insulation layer. The current collector includes a first surface, the first active substance layer includes a first active substance, and the second active substance layer includes a second active substance. The first active substance layer is sandwiched between the current collector and the second active substance layer and covers a first portion of the first surface, the insulation layer covers a second portion of the first surface, and the first active substance layer and the insulation layer are stacked to form an overlapped portion in a length direction of the electrode plate. The current collector can be covered by a high-resistance layer, thereby improving safety performance of the electrochemical apparatus and the electronic apparatus.

A negative electrode plate includes: a current collector; and a negative electrode framework located on the current collector, where the negative electrode framework includes at least a first negative electrode framework layer and a second negative electrode framework layer, the first negative electrode framework layer is located between the current collector and the second negative electrode framework layer, and a porosity of the first negative electrode framework layer is higher than a porosity of the second negative electrode framework layer. With this design, side reactions between lithium metal and an electrolyte can be reduced, formation of lithium dendrites can be inhibited, and drastic swelling and contraction of the negative electrode plate in volume due to intercalation and deintercalation of lithium ions can be greatly alleviated or even eliminated, thereby improving safety and stability of the electrochemical apparatus.

A negative electrode material includes a composite of a silicon-based material (1), a polymer (2), and carbon nanotubes (3), where the polymer (2) contains a first group and a second group, the first group is chemically bonded to the carbon nanotubes (3), and the second group is chemically bonded to the silicon-based material (1). Both the carbon nanotubes (3) and the polymer (2) containing two groups are applied to surfaces of particles of the silicon-based material (1). The two groups of the polymer (2) are chemically bonded to the silicon-based material (1) and the carbon nanotubes (3) respectively, so that bonding force between the silicon-based material (1) and the carbon nanotubes (3) is enhanced and a uniform carbon nanotube (3) coating layer is formed. This can significantly improve conductive performance of the silicon-based material (1), thereby improving cycling performance and rate performance of an electrochemical apparatus.

Provided is an electrode mixture containing a lithium-containing transition metal oxide; a conductive additive; a binder; and an organic solvent, wherein the conductive additive comprises at least one nanocarbon material selected from the group consisting of a multilayer carbon nanotube, a carbon nanohorn, a carbon nanofiber, a fullerene, and a graphene, the binder comprises a fluorine-containing copolymer comprising vinylidene fluoride unit and a fluorinated monomer unit, provided that vinylidene fluoride unit is excluded from the fluorinated monomer unit, and a content of vinylidene fluoride unit in the fluorine-containing copolymer is more than 50 mol % and 99 mol % or less with respect to all monomer units.

The present invention discloses a method for making lead-carbon electrode sheets, lead-carbon electrode sheets and lead-carbon battery. The method consists of steps of oxidizing lead under low-temperature atmosphere and the oxidized lead is used as interface layer of lead-carbon coupling, and using a specialized ventilation method for the carbon to coat the lead. The interface layer of oxidized lead forms a stable interface between the carbon and the lead. Meanwhile, through controlling pressure and temperature, a multi-porous metal composite is formed and the porosity can be penetration paths for air and liquid when the multi-porous metal composite is applied. The lead-carbon composite is applied as a lead-carbon electrode sheet and is further welded as a lead-carbon electrode sheet of a lead-carbon battery. The lead-carbon battery carrying the lead-carbon electrode demonstrates Coulomb efficiency of 100% without heat loss on an unsaturated charge-discharge condition of high-efficiency charging and high-efficiency discharging.

A separator structure for a secondary battery includes: a porous substrate; an intermediate layer on the porous substrate and including lithium fluoride (LiF) and a defluorinated polymer; and a lithium metal layer on the intermediate layer. An anode-separator assembly for a secondary battery includes an anode comprising an anode current collector and an anode active material layer on a surface of the anode current collector, and the separator structure. A secondary battery includes the anode-separator assembly, and a cathode on the porous substrate of the anode-separator assembly.

A lithium-sulfur battery includes a casing, a top lid circumferentially welded to the casing, a negative contact surface positioned opposite the top lid, a positive terminal disposed within the casing, welded to the top lid, and configured as a mandrel, a glass insulator circumferentially wound around the mandrel, and a jelly roll including at least an anode and a cathode wound around the mandrel. The jelly roll may also include a top surface not in contact with the top lid, a bottom surface partially in contact with the negative contact surface, and partially in contact with a plurality of non-hollow carbonaceous spherical particles disposed between the bottom surface of the jelly roll and the negative contact surface. At least some of the non-hollow carbonaceous spherical particles may provide one or more electrically-conductive pathways between the bottom surface and the negative contact surface.

The propose method of manufacturing a solid-state lithium battery consists of preparing an anode coated with a solid-state electrolyte precursor and a cathode unit coated with solid-state electrolyte, both precursors containing a predetermined amount of a redundant water. The thus prepared anode unit and cathode unit are pressed to each other through their respective electrolyte precursor layers in a closed chamber at a predetermined elevated temperature and under a predetermined mechanical pressure, whereby an integral pre-final solid-state battery unit is formed. The manufacture of the battery is completed by inserting the prefinal product into a casing that leaves parts of the metal current collectors of the prefinal product exposed for use as a battery anode and a battery cathode.