According to the present disclosure, it is possible to inhibit the electrically conductive foreign substance from falling off and being peeled off from the electrode plate that has been already manufactured, so as to contribute in improving the safety property of the secondary battery. The manufacturing method of the electrode plate herein disclosed includes a precursor preparing step for preparing an electrode precursor 20A including an active substance provided area A1 in which an electrode active substance layer 24 is provided on a surface of the electrode substrate 22 and including a substrate exposed area A2 in which the electrode active substance layer 24 is not provided and the electrode substrate 22 is exposed, an active substance provided area cutting step for cutting the active substance provided area A1 by a pulse laser, and a substrate exposed area cutting step for cutting the substrate exposed area A2 by the pulse laser. Then, the frequency of the pulse laser in the substrate exposed area cutting step is made to be larger than the frequency of the pulse laser in the active substance provided area cutting step, and the lap rate of the pulse laser in the substrate exposed area cutting step is made to be equal to or more than 90%. According to the manufacturing method of the electrode plate as described above, it is possible to inhibit the electrically conductive foreign substance from falling off and being peeled off from the electrode plate that has been already manufactured, and thus it is possible to contribute in improving the safety property of the secondary battery.

An electrode for a lithium-ion battery is disclosed, which comprises: a collector comprising a nano-twinned copper foil; and a negative electrode material disposed on the collector, wherein the negative electrode material comprises at least one selected from the group consisting of: silicon, silicon nitride, graphite, graphene, carbon nanotubes, carbon nano-fibers and carbon nano-particles. In addition, a lithium-ion battery comprising the aforesaid electrode is also provided.

A rechargeable zinc metal battery cell includes a zinc metal anode, a cathode, a porous separator between them, and an electrolyte composition absorbed by the porous separator and in contact with both anode and cathode. The electrolyte composition includes (i) an aqueous solution of zinc chloride at a concentration greater than 15 molal, and (ii) dimethyl carbonate present at a mass ratio between 0.1:1.0 and 1.0:1.0 with respect to water in the aqueous solution. In some examples: the anode includes zinc metal foil stacked on titanium metal foil; the cathode includes vanadium(V) phosphate; the porous separator includes glass fibers and is less than 200 μm thick; or the electrolyte composition includes (i) an aqueous solution of 30 molal zinc chloride, 5 molal lithium chloride, and 10 molal trimethyl ammonium chloride, and (ii) dimethyl carbonate present at a mass ratio of 1.0:1.0 with respect to water in the aqueous solution.

Novel, rechargeable magnesium/magnesium sulfide batteries are disclosed therein, having energy density competitive with lithium batteries, high cycle life, and lower cost. Production method of stabilized MgS is also described, as well as various cells constructions.

An electrode, a battery laminate, a battery and methods of providing the electrode, laminate or battery, where the electrode has an electrode layer and a current collector both having through-going bores of a size allowing liquid transport through the current collector and the electrode layer. The bores are provided by providing elongate slits or weakened portions and deforming the electrode. The current collector also has channels therein allowing liquid to travel along a plane of the current collector. In this manner, the drying of and introduction of electrolyte therein is made much faster.

According to an exemplary embodiment, there is provided a secondary battery in which a value of K.sub.1 represented by the following Expression (1) is 130 to 270:

(200*A.sub.R+C.sub.R+20*C.sub.IR)*(1+C.sub.A)/C.sub.P  (1) in Expression (1), A.sub.R is a bulk resistance (Ω.Math.cm) of the anode, C.sub.R is a bulk resistance (Ω.Math.cm) of the cathode, C.sub.IR is an interfacial resistance (Ω.Math.cm.sup.2) between the cathode active material layer and the cathode current collector, C.sub.P is 1−D/4.7, D is a pressed density (g/cc) of the cathode, and C.sub.A is an adhesive force (N/18 mm) between the cathode active material layer and the cathode current collector.

A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

In general, a solid-state electrode includes an electrode composite layer comprising a plurality of active material particles mixed with a solid electrolyte buffer material comprising a first plurality of solid electrolyte particles layered onto and directly contacting a current collector foil, and an electrically non-conductive separator layer comprising a second plurality of solid electrolyte particles layered onto and directly contacting the electrode composite layer. In some examples, an interpenetrating boundary layer is disposed between the electrode composite layer and the electrically non-conductive separator layer. In some examples, the electrode composite layer includes one or more conductive additives intermixed with the plurality of active material particles, and the electrode composite layer is electrically conductive. In some examples, the electrode composite layer is adhered together by a binder.

An electrochemical cell is provided which includes a cathode, an anode, an electrolyte separator, and an anode current collector located on the anode. The anode is a three-dimensional (3D) porous anode including ionically conducting electrolyte strands and pores which extend through the anode from the anode current collector to the electrolyte separator. The anode also includes electronically conducting networks extending on sidewall surfaces of the pores from the anode current collector to the electrolyte separator.

Self-charging electrochemical cells, including self-charging batteries that incorporate such self-charging electrochemical cells, the electrochemical cells including a cathode including a cathode active material, an electrolyte including a solvent and a salt dissolved in the solvent, the electrolyte being in contact with the cathode, where the cathode active material is transformed into a discharge product during or after a discharge of the self-charging electrochemical cell and a solubility of the cathode active material in the electrolyte is less than a solubility of the discharge product in the electrolyte.