Provided is a bipolar all-solid-state sodium ion secondary battery that can increase the voltage without impairing safety. A bipolar all-solid-state sodium ion secondary battery includes: a plurality of all-solid-state sodium ion secondary batteries 1 in each of which a positive electrode layer 3 capable of absorbing and releasing sodium, a solid electrolyte layer 4 made of a sodium ion-conductive oxide, and a negative electrode layer 5 capable of absorbing and releasing sodium are laid one upon another in this order; and a current collector layer 2 provided between the positive electrode layer 3 of each of the plurality of all-solid-state sodium ion secondary batteries 1 and the negative electrode layer 5 of the adjacent all-solid-state sodium ion secondary battery 1 and shared by the positive electrode layer 3 and the negative electrode layer 5.

A lithium metal electrode has no more than five ppm of non-metallic elements by mass, and is bonded to a conductive substrate. Optionally, the lithium metal electrode may be bonded on one side to a conductive substrate and on another side to a lithium ion selective membrane. The lithium metal electrode may be integrated into lithium metal batteries. The inventive lithium metal electrode may be manufactured by a process involving electrolysis of lithium ions from an aqueous lithium salt solution through an ion selective membrane, carried out under a blanketing atmosphere having no more than 10 ppm of non-metallic elements, the electrolysis being performed at a constant current between about 10 mA/cm.sup.2 and about 50 mA/cm.sup.2, and wherein the constant current is applied for a time between about 1 minute and about 60 minutes.

A carbon-sulfur composite including a carbonized metal-organic framework (MOF); and a sulfur compound introduced to at least a part of an outside surface and an inside of the carbonized metal-organic framework, wherein the carbonized metal-organic framework has a specific surface area of 1000 m.sup.2/g to 4000 m.sup.2/g, and the carbonized metal-organic framework has a pore volume of 0.1 cc/g to 10 cc/g, and a method for preparing the same.

Proposed is a high-capacity anode active material including a primary silicon composite formed such that silicon nanoparticles are dispersed on a first amorphous carbon matrix and a secondary silicon composite formed such that the primary silicon composite is assembled by a network of conductive fibers on a second amorphous carbon matrix. With this structure, contact between the silicon nanoparticles and an electrolyte is prevented so that the anode active material has high capacity and conductivity. A lithium secondary battery including the anode active material is also proposed.

The present invention relates to a method using chemical reaction transparency of graphene, and more specifically to a method capable of forming a desired material by a catalytic reaction on a graphene surface using the graphene which inhibits oxygen diffusion without blocking electron delivery, and an applied method thereof.

The invention relates to a battery electrode foil comprising an aluminium alloy, wherein the aluminium alloy has the following composition in weight percent: Si: 0.07-0.12% by weight, Fe: 0.18-0.24% by weight, Cu: 0.03-0.08% by weight, Mn: 0.015-0.025% by weight, Zn: ≤0.01% by weight, Ti: 0.015-0.025% by weight, Zn: ≤0.01% by weight, Ti: 0.015-0.025% by weight, Mn: 0.015-0.025% by weight, Zn: ≤0.01% by weight, Ti: 0.015-0.025% by weight, wherein the aluminium alloy can contain impurities up to a maximum of 0.01% in each case, up to a maximum of 0.03% in total, but the proportion of aluminium must be at least 99.5% by weight; wherein the battery electrode foil has intermetallic phases of a diameter length of 0.1 to 1.0 μm with a density of ≤9500 particles/mm.sup.2. The invention further relates to a process for the production of a battery electrode foil, its use for the production of accumulators, and accumulators containing the battery electrode foil.

The present invention relates to a three-dimensional structure electrode, a method for manufacturing same, and an electrochemical element including the electrode. The present invention is characterized by comprising: (a) an upper conductive layer and a lower conductive layer which have a structure constituting an assembly within which a conductive material and a porous nonwoven fabric including a plurality of polymeric fibers are three-dimensionally connected in an irregular and continuous manner, thereby forming a mutually connected porous structure; and (b) an active material layer forming the same assembly structure as the conductive layers and forming a three-dimensionally filled structure in which electrode active material particles are uniformly filled inside the mutually connected porous structure formed in the assembly structure, wherein the active material layer is formed between the upper conductive layer and the lower conductive layer.

The present invention provides a thin film forming composition for energy storage device electrodes, said composition containing a conductive carbon material, a dispersant, a solvent and a polymer that has a partial structure represented by formula (P1) in a side chain.

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(In the formula, L represents —O— or —NH—; R represents an alkylene group having from 1 to 20 carbon atoms; T represents a substituted or unsubstituted amino group, a nitrogen-containing heteroaryl group having from 2 to 20 carbon atoms or a nitrogen-containing aliphatic heterocyclic group having from 2 to 20 carbon atoms; and * represents a bonding hand.)

This application relates to a positive electrode plate and an electrochemical device. The positive electrode plate comprises a metal current collector, a positive electrode active material layer and a safety coating disposed between the metal current collector and the positive electrode active material layer; the safety coating comprises a polymer matrix, a conductive material and an inorganic filler; the positive electrode active material layer comprises Li.sub.1+xNi.sub.aCo.sub.bMe.sub.(1−a−b)O.sub.2, wherein −0.1≤x≤0.2, 0.6≤a<1, 0<b<1, 0<(1−a−b)<1, and Me is at least one of Mn, Al, Mg, Zn, Ga, Ba, Fe, Cr, Sn, V, Sc, Ti and Zr; and the metal current collector is a porous aluminum-containing current collector. The positive electrode plate can improve safety and electrical performances of an electrochemical device (such as a capacitor, a primary battery, or a secondary battery).

A method for forming a current collector is provided. At least two carbon nanostructure reinforced copper composite substrates are provided. The at least two carbon nanostructure reinforced copper composite substrates are stacked to form a composite substrate. An active metal layer is disposed on a surface of the composite substrate to form a first a composite structure. The first composite structure is pressed to form a second composite structure. The second composite structure is annealed to form a third composite structure. The third composite structure is de-alloyed to form a porous copper composite.