A method of making an anode for use in an energy storage device includes providing a current collector having an electrically conductive layer and a metal oxide layer overlaying over the electrically conductive layer. The metal oxide layer has an average thickness of at least 0.01 m. A continuous porous lithium storage layer is deposited onto the metal oxide layer by a CVD process. The anode is thermally treated after deposition of the continuous porous lithium storage layer is complete and prior to battery assembly. The thermal treatment includes heating the anode to a temperature in a range of 100 C. to 600 C. for a time period in a range of 0.1 min to 120 min. The anode may be incorporated into a lithium ion battery along with a cathode. The cathode may include sulfur or selenium and the anode may be prelithiated.

An anode for an energy storage device includes a current collector having a metal oxide layer. A continuous porous lithium storage layer overlays the metal oxide layer, and a first supplemental layer overlays the continuous porous lithium storage layer. The first supplemental layer includes silicon nitride, silicon dioxide, or silicon oxynitride. The anode may further include a second supplemental layer overlaying the first supplemental layer. The second supplemental layer has a composition different from the first supplemental layer and may include silicon dioxide, silicon nitride, silicon oxynitride, or a metal compound.

An anode for an energy storage device such as a lithium-ion energy storage device is disclosed. The anode includes a current collector having a metal oxide layer, a first lithium storage layer overlaying the current collector, a first intermediate layer overlaying at least a portion of the first lithium storage layer, and a second lithium storage layer overlaying the first intermediate layer. The first lithium storage layer is a continuous porous lithium storage layer having a total content of silicon, germanium, or a combination thereof, of at least 40 atomic %.

The present application provides an electrode and an electrochemical device comprising the electrode. The electrode comprises a current collector; and an inorganic layer arranged on a surface of the current collector, wherein the inorganic layer comprises a metal oxide and does not comprise a polymer. The electrode of the lithium ion battery provided by the present application has little influence on the volume energy density of the lithium ion battery while improving the safety performance of the lithium ion battery.

A method of making a prelithiated anode for use in a lithium-ion battery includes providing a current collector having an electrically conductive layer and a metal oxide layer overlaying the electrically conductive layer. The metal oxide layer has an average thickness of at least 0.01 m. A continuous porous lithium storage layer is deposited onto the metal oxide layer by a CVD process. Lithium is incorporated into the continuous porous lithium storage layer to form a lithiated storage layer prior to a first electrochemical cycle when the anode is assembled into the battery. The anode may be incorporated into a lithium ion battery along with a cathode. The cathode may include sulfur or selenium and the anode may be prelithiated.

According to an aspect of the present invention, provided is a non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode includes a positive electrode current collector, a positive electrode active material layer which is formed on the positive electrode current collector except for an exposed part of the positive electrode current collector, and an inorganic filler layer formed at a boundary part between the exposed part of the positive electrode current collector and the positive electrode active material layer. A stacking part in which the inorganic filler layer is overlaid with the positive electrode active material layer is formed at the boundary part, and an end surface of the positive electrode active material layer closer to the boundary part is covered with the inorganic filler layer.

A current collector, an electrode plate, and an electrochemical device are provided in the present disclosure. The current collector includes an insulation layer and at least one conductive layer. The insulation layer is used to support the conductive layer. The at least one conductive layer is used to support an electrode active material layer and is located above at least one surface of the insulation layer. The insulation layer has a density smaller than that of the conductive layer. A metal protective layer is arranged on at least one surface of each of the at least one conductive layer.

This positive electrode includes a current collector, an intermediate layer which is formed at least on one surface of the current collector, and a composite material layer which is formed on the intermediate layer. The intermediate layer includes metal compound particles, a conductive material, and a binding material. The metal compound particles comprise at least one selected from a sulfated oxide, hydroxide, or oxide of alkali earth metal or alkali metal.

A monolithic ceramic electrochemical cell housing is provided. The housing includes two or more electrochemical sub cell housings. Each of the electrochemical sub cell housing includes an anode receptive space, a cathode receptive space, a separator between the anode receptive space and the cathode receptive space, and integrated electron conductive circuits. A first integrated electron conductive circuit is configured as an anode current collector within the anode receptive space. A second integrated electron conductive circuit is disposed as a cathode current collector within the cathode receptive space.

Features for rechargeable lithium ion batteries, the batteries optionally employing vertically aligned carbon nanotube scaffolding, are described. Methods of manufacture and a solid polymer electrolyte are described for 3-dimensional battery architectures using the vertically aligned carbon nanotubes. Poly(ethylene)oxide bis(azide) and graphene poly(lactic acid) composite coatings are also described for use in such batteries or others.