A non-aqueous electrolyte secondary battery disclosed herein includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive and negative electrodes each include a current collector and a mixture layer formed on the surface of the current collector. The current collector includes a resin layer and metallic foils provided on both surfaces of the resin layer in at least one of the positive and negative electrodes. A surface of the metallic foils on which the mixture layer is formed is roughened. Furthermore, the average X (μm) of the thicknesses at the thinnest parts and the average Y (μm) of the thicknesses at the thickest parts of the metallic foil determined based on a plurality of obtained sectional SEM images in a stacked direction of the resin layer and the metallic foils satisfy the following relationship: 0.1 μm<X<4 μm, and 1.2≤Y/X.

This disclosure provides a method for preparing a current collector. The method includes: (1) anchoring vinyl groups onto the surface of textiles through the silanization between hydroxyl groups and coupling agents; (2) synthesizing polyelectrolyte brushes through in-situ radical polymerization; and (3) obtaining catalyst ions on the polyelectrolyte brushes through ion-exchange and obtaining metal-coated layers through subsequent electroless deposition). The current collector according to the present disclosure has high electrical conductivity and excellent mechanical flexibility, and thus the lithium ion battery including the same is suitable for portable and wearable electronic devices.

An electrically conductive porous composite composed of an expanded microsphere matrix binding a material composition having electrical conductivity properties to form an electrically conductive porous composite is disclosed herein. An energy storage device incorporating the electrically conductive porous composite is also disclosed herein.

This application provides a lithium secondary battery and a negative electrode plate for the lithium secondary battery. The negative electrode plate includes a negative electrode current collector and a negative electrode active material layer disposed on at least one surface of the negative electrode current collector, where a surface of the negative electrode active material layer closer to the current collector is provided with an elastic coating. And the elastic coating includes an elastic polymer and a conductive agent. At a pressure of 1 MPa to 20 MPa, the elastic coating has a compression deformation of 20% to 80% and an elastic modulus of 1 MPa to 800 MPa. And optionally, at the pressure of 1 MPa to 20 MPa, the elastic coating has a compression deformation of 30% to 60% and an elastic modulus of 5 MPa to 100 MPa.

There is provided a lithium ion battery having a current collector and an electrode composition layer formed on a surface of the current collector, where the electrode composition layer contains coated electrode active material particles, each of which is obtained by coating at least a part of a surface of an electrode active material particle with a coating layer containing a polymer compound, the current collector has a conductive base material and a conductive composition layer containing a polymer compound and a conductive filler, on a surface of the conductive base material, the surface being in contact with the electrode composition layer, and the polymer compound contained in the conductive composition layer and the polymer compound contained in the coating layer have the same composition.

A current collector for a lithium ion battery includes a first conductive resin layer and a second conductive resin layer. The first conductive resin layer includes a first conductive filler. The second conductive resin layer is formed on the first conductive resin layer and includes a second conductive filler. The first conductive filler is a conductive carbon. The second conductive filler contains at least one kind of metal element selected from the group consisting of platinum, gold, silver, copper, nickel, and titanium. A volume % of the second conductive filler in the second conductive resin layer on a first surface side, which is a first conductive resin layer side, is higher than that on the second surface side that is opposite to the first conductive resin layer.

The present disclosure relates to high capacity (e.g., areal capacity greater than about 4 mAh/cm.sup.2 to less than or equal to about 50 mAh/cm.sup.2) electrodes for electrochemical cells. An example electrode may include a current collector (e.g., meshed current collector) and one or more electroactive material layers having thicknesses greater than about 150 μm to less than or equal to about 5 mm. The electroactive material layers may each include lithium manganese iron phosphate (LiMn.sub.xFe.sub.1-xPO.sub.4, where 0≤x≤1) (LMFP). The electrode may further include one or more electronically conductive adhesive layers disposed between the current collector and the electroactive material layers. The adhesive layers may include one or more polymer components and one or more conductive fillers. The electroactive material layers may be gradient layers, where sublayers closer to the current collector has a lower porosity than layers further from the current collector.

The present application relates to a positive electrode plate, an electrochemical device and a safety coating. The positive electrode plate comprises a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating comprising a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix, a conductive material and an inorganic filler. The positive electrode plate can quickly disconnect circuit when the electrochemical device (such as a capacitor, primary battery, or secondary battery, and the like) is in a high temperature condition or an internal short circuit occurs, thereby improving high temperature safety performance of the electrochemical device.

A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolyte provided between the positive electrode and the negative electrode. The positive electrode includes a positive electrode current collector and a positive electrode active material layer over the positive electrode current collector. The positive electrode active material layer includes a plurality of lithium-containing composite oxides each of which is expressed by LiMPO.sub.4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) that is a general formula. The lithium-containing composite oxide is a flat single crystal particle in which the length in the b-axis direction is shorter than each of the lengths in the a-axis direction and the c-axis direction. The lithium-containing composite oxide is provided over the positive electrode current collector so that the b-axis of the single crystal particle intersects with the surface of the positive electrode current collector.

A catholyte-like material including a cathode material and an interfacial additive layer for providing a lithium ion energy storage device having low impedance is disclosed. The interfacial additive layer, which is composed of vapor deposited iodine, is present between the cathode material and an electrolyte layer of the device. The presence of such an interfacial additive layer increases the ion and electron mobile dependent performances at the cathode material interface due to significant decrease in the resistance/impedance that is observed at the respective interface as well as the impedance observed in the bulk of the device. The catholyte-like material of the present application can be used to provide a lithium ion energy storage device having high charge/discharge rates and/or high capacity.