An electrode structure of a flow battery, a flow battery stack, and a sealing structure of the flow battery stack, wherein the density of the vertical tow in the electrode fiber is larger than the density of the parallel tow. In the electrode fiber per unit volume, the quantity ratio of the vertical tow to the parallel tow is at least 6:4. The electrode structure is composed of an odd number of layers of the electrode fibers, and the porosity of other layers is larger than the porosity of the center layer. The electrode structure is mainly composed of the vertical tows perpendicular to the surface of the electrode, so that, firstly, the contact area between the outer surface of the electrode and the adjacent component can be increased and the contact resistance can be reduced, secondly, the electrode is endowed with good mechanical properties, compared with the original structure, the contact resistance of such structure is reduced by 30%-50%; and the layers of the electrode have different thickness depending on the porosity, after compression, the layers with optimized thickness have a consistent porosity, this compressed uniform structure avoids uneven mass transfer phenomena when the electrolyte flows through the electrode, and reduces the concentration polarization of the battery and thereby improving the battery energy output under the given power.

An electrode structure of a flow battery, a flow battery stack, and a sealing structure of the flow battery stack, wherein the density of the vertical tow in the electrode fiber is larger than the density of the parallel tow. In the electrode fiber per unit volume, the quantity ratio of the vertical tow to the parallel tow is at least 6:4. The electrode structure is composed of an odd number of layers of the electrode fibers, and the porosity of other layers is larger than the porosity of the center layer. The electrode structure is mainly composed of the vertical tows perpendicular to the surface of the electrode, so that, firstly, the contact area between the outer surface of the electrode and the adjacent component can be increased and the contact resistance can be reduced, secondly, the electrode is endowed with good mechanical properties, compared with the original structure, the contact resistance of such structure is reduced by 30%-50%; and the layers of the electrode have different thickness depending on the porosity, after compression, the layers with optimized thickness have a consistent porosity, this compressed uniform structure avoids uneven mass transfer phenomena when the electrolyte flows through the electrode, and reduces the concentration polarization of the battery and thereby improving the battery energy output under the given power.

A thread battery that includes: a thread-like solid electrolyte that extends in a longitudinal direction between a first end and a second end that face each other in the longitudinal direction; a first electrode on a first part of an outer peripheral surface of the solid electrolyte along the longitudinal direction; a second electrode on a second part of the outer peripheral surface of the solid electrolyte along the longitudinal direction, wherein the first electrode and the second electrode do not contact each other; a first current collector on an outer peripheral surface of the first electrode along the longitudinal direction; and a second current collector on an outer peripheral surface of the second electrode along the longitudinal direction.

A method of manufacturing an electrochemical system comprising an electrode is described herein, comprising dispensing, in a configured pattern corresponding to the shape of the electrode, a model composition which comprises a substance capable of reversibly releasing an electrochemically-active agent (such as lithium) or depleted form of same, wherein dispensing comprises heating a filament comprising the model composition and dispensing a heated composition. Further described is an electrochemical system comprising an electrode which comprises a composite material, as well as batteries and supercapacitors comprising such a system. The composite material comprises a thermoplastic polymer and substance capable of reversibly releasing an electrochemically-active agent (such as lithium) or depleted form of same, wherein at least 20 weight percents of the composite material is thermoplastic polymer.

Molten lithium electrochemical cells are disclosed. A solid electrolyte separates a molten lithium metal or molten lithium metal alloy from a cathode. The molten lithium cells provide high Coulombic efficiency and energy efficiency at operating temperatures less than 600 C. The cells are useful for stationary energy storage in power grids.

Molten lithium electrochemical cells are disclosed. A solid electrolyte separates a molten lithium metal or molten lithium metal alloy from a cathode. The molten lithium cells provide high Coulombic efficiency and energy efficiency at operating temperatures less than 600 C. The cells are useful for stationary energy storage in power grids.

A secondary battery includes a first electrode; a first active material fluid which is electrically connected to the first electrode, contains a first active material and a supporting salt, and is flowable; and a second electrode including a structure which is formed by containing a second active material, the structure either being immersed in the first active material fluid or holding the first active material fluid, and a separating membrane disposed between the first active material fluid and the structure, the separating membrane having ion conducting properties and insulating properties.

A secondary battery includes a first electrode; a first active material fluid which is electrically connected to the first electrode, contains a first active material and a supporting salt, and is flowable; and a second electrode including a structure which is formed by containing a second active material, the structure either being immersed in the first active material fluid or holding the first active material fluid, and a separating membrane disposed between the first active material fluid and the structure, the separating membrane having ion conducting properties and insulating properties.

A secondary lithium ion cell includes an electrode-separator assembly in the form of a winding with two terminal end faces. The electrode separator assembly comprising an anode, a cathode, and a separator. The anode comprises an anode current collector comprising a first longitudinal edge, a second longitudinal edge, a strip-shaped main region, and a free edge strip extending along the first longitudinal edge. The strip shaped main region of the anode current collector is loaded with a layer of negative electrode material and the free edge strip of the anode current collector is not loaded with the negative electrode material. The layer of negative electrode material comprises metallic lithium. The cathode comprises a cathode current collector comprising a first longitudinal edge, a second longitudinal edge, a strip-shaped main region, and a free edge strip extending along the first longitudinal edge.

A secondary lithium ion cell includes an electrode-separator assembly in the form of a winding with two terminal end faces. The electrode separator assembly comprising an anode, a cathode, and a separator. The anode comprises an anode current collector comprising a first longitudinal edge, a second longitudinal edge, a strip-shaped main region, and a free edge strip extending along the first longitudinal edge. The strip shaped main region of the anode current collector is loaded with a layer of negative electrode material and the free edge strip of the anode current collector is not loaded with the negative electrode material. The layer of negative electrode material comprises metallic lithium. The cathode comprises a cathode current collector comprising a first longitudinal edge, a second longitudinal edge, a strip-shaped main region, and a free edge strip extending along the first longitudinal edge.