The all-solid battery includes: a cathode layer including a cathode active material layer, an anode layer, and a solid electrolyte layer that is disposed between the cathode layer and the anode layer and includes a solid electrolyte, wherein the anode layer includes a porous anode current collector; a first anode active material layer including a first metal and a carbonaceous anode active material disposed on the porous anode current collector; a conformal coating layer including a second metal disposed on the first anode active material layer, wherein the conformal coating layer of the anode layer is between the first anode active material layer and the solid electrolyte layer, and a surface roughness of the solid electrolyte layer, proximate to the conformal coating layer, is about 2 micrometers or less.

The all-solid battery includes: a cathode layer including a cathode active material layer, an anode layer, and a solid electrolyte layer that is disposed between the cathode layer and the anode layer and includes a solid electrolyte, wherein the anode layer includes a porous anode current collector; a first anode active material layer including a first metal and a carbonaceous anode active material disposed on the porous anode current collector; a conformal coating layer including a second metal disposed on the first anode active material layer, wherein the conformal coating layer of the anode layer is between the first anode active material layer and the solid electrolyte layer, and a surface roughness of the solid electrolyte layer, proximate to the conformal coating layer, is about 2 micrometers or less.

This disclosure provides an electrode having a carbon-based structure with a plurality of localized reaction sites. An open porous scaffold is defined by the carbon-based structure and can confine an active material in the localized reaction sites. A plurality of engineered failure points is formed throughout the carbon-based structure and can expand in a presence of volumetric expansion associated with polysulfide shuttle. The open porous scaffold can inhibit a formation of interconnecting solid networks of the active material between the localized reaction sites. The plurality of engineered failure points can relax or collapse during an initial activation of the electrode. The open porous scaffold can define a hierarchical porous compliant cellular architecture formed of a plurality of interconnected graphene platelets fused together at substantially orthogonal angles. The hierarchical porous compliant cellular architecture can be expansion-tolerant and can expand in a presence of Li ion insertion or de-insertion.

Alkali metal secondary batteries that include anodes constructed from alkali metal foil applied to only one side of a porous current collector metal foil. Openings in the porous current collectors permit alkali metal accessibility on both sides of the anode structure. Such anode constructions enable the utilization of lower-cost and more commonly available alkali metal foil thickness, while still achieving high cell cycle life at a significantly reduced cost. Aspects of the present disclosure also include batteries with porous current collectors having increased volumetric and gravimetric energy densities, and methods of manufacturing anodes with porous current collectors.

Alkali metal secondary batteries that include anodes constructed from alkali metal foil applied to only one side of a porous current collector metal foil. Openings in the porous current collectors permit alkali metal accessibility on both sides of the anode structure. Such anode constructions enable the utilization of lower-cost and more commonly available alkali metal foil thickness, while still achieving high cell cycle life at a significantly reduced cost. Aspects of the present disclosure also include batteries with porous current collectors having increased volumetric and gravimetric energy densities, and methods of manufacturing anodes with porous current collectors.

Provided is a current collector 30, including a metal foil 5 having a plurality of first through holes 5a, a metal oxide film 15 formed on a top or bottom surface of the metal foil 5, and a conductive layer 25 formed on a top or bottom surface of the metal oxide film 15. The plurality of first through holes 5a is filled with a conductive connection member 10 to form the metal foil 5. The metal oxide film 15 is formed to have second through holes 15a at locations corresponding to the plurality of first through holes 5a, respectively, on the top or bottom surface of the metal foil 5. The conductive layer 25 is formed to have a third through hole 25a at a location corresponding to each of the second through holes 15a on a top or bottom surface of the metal oxide film 15.

Provided is a current collector 30, including a metal foil 5 having a plurality of first through holes 5a, a metal oxide film 15 formed on a top or bottom surface of the metal foil 5, and a conductive layer 25 formed on a top or bottom surface of the metal oxide film 15. The plurality of first through holes 5a is filled with a conductive connection member 10 to form the metal foil 5. The metal oxide film 15 is formed to have second through holes 15a at locations corresponding to the plurality of first through holes 5a, respectively, on the top or bottom surface of the metal foil 5. The conductive layer 25 is formed to have a third through hole 25a at a location corresponding to each of the second through holes 15a on a top or bottom surface of the metal oxide film 15.

To provide a solid-state battery having high safety and high energy density. An electrode for a solid-state battery includes a current collector that is a metal porous body, and an electrode material mixture with which the current collector is filled. The current collector has an end portion having a material mixture non-filled region that is not filled with the electrode material mixture. The material mixture non-filled region has a part that is a fuse function portion. The fuse function portion has a smaller total cross-sectional area of metal in a cross section perpendicular to a direction of the end portion than the rest of the material mixture non-filled region.

To provide a solid-state battery having high safety and high energy density. An electrode for a solid-state battery includes a current collector that is a metal porous body, and an electrode material mixture with which the current collector is filled. The current collector has an end portion having a material mixture non-filled region that is not filled with the electrode material mixture. The material mixture non-filled region has a part that is a fuse function portion. The fuse function portion has a smaller total cross-sectional area of metal in a cross section perpendicular to a direction of the end portion than the rest of the material mixture non-filled region.

An all-solid-state battery is provided. The all-solid-battery comprises a positive electrode, a negative electrode including a negative electrode current collector having a porous structure, a solid electrolyte layer located between the positive electrode and the negative electrode, a stopper disposed at an outer periphery of the negative electrode, a battery case, and a pressing member, and has improved safety due to inhibition of lithium dendrite formation.