Disclosed are an anode for a lithium secondary battery including a porous and thin-film anode current collector layer and a method for manufacturing the same.

Disclosed are an anode for a lithium secondary battery including a porous and thin-film anode current collector layer and a method for manufacturing the same.

A method for preparing an ultrathin Li complex includes the steps of preparing an organic transition layer on a substrate in advance, and contacting the substrate having transition layer with molten Li in argon atmosphere with H.sub.2O≤0.1 ppm and O.sub.2≤0.1 ppm. The molten Li spreads rapidly on the surface of the substrate to form a lithium thin layer. The ultrathin Li layer stores lithium on the current collector beforehand. It can be used as a safe lithium anode to inhibit dendrites.

Alkali metal secondary batteries that include anodes constructed from alkali metal foil applied to only one side of a porous current collector metal foil. Openings in the porous current collectors permit alkali metal accessibility on both sides of the anode structure. Such anode constructions enable the utilization of lower-cost and more commonly available alkali metal foil thickness, while still achieving high cell cycle life at a significantly reduced cost. Aspects of the present disclosure also include batteries with porous current collectors having increased volumetric and gravimetric energy densities, and methods of manufacturing anodes with porous current collectors.

Alkali metal secondary batteries that include anodes constructed from alkali metal foil applied to only one side of a porous current collector metal foil. Openings in the porous current collectors permit alkali metal accessibility on both sides of the anode structure. Such anode constructions enable the utilization of lower-cost and more commonly available alkali metal foil thickness, while still achieving high cell cycle life at a significantly reduced cost. Aspects of the present disclosure also include batteries with porous current collectors having increased volumetric and gravimetric energy densities, and methods of manufacturing anodes with porous current collectors.

A composite negative electrode structure includes a current collecting layer, a porous layer, a plurality of lithiophilic structures, and a solid-state electrolyte layer. The porous layer is located on a surface of the current collecting layer and includes a plurality of pores. The lithiophilic structures are located on the surface of the current collecting layer and accommodated in some of the pores. The solid-state electrolyte layer is located on the porous layer.

A composite negative electrode structure includes a current collecting layer, a porous layer, a plurality of lithiophilic structures, and a solid-state electrolyte layer. The porous layer is located on a surface of the current collecting layer and includes a plurality of pores. The lithiophilic structures are located on the surface of the current collecting layer and accommodated in some of the pores. The solid-state electrolyte layer is located on the porous layer.

An innovative fuel cell system with membrane electrode assemblies (MEAs) includes a polymer electrolyte membrane, a gas diffusion layer (GDL) made of porous metal foam, and a catalyst layer. A fuel cell has a metal foam layer that improves efficiency and lifetime of the conventional gas diffusion layer, which consists of both gas diffusion barrier (GDB) and microporous layer (MPL). This metal foam GDL enables consistent maintenance of the suitable structure and even distribution of pores during the operation. Due to the combination of mechanical and physical properties of metallic foam, the fuel cell is not deformed by external physical strain. Among many other processing methods of open-cell metal foams, ice-templating provides a cheap, easy processing route suitable for mass production. Furthermore, it provides well-aligned and long channel pores, which improve gas and water flow during the operation of the fuel cell.

Novel, high voltage cathode active materials for non-aqueous ammonia based primary and reserve batteries are described therein, as well as non-aqueous electrolytes supporting high voltage, and various anodes, separators and cell constructions are disclosed. Said materials provide higher power output at low temperatures over prior art ammonia based batteries.

A secondary battery and a method for making the same are disclosed. The secondary battery includes a battery negative electrode, an electrolyte liquid, a diaphragm and a battery positive electrode. The battery negative electrode includes a negative electrode current collector, which also acts as a negative electrode active material. The electrolyte liquid includes an electrolyte and a solvent, the electrolyte being a lithium salt. The battery positive electrode includes a positive electrode current collector and a positive electrode active material layer, which includes a positive electrode active material capable of reversibly de-intercalating lithium ions.