The present disclosure provides a method for preparing a supported metal alloy catalyst for low temperature engine exhaust oxidation without CO or NO inhibition. The catalyst includes bimetallic PdCu alloy deposited on a SiO.sub.2 support using the strong electrostatic adsorption method. The PdCu catalyst may be combined with a traditional PGM-based automotive oxidation catalyst in a series or dual-bed configuration. The first stage of the dual-bed system includes the PdCu catalyst, with the primary role of oxidizing CO at low temperature; the PGM-based catalyst in the second stage then oxidizes NO and hydrocarbons in the absence of any CO-inhibition effects.

A fuel cell catalyst including a conductive carrier and core-shell nanoparticles supported on the carrier. The core includes platinum and a transition metal and the shell includes a secondary metal. An electrochemical specific activity measured at a voltage of 0.05 V to 1.05 V (vs. RHE) in a potential range, at a scan rate of 5 mV/s and a rotation rate of 1,600 rpm in an O.sub.2-saturated 0.1 M HClO.sub.4 electrolyte solution is 0.3 mA/cm2 to 0.6 mA/cm2, and a mass activity is 0.05 mA/μg to 0.08 mA/μg.

The present invention provides a catalysed decal transfer substrate comprising a decal transfer substrate, an electrocatalyst later, and a layer D between the decal transfer substrate and the electrocatalyst layer which comprises an ion-conducting polymer and a carbon material. The layer D is configured such that, upon transfer of the electrocatalyst layer to a surface, at least a portion of the layer D remains attached to and is transferred with the electrocatalyst layer.

Electrocatalysts and methods of forming the same are provided. A hybrid electrocatalyst can be a combination of a platinum (Pt)-based catalyst and a carbon-based non-precious-metal catalyst using a single atom approach. A fuel cell electrocatalyst can include a nitrogen-doped carbon support and a plurality of atoms of both Pt and of a non-precious-metal catalyst dispersed in the support. The dispersed atoms can be isolated from each other within the support.

A carbon monoxide (CO) tolerant membrane electrode assembly (MEA) includes an ionically-conductive proton exchange membrane, an anode contacting a first side of the membrane and including a hydrophobic bonding agent, an ionomer bonding agent, first catalyst particles, second catalyst particles, and an anode gas diffusion layer (GDL), a cathode contacting a second side of the membrane and including a cathode GDL. The first catalyst particles are configured to preferentially catalyze oxidation of CO, and the second catalyst particles are configured to preferentially catalyze generation of hydrogen ions.

Disclosed are an electrode including a polymer matrix and a catalyst including metal nanoparticles and a conductive polymer shell and, a method of preparing the same. According to various exemplary embodiments of the present invention, various hybrid nano-composites may be formed by a combination of other conductive polymers than P3HT with metal nanoparticles. For example, the method may include selectively disposing metal nanoparticles to a surface modified conductive polymer including a block copolymer of two or more types of conductive polymers.

The present disclosure is directed to compositions and structures of supported metal catalysts for use in applications such as direct methanol fuel cells. Generally, implementations include supported metal catalysts that include Pt active sites that have been modified by addition or co-localization of a second metal such as Cu, Co, Ni, and/or other base metals to lower the inhibiting effect of strongly-adsorbed CO, an intermediate of methanol oxidation. An example aspect of the present disclosure includes catalyst compositions where the exterior metal sites in the supported catalyst include at least two metals: Pt and a competitive binder (e.g., a second metal).

The present invention relates to a transition metal nitride support, a method of manufacturing the same, a metal catalyst and a platinum-alloy catalyst including the transition metal nitride support, and manufacturing methods thereof. The manufactured transition metal support prevents corrosion of the support and aggregation of the platinum catalyst, thereby exhibiting high oxygen reduction catalytic activity. Also, strong metal-support interaction (SMSI) can be stabilized, thus improving the durability of the catalyst. The transition metal support includes large pores uniformly distributed therein, thereby increasing the amount of the catalyst supported and minimizing mass-transfer resistance in a membrane- electrode assembly, increasing the performance of a polymer electrolyte membrane fuel cell. The metal catalyst includes platinum particles loaded on the transition metal nitride support, thus exhibiting superior durability and activity. The manufactured platinum-alloy catalyst decreases the use of expensive platinum, thus generating economic benefits and improving the inherent oxygen reduction performance.

A catalyst including: a carbon support doped with a nitrogen atom and a first transition metal atom; and a plurality of fine particles containing a noble metal and supported on the carbon support. The fine particles have an average particle size of 0.8 nm or more and 1.5 nm or less.

The present disclosure relates to a catalyst for a fuel cell, a fuel cell including the same and a method for preparing the catalyst for a fuel cell. More specifically, the catalyst for a fuel cell according to the present disclosure can exhibit superior catalytic activity as compared to the existing catalyst even when the catalyst metal is used at a very low content because some metal of the metal nanoparticles distributed on a carbon support is replaced with catalyst metal single atoms.