The purpose of the present invention is to provide: a method for producing a gas diffusion electrode base which enables the achievement of a gas diffusion electrode base that has a microporous layer with small surface roughness and is not susceptible to damaging an electrolyte membrane; and a gas diffusion electrode base that has a microporous layer with small surface roughness and is not susceptible to damaging an electrolyte membrane. For the purpose of achieving the above-described purpose, the present invention has the configuration described below. Namely, a specific gas diffusion electrode base which has a carbon sheet and a microporous layer, and wherein the carbon sheet is porous and the DBP oil absorption of a carbon powder contained in the microporous layer is 70-155 ml/100 g.

A layered structure for a fuel cell comprises a carbon-based catalyst-free gas diffusion layer substrate and a carbon-based microporous layer, which is joined to the gas diffusion layer substrate and comprises a plurality of carbon carriers or carbon fibers embedded into an ion-conducting polymer binder mixture. The polymer binder mixture comprises a sulfur-free binding polymer and a sulfonated polymer, and a fraction of the binding polymer at or near a surface of the microporous layer facing away from the gas diffusion layer substrate is less than or equal to a fraction of the sulfonated polymer. A method for producing a layered structure of this type is also provided.

A layered structure for a fuel cell comprises a carbon-based catalyst-free gas diffusion layer substrate and a carbon-based microporous layer, which is joined to the gas diffusion layer substrate and comprises a plurality of carbon carriers or carbon fibers embedded into an ion-conducting polymer binder mixture. The polymer binder mixture comprises a sulfur-free binding polymer and a sulfonated polymer, and a fraction of the binding polymer at or near a surface of the microporous layer facing away from the gas diffusion layer substrate is less than or equal to a fraction of the sulfonated polymer. A method for producing a layered structure of this type is also provided.

A battery includes a cathode compartment, a catholyte solution disposed within the cathode compartment, an anode compartment, an anolyte solution disposed within the anode compartment, a separator disposed between the cathode compartment and the anode compartment, and a flow system configured to provide fluid circulation in the cathode compartment and the anode compartment. The catholyte solution and the anolyte solution have different compositions.

A gas diffusion electrode including: a conductive porous substrate and a microporous layer on at least one side of the conductive porous substrate; in which the total of regions passing through the microporous layer in the thickness direction has an area ratio of 0.1% or more and 1% or less; and in which the microporous layer has a portion that has penetrated into the conductive porous substrate (hereinafter referred to as penetration portion), the penetration portion having a thickness ratio of 30% or more and 70% or less with respect to 100% of the thickness of the microporous layer. The gas diffusion electrode used for fuel cells affords fuel cells having high water removal performance and high power generation performance.

A gas diffusion electrode including: a conductive porous substrate and a microporous layer on at least one side of the conductive porous substrate; in which the total of regions passing through the microporous layer in the thickness direction has an area ratio of 0.1% or more and 1% or less; and in which the microporous layer has a portion that has penetrated into the conductive porous substrate (hereinafter referred to as penetration portion), the penetration portion having a thickness ratio of 30% or more and 70% or less with respect to 100% of the thickness of the microporous layer. The gas diffusion electrode used for fuel cells affords fuel cells having high water removal performance and high power generation performance.

A fuel cell gas supply and diffusion layer includes a sheet-like porous body layer, and a plurality of gas passage grooves formed on one surface of the porous body layer in parallel and formed in a zigzag shape or a wave shape respectively. As viewed in a plan view, a first rectangular region where circumscribes one gas passage groove and a second rectangular region where circumscribes a gas passage groove adjacent to the one gas passage groove overlap along a region in contact each other. An overlapping region where the first rectangular region and the second rectangular region overlap exists at any depth position of the grooves. According to the fuel cell gas supply and diffusion layer, it is possible to increase a power generation efficiency of a fuel cell.

A fuel cell gas supply and diffusion layer includes a sheet-like porous body layer, and a plurality of gas passage grooves formed on one surface of the porous body layer in parallel and formed in a zigzag shape or a wave shape respectively. As viewed in a plan view, a first rectangular region where circumscribes one gas passage groove and a second rectangular region where circumscribes a gas passage groove adjacent to the one gas passage groove overlap along a region in contact each other. An overlapping region where the first rectangular region and the second rectangular region overlap exists at any depth position of the grooves. According to the fuel cell gas supply and diffusion layer, it is possible to increase a power generation efficiency of a fuel cell.

The present invention provides carbon-nanotube (CNT)-polymer-metal composite substrate products, each product including a first current collector including at least one carbon nanotube (CNT) mat and a high conducting metallic element in electrical connection with a first tab, the high conducting metallic element bound to the at least one carbon nanotube mat, and optionally including a second current collector including a metallic conducting element in electrical connection with a second tab, a separator material separating between the first and second current collectors, an electrolyte solution disposed between the first collector and the second collector and a housing configured to house the first collector, second collector, separator material electrolyte solution and active material.

In the present invention, a water-based wetting dispersant having an acid value of 5 mg KOH/g or more and an amine value of 10 mg KOH/g or less is used to dilute and disperse black carbon and a hydrophobic fluorine resin in an organic solvent to manufacture a slurry for microporous layer formation. In this regard, the added amount of the water-based wetting dispersant is adjusted to 5 to 30 parts by weight on the basis of 100 parts by weight of black carbon. In the present invention, the slurry is applied to at least one surface of carbon fiber paper and dried to form a microporous layer in which two independent peaks appear as analyzed on a particle size graph, followed by compression and deposition thereof to fabricate a gas diffusion layer including the microporous layer in which two independent peaks appear as analyzed on a particle size graph. With the appearance of two independent peaks on a particle size analysis graph, the gas diffusion layer of the present invention has an excellent drainage function, thereby increasing in the current value of the concentration polarization curve at the equivalent voltage value.