Batteries having a metal interlayer that acts as an ion conductor are provided, as well as methods of forming the same. The metal interlayer can include, for example, palladium, platinum, iridium, rhodium, ruthenium, osmium, gold, silver, or a combination thereof, and can act as a conductor while also inhibiting the transport of other species that would produce byproduct films and cause capacity degradation in the battery.

Batteries having a metal interlayer that acts as an ion conductor are provided, as well as methods of forming the same. The metal interlayer can include, for example, palladium, platinum, iridium, rhodium, ruthenium, osmium, gold, silver, or a combination thereof, and can act as a conductor while also inhibiting the transport of other species that would produce byproduct films and cause capacity degradation in the battery.

Provided is a pouch type secondary battery including a jelly roll in which a plurality of unit cells including a structure of a separator interposed between a positive electrode and a negative electrode are laminated, wherein a unit cell positioned in an outermost layer of the jelly roll includes a carbon dioxide adsorbent.

Novel or improved microporous single or multilayer battery separator membranes, separators, batteries including such membranes or separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries are provided. In accordance with at least certain embodiments, a multilayer dry process polyethylene/polypropylene/polyethylene microporous separator which is manufactured using the inventive process which includes machine direction stretching followed by transverse direction stretching and a subsequent calendering step as a means to reduce the thickness of the multilayer microporous membrane, to reduce the percent porosity of the multilayer microporous membrane in a controlled manner and/or to improve transverse direction tensile strength. In a very particular embodiment, the inventive process produces a thin multilayer microporous membrane that is easily coated with polymeric-ceramic coatings, has excellent mechanical strength properties due to its polypropylene layer or layers and a thermal shutdown function due to its polyethylene layer or layers. The ratio of the thickness of the polypropylene and polyethylene layers in the inventive multilayer microporous membrane can be tailored to balance mechanical strength and thermal shutdown properties.

A one-step molded lithium ion battery separator and preparation method and application thereof are provided. The battery separator comprises a support layer and a filler layer. The support layer comprises at least two of superfine main fiber, thermoplastic bonded fiber and first nanofiber, and the filler layer comprises at least one of inorganic fillers and third nanofiber. The lithium ion battery separator has a thickness of 19-31 μm, a maximum pore diameter of no more than 1 μm, and a heat shrinkage rate of less than 3% after treatment at 300° C. for 1 hour, and the separator still has a certain strength at a high temperature, ensuring stability and isolation of the rigid structure of the filler layer at a high temperature, satisfying requirements of the separator in terms of heat resistance, pore size and strength, having excellent comprehensive performance.

A one-step molded lithium ion battery separator and preparation method and application thereof are provided. The battery separator comprises a support layer and a filler layer. The support layer comprises at least two of superfine main fiber, thermoplastic bonded fiber and first nanofiber, and the filler layer comprises at least one of inorganic fillers and third nanofiber. The lithium ion battery separator has a thickness of 19-31 μm, a maximum pore diameter of no more than 1 μm, and a heat shrinkage rate of less than 3% after treatment at 300° C. for 1 hour, and the separator still has a certain strength at a high temperature, ensuring stability and isolation of the rigid structure of the filler layer at a high temperature, satisfying requirements of the separator in terms of heat resistance, pore size and strength, having excellent comprehensive performance.

The present application relates to a separator, comprising a substrate and a coating formed on at least one surface of the substrate; wherein the coating comprises inorganic particles and organic particles, the organic particles comprise first organic particles and second organic particles; the first organic particles and the second organic particles are embedded in the inorganic particles and form protrusions on the surface of the coating; the first organic particles have a number-average particle size of >10 μm, and the second organic particles have a number-average particle size of 2 μm-10 μm. The present application also relates to a secondary battery comprising the separator, a device comprising the secondary battery and a method for preparing the separator.

Lithium ion-exchanged zeolite particles and methods of making such lithium ion-exchanged zeolite particles are provided herein. The method includes combining precursor zeolite particles with (NH.sub.4).sub.3PO.sub.4 to form a first mixture including intermediate zeolite particles including NH.sub.4.sup.+ cations. The method further includes adding a lithium salt to the first mixture to form the lithium ion-exchanged zeolite particles, or separating the intermediate zeolite particle from the first mixture and combining the intermediate zeolite particles with the lithium salt to form the lithium ion-exchanged zeolite particles.

Lithium ion-exchanged zeolite particles and methods of making such lithium ion-exchanged zeolite particles are provided herein. The method includes combining precursor zeolite particles with (NH.sub.4).sub.3PO.sub.4 to form a first mixture including intermediate zeolite particles including NH.sub.4.sup.+ cations. The method further includes adding a lithium salt to the first mixture to form the lithium ion-exchanged zeolite particles, or separating the intermediate zeolite particle from the first mixture and combining the intermediate zeolite particles with the lithium salt to form the lithium ion-exchanged zeolite particles.

Disclosed herein are a multilayer separator for a lithium secondary battery capable of preventing an internal short-circuit due to growth of lithium dendrite, and a method of manufacturing the same.