A composite including: at least one selected from a silicon oxide of the formula SiO.sub.2 and a silicon oxide of the formula SiO.sub.x wherein 0<x<2; and graphene, wherein the silicon oxide is disposed in a graphene matrix.

A composite including: at least one selected from a silicon oxide of the formula SiO.sub.2 and a silicon oxide of the formula SiO.sub.x wherein 0<x<2; and graphene, wherein the silicon oxide is disposed in a graphene matrix.

A composite including: at least one selected from a silicon oxide of the formula SiO.sub.2 and a silicon oxide of the formula SiO.sub.x wherein 0<x<2; and graphene, wherein the silicon oxide is disposed in a graphene matrix.

Devices and methods are provided for the low-cost manufacturing of thermoelectric power-generation devices (thermopiles) using stable, common materials that can function at very high temperatures. An improved geometry for thermocouple elements in the assembly provides for incorporating a large number of thermocouples. The geometry includes holes and cross-channels in an electrically-insulative device body comprising a material such as a ceramic or glass whereby thermocouple material may be deposited and the device heated to sinter or melt the deposited thermocouple material to form a thermopile. Also provided is a thermopile assembly wherein substrates formed by 3D printing or otherwise are stacked to create the thermopile. These device geometries and manufacturing procedures enable the low-cost production of thermopiles comprised of a massive number of thermocouple elements, from hundreds to hundreds of thousands or more, for electrical power generation using common, standard metallic thermocouple materials and common, widely used electrical insulation materials.

Provided is a thermoelectric material having an intermetallic compound in an AlFeSi system as a main component, exhibiting a thermoelectric effect in a temperature range from a room temperature to 600 C., and becoming a p-type or n-type thermoelectric material by a composition control, a manufacturing method thereof, and a thermoelectric power generation module thereof. A thermoelectric material according to the present invention including at least Al, Fe, and Si and represented by a general formula of Al.sub.22+pqFe.sub.38.5+3qSi.sub.49.5p2q (where p satisfies 0p16.5 and q satisfies 0.34q0.34) and including a phase represented by Al.sub.2Fe.sub.3Si.sub.3 as a main phase.

Provided are a p-type thermoelectric conversion material, a thermoelectric conversion module, and a method of manufacturing a p-type thermoelectric conversion material that are capable of obtaining high thermoelectric conversion characteristics. The p-type thermoelectric conversion material has a full Heusler alloy having a composition represented by the following General Formula (1) and has a relative density of 85% or more, Fe.sub.xTi.sub.yMA.sub.aMB.sub.b . . . (1), wherein in Formula (1), MA is one element selected from the group consisting of Si, Sn, and Ge, MB is one element selected from the group consisting of Al, Ga, and In, and x, y, a, and b are numbers set so that x+y+a+b=100, a+b=z, 50<x52.5, 20y24.5, 24.5z29, a>0, and b>0 in atom %, respectively.

A composite including: at least one selected from a silicon oxide of the formula SiO.sub.2 and a silicon oxide of the formula SiO.sub.x wherein 0<x<2; and graphene, wherein the silicon oxide is disposed in a graphene matrix.

A composite including: at least one selected from a silicon oxide of the formula SiO.sub.2 and a silicon oxide of the formula SiO.sub.x wherein 0<x<2; and graphene, wherein the silicon oxide is disposed in a graphene matrix.

A thermoelectric device (20) and a method for manufacturing and using the same are disclosed. The thermoelectric device (20) includes a hot shoe (24) and a cold shoe (28) disposed about the hot shoe. A heat conducting member (32) formed of a thermoelectric material extends between the hot shoe (24) and the cold shoe (28) and generates electricity in response to a temperature difference therebetween. The hot shoe (24) is heated and expands at a greater rate than the cold shoe (28) does during operation. The structural and spatial relationship of the hot shoe (24) and the cold shoe (28) maintains the thermoelectric material of the heat conducting member (32) in compression during operation of the thermoelectric device (20).

A method for producing a thermoelectric object for a thermoelectric conversion device is provided. A starting material which has elements in the ratio of a half-Heusler alloy is melted and then cooled to form at least one ingot. The ingot is homogenized at a temperature of 1000 C. to 1400 C. for a period of time t, wherein 0.5 ht<12 h or 24 h<t<100 h. The homogenized ingot is crushed and ground into a powder. The powder is cold-pressed and sintered at a maximum pressure of 1 MPa for 0.5 to 24 h at a temperature of 1000 C. to 1500 C.