Disclosed are two geometrically identical integrated Z-device structures, integrated in two distinct silicon dices, joined together in a face-to-face configuration, such that a p-doped thin film leg of one structure faces toward a n-doped thin film leg of the other structure and vice versa. Upon joining the Z-device structures together, the hill-top metal contacts of one integrated structure are bonded in electrical and thermal continuity with correspondent hill-top metal contacts of the other integrated structure, forming a substantially bivalve TEG of increased power yield for the same footprint area and having an enhanced conversion efficiency. Thermo-electrically generated current may be gathered from one or several end pad pairs, the pads of which are connected to respective valley bottom contacts, on one and on the other of the two dices of the bivalve device, at the ends of conductive lines of micro cells respectively belonging to one and to the other of the two coupled dices.

Dices of integrated Z-device structures on a substrate wafer of a 3D integrated thermo-electric generator (iTEG) may be stacked in a tri-dimensional heterogeneous integration mode, without or with interposer wafer dices, in coherent thermal coupling among them. Through silicon vias (TSVs) holes through the thickness of the semiconductor crystal of substrate of the dices of integrated Z-device structures in geometrical projection correspondence with valley bottom metal junction contacts, and through silicon vias (TSVs) holes through the thickness of the semiconductor crystal of interposer dices, in geometrical projection correspondence with the hill-top metal junction contacts of the coupled Z-device structures, have a copper or other good heat conductor filler, form low thermal resistance heat conduction paths through the stacked Z-device structures. Thermoelectrically generated current is gathered from every integrated Z-device of a multi-tier iTEG operating in an out-of-plane heat flux configuration.

Disclosed is an article having: a porous thermally insulating material, an electrically conductive coating on the thermally insulating material, and a thermoelectric coating on the electrically conductive coating. Also disclosed is a method of forming an article by: providing a porous thermally insulating material, coating an electrically conductive coating on the thermally insulating material, and coating a thermoelectric coating on the electrically conductive coating. The articles may be useful in thermoelectric devices.

The invention relates to a method for producing thermoelectric layers by depositing thermoelectric material on a substrate by means of sputter deposition. In order to create a method for producing thermoelectric layers that are better suited for use in thermogenerators, and in particular have higher Seebeck coefficients, the production of a target made of thermoelectric material is proposed by mixing at least two powdered starting materials having a particle size from 0.01 ?m-5000 ?m, while coupling in energy and depositing the thermoelectric material from the target on the substrate by way of magnetron sputter deposition.

The present invention relates to a thermoelectric composite material and a method for preparing a thermoelectric composite material. Specifically, the invention relates to a thermoelectric composite material in which graphene oxide attached with conductive metal nanoparticles is dispersed in a thermoelectric material and a method for preparing a thermoelectric composite powder comprising the steps of: growing conductive metal nanoparticles on the surface of graphene oxide (step 1); and introducing the graphene oxide attached with the conductive metal nanoparticles prepared in step 1 into a thermoelectric material precursor solution, followed by heat treatment (step 2).

An exemplary thermoelectric generator unit according to the present disclosure includes a plurality of tubular thermoelectric generators. Each generator generates electromotive force in an axial direction based on a difference in temperature between its inner and outer peripheral surfaces. The unit further includes a container housing the generators inside and a plurality of electrically conductive members providing electrical interconnection among the generators. The container has fluid inlet and outlet ports through which a fluid flows inside the container, and a plurality of openings into which the respective generators are inserted. In one implementation, the unit includes a baffle, which is provided between the fluid inlet port and the generators and changes the flow direction of the fluid that has flowed into the container through the fluid inlet port.

A thermoelectric conversion material according to the present disclosure includes Ge, In, and at least one selected from the group consisting of Sb and Bi, and Te, and satisfies a requirement (1): ++1.00. In the requirement (1), is a molar ratio of a content of Ge to a content of Te, is a molar ratio of a content of In to the content of Te, and is a molar ratio of a sum of a content of Sb and a content of Bi to the content of Te.

Methods and processes to fabricate thermoelectric materials and more particularly to methods and processes to fabricate nano-sized doped silicon-based semiconductive materials to use as thermoelectrics in the production of electricity from recovered waste heat. Substantially oxidant-free and doped silicon particulates are fractured and sintered to form a porous nano-sized silicon-based thermoelectric material.

A photovoltaic-thermoelectric hybrid device is disclosed, which comprises a bi-layer silicon substrate, an electrode unit having a first electrode and a second electrode disposed on and connected to the bi-layer silicon substrate, and an external circuit connecting to the electrode unit, in which an electric current is set up between the first electrode and the second electrode and flows through the bi-layer silicon substrate as the first electrode is either heated or illuminated more than the second electrode.

A porous silicon composite cluster comprising: a porous core comprising a porous silicon composite secondary particle, wherein the silicon composite secondary particle comprises an aggregate of two or more silicon composite primary particles, and the silicon composite primary particles each comprise silicon, a silicon oxide of the Formula SiO.sub.x, wherein 0<x<2, disposed on the silicon, and a first graphene disposed on the silicon oxide; and a shell disposed on and surrounding the core, the shell comprising a second graphene.