A method of forming an electrode in a ceramic transducer electronic component is provided. The method includes preparing a sintered body for a ceramic transducer containing a metal oxide, performing patterning by irradiating a laser on a surface of the sintered body for a ceramic transducer, and forming a metal electrode by performing an electroless plating process on the sintered body for a ceramic transducer on which the patterning is formed, wherein, in the performing of the patterning by irradiating the laser on the surface of the sintered body for a ceramic transducer, the patterning is performed by irradiating the laser that satisfies at least one of a predetermined power condition and a predetermined processing speed condition.

A method for fabricating a piezoelectric transducer includes depositing a layer of a piezoelectric material on a base using a depositor and applying an electric field to the layer of deposited piezoelectric material in defined locations using an electrode to sinter and pole the deposited piezoelectric material at those defined locations to form a layer of the piezoelectric transducer in a selected shape and with a selected dipole direction.

A lead-free KNN-based piezoelectric material represented by the composition formula (K.sub.aNa.sub.bLi.sub.c)(Nb.sub.dTa.sub.eSb.sub.f)O.sub.g, where 0.4≤a≤0.5, 0.5≤b≤0.6, 0.01≤c≤0.1, 0.5≤d≤1.0, 0.05≤e≤0.15, 0.01≤f≤0.09, 1≤g≤3. In one embodiment, the lead-free KNN-based piezoelectric material has a d.sub.33>300 pm/V and a T.sub.curie>250° C. In one embodiment, the d.sub.33 and T.sub.curie of the lead-free textured KNN-based piezoelectric material can be adjusted by creating phase boundaries of (i) orthorhombic to tetragonal (O-T), (ii) rhombohedral to orthorhombic (R-O), and (iii) orthorhombic to tetragonal (O-T). In one embodiment, the lead-free KNN-based piezoelectric material is textured with NaNbO.sub.3 or Ba.sub.2NaNb.sub.5O.sub.15 seeds which are platelet or acicular shaped. In one embodiment, the amount, orientation, or particle size distribution of the NaNbO.sub.3 or Ba.sub.2NaNb.sub.5O.sub.15 texturing seeds in the lead-free textured KNN-based piezoelectric material can be altered.

A process for preparing a porous ceramic body includes forming a green body with a mixture of ceramic material powder, binder material, and pore-forming particles. The process further includes extracting the binder material, decomposing the pore-forming particles, and removing residual organic materials from the green body at respective, progressively higher pre-firing temperatures. After these three stages, the green body is sintered at a still-higher temperature to form the porous ceramic body. Embodiments facilitate manufacturing and can render most or all surface grinding unnecessary, allowing electrode deposition directly onto substantially non-porous surfaces of the porous ceramic body that are naturally formed during sintering. Advantageously, the green body may be formed into net shape by injection molding the mixture that includes the pore-forming particles, and embodiments can result in porous ceramic bodies that are much thicker than currently available, with better structural integrity.

Provided are a piezoelectric ceramics which does not contain lead, has small temperature dependence of a piezoelectric constant within an operating temperature range, and has high density, a high mechanical quality factor, a satisfactory piezoelectric constant, and a small surface roughness, and a method of manufacturing the piezoelectric ceramics. The method of manufacturing a piezoelectric ceramics is characterized by including: sintering a compact containing a raw material at 1,000° C. or more to obtain a sintered compact; abrading the sintered compact; and annealing the abraded sintered compact at a temperature of 800° C. or more and less than 1,000° C.

In an embodiment a piezoelectric multilayer component includes a ceramic main body comprising a ceramic material, wherein a main component of the ceramic material has the general empirical formula (K.sub.XNa.sub.1-X)NbO.sub.3, where 0≤x≤1, wherein the ceramic material comprises at least two additives selected from a number of compounds respectively comprising at least one metal, wherein a metal of a first additive comprises at least K, Nb, Cu, Mn or Ta, and wherein a metal of a second additive comprises K, Nb or Ta.

A piezoelectric material having a large electromechanical coupling coefficient is provided. The material is manufactured by a method including the steps of: heating a piezoelectric material having a low-temperature side ferroelectric phase A and a high-temperature side ferroelectric phase B between which the phase of the piezoelectric material transitions according to a temperature change, from room temperature to a temperature range higher than T.sub.(B.fwdarw.A) at which temperature a change from the ferroelectric phase B to the ferroelectric phase A occurs in a temperature lowering process and lower than T.sub.(A.fwdarw.B) at which temperature a change from the ferroelectric phase A to the ferroelectric phase B occurs in a temperature rising process; starting application of an electric field to the piezoelectric material in a state where it is held within this temperature range; and continuing and finishing the electric field application at a temperature lower than T.sub.(A.fwdarw.B).

The present invention relates to a bismuth-based solid solution ceramic material, as well as a process for preparing the ceramic material and uses thereof, particularly in an actuator component employed, for example, in a droplet deposition apparatus. In particular, the present invention relates to a ceramic material having a general chemical formula (I): (I): x(Bi.sub.0.5Na.sub.0.5)TiO.sub.3-y(Bi.sub.0.5K.sub.0.5)TiO.sub.3-z.sub.1SrHfO.sub.3-z.sub.2SrZrO.sub.3, wherein x+y+Z.sub.1+Z.sub.2=1; y, (z.sub.1+z.sub.2)≠0; x≥0. In embodiments, the present invention also relates to a ceramic material having a general chemical formula (II): x(Bi0.5Na0.5)TiO3-y(Bi0.5K0.5)TiO3-y(Bi0.5K0.5)TiO3-ZiSrHfO3-z2SrZrO3, wherein x+y+z−i+z2=1; x, y, fa+z2)≠0; as well as a ceramic material of general formula (III): y(Bi.sub.0.5K.sub.0.5)TiO.sub.3-z.sub.1SrHfO.sub.3-z.sub.2SrZrO.sub.3, wherein y+z.sub.1,+z.sub.2=1; y, (z.sub.1+z.sub.2)≠0.

Form internal electrodes with a metal whose silver content is 80 percent by mass or higher, and also constitute piezoelectric ceramic layers with a piezoelectric ceramic whose primary component is an alkaline niobate having a perovskite structure and which contains at least one type of alkaline earth metal selected from calcium and barium, as well as silver, wherein the total content of the alkaline earth metal is 0.2 percent by mol or higher but lower than 2.0 percent by mol when the element content in the B sites of the alkaline niobate represents 100 percent by mol, and wherein the piezoelectric ceramic layers each contain at least one sintered grain 41 that has silver-segregated regions 42 inside and the silver-segregated regions 42 have a long diameter of 10 nm or smaller.

A multilayer piezoelectric element using an alkaline niobate-based piezoelectric ceramic, which can inhibit its reliability from dropping while lowering production cost, is characterized by forming internal electrodes (10) with a metal whose silver content is 80 percent by mass or higher, and also constituting piezoelectric ceramic layers (40) with a piezoelectric ceramic whose primary component is an alkaline niobate having a perovskite structure and which also contains a lithium manganate.