A substrate treatment method of treating a substrate using a block copolymer containing a hydrophilic polymer and a hydrophobic polymer, includes: a resist pattern formation step of forming a predetermined resist pattern by a resist film on the substrate; a thin film formation step of forming a thin film for suppressing deformation of the resist pattern on a surface of the resist pattern; a block copolymer coating step of applying a block copolymer to the substrate after the formation of the thin film; and a polymer separation step of phase-separating the block copolymer into the hydrophilic polymer and the hydrophobic polymer.

Techniques for tight pitch patterning are provided. In one aspect, a patterning method includes: forming mandrels on a substrate; forming spacers that are undoped alongside the mandrels, wherein gaps are present between the spacers; filling the gaps with a sacrificial material having a dopant; forming a mask having an opening marking a cut region of at least one of the spacers; removing the sacrificial material from the cut region of the at least one spacer via the mask; removing the mask; performing an anneal to diffuse the dopant from the sacrificial material into the spacers to form doped spacers, wherein following the anneal the cut region of the at least one spacer remains undoped; removing the cut region of the at least one spacer selective to the doped spacers; and patterning features in the substrate using the doped spacers as a hardmask. A patterning structure is also provided.

Embodiments of the present disclosure provide a forming method of a semiconductor structure and a semiconductor structure. The forming method includes: providing a base, the base includes a central region and dummy regions, and the central region includes a molding region and cutting regions; forming multiple spaced core pillars on the base; forming an initial mask layer surrounding and covering a sidewall of each core pillar on the base; removing the initial mask layers located in each cutting region to form multiple spaced mask sidewall strips in the molding region, and retaining at least one of the initial mask layers in each dummy region as a ring-shaped sidewall; removing the core pillars located in the central region and the dummy regions; and etching the base to form multiple functional structures, and etching the base to form dummy functional structures on two sides of the multiple functional structures.

Methods and techniques for deposition of amorphous carbon films on a substrate are provided. In one example, the method includes depositing an amorphous carbon film on an underlayer positioned on a susceptor in a first processing region. The method further includes implanting a dopant or the inert species into the amorphous carbon film in a second processing region. The implant species, energy, dose & temperature in some combination may be used to enhance the hardmask hardness. The method further includes patterning the doped amorphous carbon film. The method further includes etching the underlayer.

Exemplary etching methods may include forming a plasma of a fluorine-containing precursor to produce plasma effluents. A first bias frequency may be applied while forming the plasma. The methods may include contacting a substrate housed in a processing region of a semiconductor processing chamber with the plasma effluents. The substrate may be or include a photomask. The methods may include etching a first layer of the photomask. Etching the first layer of the photomask may expose a second layer of the photomask. The methods may include adjusting the first bias frequency to a second bias frequency while maintaining the plasma of the fluorine-containing precursor. The methods may include etching the second layer of the photomask.

A method of forming a multi color resist structure includes providing a substrate including an underlayer material; forming a first organic planarizing layer on the substrate; forming a first anti reflecting layer on the first organic planarizing layer, forming and developing a first patterned resist on the first anti reflecting layer; forming a second organic planarizing layer on the first anti reflecting layer and on the first patterned resist; forming a second anti reflecting layer on the second organic planarizing layer and forming and developing the second patterned resist, wherein the first patterned resist is a non-chemically amplified resist (n-CAR) or metal resist and the second patterned resist is CAR organic resist.

Methods for formation of a layer stack during a back-end-of-line (BEOL) process flow and the layer stack formed therefrom are provided. In one or more embodiments, the method utilizes a two-dimensional (2D) self-aligned scheme with a subtractive metal etch. The method includes using a hard mask to form a via with a small width which is formed through or contacts each of a first metal layer and a second metal layer. The via is filled with a metal gapfill to connect the first metal layer and the second metal layer. Each of the first metal layer and the second metal layer are patterned to form a plurality of features.

A method for forming a patterned mask layer is provided. The method includes forming a first layer over a substrate. The method includes forming a first strip structure and a second strip structure over the first layer. The method includes forming a spacer layer conformally covering the first strip structure, the second strip structure, and the first layer. The method includes forming a block structure in the first trench. The method includes removing a first portion of the spacer layer, which is under the first trench and not covered by the block structure, and a second portion of the spacer layer, which is over the first strip structure and the second strip structure. The method includes forming a third strip structure in the second trench and the third trench. The method includes removing the block structure. The method includes removing the spacer layer.

The present disclosure provides forming nanostructures utilizing multiple patterning process with good profile control and feature transfer integrity. In one embodiment, a method for forming features on a substrate includes forming a first mandrel layer on a material layer disposed on a substrate. A first spacer layer is conformally formed on sidewalls of the first mandrel layer, wherein the first spacer layer comprises a doped silicon material. The first mandrel layer is selectively removed while keeping the first spacer layer. A second spacer layer is conformally formed on sidewalls of the first spacer layer and selectively removing the first spacer layer while keeping the second spacer layer.

Provided is a method of high-density pattern forming, which includes: providing a substrate; forming a hard mask layer on the substrate; forming a sacrificial layer on the hard mask layer; forming photoresists arranged at intervals on the sacrificial layer; etching the sacrificial layer to enable the sacrificial layer to form a mandrel corresponding to the photoresist one by one, wherein a cross-sectional size of the mandrel gradually decreases from an end of the mandrel away from the hard mask layer to an end close to the hard mask layer; forming an isolation layer on the mandrel; removing the isolation layer on the top of the mandrel, the isolation layer covering the hard mask layer, and the mandrel to form an isolation sidewall pattern; and transferring the isolation sidewall pattern to the hard mask layer.