A negative electrode-solid electrolyte sub-assembly for an all-solid secondary battery, the sub-assembly including: a negative electrode current collector; a first negative active material layer on the current collector; an interlayer on the first negative active material layer; and a solid electrolyte on the interlayer and opposite the first negative active material layer, wherein the interlayer includes a composite including a first metal material and a lithium ion conductor, wherein the first metal material includes a first metal, an alloy including the first metal and lithium, a compound including the first metal and lithium, or a combination thereof, wherein the first negative active material layer includes a carbonaceous negative active material, and optionally a first negative active material including a second metal, a metalloid, or a combination thereof.

An anode for an energy storage device includes a current collector having an electrically conductive layer that includes nickel or copper, and a lithium storage structure comprising a plurality of first microstructures in contact with the electrically conductive layer. Each first microstructure includes silicon and is characterized by a first maximum width measured across the widest section orthogonal to the first microstructure axis. Each first microstructure includes a first portion characterized by the width substantially tapering from the maximum width to a location where each first microstructure contacts the electrically conductive layer and a second portion positioned farther from the electrically conductive layer than the first portion, the second portion defining a substantially hemispherical shape and the top of each first microstructure. The lithium storage structure has at least 1 mg/cm.sup.2 of active silicon and a total atomic % of nickel and copper is from 0.5% to 1.2%.

A battery can include a separator, a first current collector, a protective layer, and a first electrode. The first current collector and the protective layer can be disposed on one side of the separator. The first electrode can be disposed on an opposite side of the separator as the first current collector and the protective layer. Subjecting the battery to an activation process can cause metal to be extracted from the first electrode and deposited between the first current collector and the protective layer. The metal can be deposited to at least form a second electrode between the first current collector and the protective layer.

A lithium-ion secondary electrochemical cell includes a negative electrode formed as a composite electrode comprising an anode current collector and a first electrochemically active component capable of intercalating and deintercalating lithium ions. The lithium-ion electrochemical cell further includes a positive electrode formed as a composite electrode comprising a cathode current collector and a second electrochemically active component capable of intercalating and deintercalating lithium ions. The lithium-ion electrochemical cell also includes a lithium reserve formed at a current collector reserve region that is at least partly free of the first and the second electrochemically active components, the current collector reserve region being a portion of the anode current collector and/or the cathode current collector.

An electrochemical device including a positive electrode current collector; a first protruding portion including a plurality of positive electrodes in electrical contact with the positive electrode current collector, and a first dented portion disposed between each positive electrode of the plurality of positive electrodes; an electrolyte layer including a second protruding portion and a second dented portion respectively disposed on the first protruding portion including the plurality of positive electrodes and the first dented portion disposed between each positive electrode of the plurality of positive electrodes; and a negative electrode current collector layer including a third protruding portion and a third dented portion respectively disposed on the second protruding portion and the second dented portion of the electrolyte layer.

The present invention relates to a method for forming an SEI layer on an anode by using a non-electrochemical process for alkaliating anodes, resulting in reductions of the manufacturing capital requirements, time investments and energy consumed during industrial battery production.

The invention relates to a positive electrode for alkali metal-ion accumulator comprising at least one organic binder and at least one alkali metal salt meeting the following formula (I):

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wherein the X represent an alkali element.

The present invention provides a lithium secondary battery, wherein a peak at 167 to 171 eV and a peak at 160 to 164 eV are present in XPS analysis of sulfur on a negative electrode surface (S2p), and P169/P162 is in the range of 0.7 to 2.0 wherein the P169/P162 is the ratio between the intensity of the peak at 167 to 171 eV (P169) and the intensity of the peak at 160 to 164 eV (P162).

Cathodes for a fast charging lithium ion battery, processes for manufacturing thereof and corresponding batteries are provided. Cathode formulations comprise cathode material having an olivine-based structure, binder material, and monomer material selected to polymerize into a conductive polymer upon partial delithiation of the cathode material during at least a first charging cycle of a cell having a cathode made of the cathode formulation. When the cathode is used in a battery, polymerization is induced in-situ (in-cell) during first charging cycle(s) of the battery to provide a polymer matrix which is evenly dispersed throughout the cathode.

The present disclosure is directed to a battery that comprise at least one electrochemical cell that comprises a cathode, an anode or an anode current collector and an electrolyte disposed between the cathode and the anode or the current collector, wherein (a) the anode comprises an isotopically enriched metal; (b) the cathode comprises isotopically enriched metal ions; (c) the electrolyte comprises an isotopically enriched metal salt; (d) a combination of (a) and (b); (e) a combination of (a) and (c); (f) a combination of (b) and (c); or (g) a combination of (a), (b) and (c).