Iron electrode materials, iron electrodes, and methods for fabricating said iron electrode materials and iron electrodes via elevated temperature thermomechanical processing of porous particulate iron materials are described. For example, as part of iron electrode manufacture, a particulate iron material into an apparatus may be provided. In addition, pressure and/or heat may be applied to the particulate iron material in the apparatus for a time period to form an electrode having therein conductive connections between particles of the particulate iron material.

The present invention relates to materials and methods for components of zinc-ion batteries, such as manganese oxide cathodes having a coating. The coating comprises an oxide compound, a nitride compound, a fluoride compound, a phosphate compound, a sulfide compound, or any combination thereof.

Provided herein are energy storage devices comprising a first electrode comprising a layered double hydroxide, a conductive scaffold, and a first current collector; a second electrode comprising a hydroxide and a second current collector; a separator; and an electrolyte. In some embodiments, the specific combination of device chemistry, active materials, and electrolytes described herein form storage devices that operate at high voltage and exhibit the capacity of a battery and the power performance of supercapacitors in one device.

In an embodiment, an active material-based nanocomposite is synthesized by infiltrating an active material precursor into pores of a nanoporous carbon, metal or metal oxide material, and then annealing to decompose the active material precursor into a first gaseous material and an active material and/or another active material precursor infiltrated inside the pores. The nanocomposite is then exposed to a gaseous material or a liquid material to at least partially convert the active material and/or the second active material precursor into active material particles that are infiltrated inside the pores and/or to infiltrate a secondary material into the pores. The nanocomposite is again annealed to remove volatile residues, to enhance electrical contact within the active material-based nanocomposite composite and/or to enhance one or more structural properties of the nanocomposite. In a further embodiment, the pores may be further infiltrated with a filler material and/or may be at least partially sealed.

Materials, designs, and methods of fabrication for electrodes for electrochemical cells are disclosed. In various embodiments, the electrode comprises iron. Various embodiments may include materials, systems, and methods for the use of various iron-bearing materials, starting from the discharged or partially discharged state in an alkaline electrochemical cell, such as an Fe—Ni, Fe—MnO.sub.2, or Fe-air battery. Various embodiments may include a battery comprising an electrode comprising iron. In various embodiments, the iron may be in various forms, such as iron ore, iron concentrate, iron pellets, BF grade pellets, DR grade pellets, hematite, magnetite, wustite, martite, goethite, limonite, siderite, pyrite, ilmenite, spinel manganese ferrite, etc. In various embodiments, the iron may include impurity phases, such as SiO.sub.2, CaO, etc.

Systems and methods of the various embodiments may provide decoupled electrode electrochemical energy storage systems.

A battery cell includes a first electrode formed from at least one of a metal foil, a metal mesh or a metal layer on a substrate. A second electrode can be formed from at least partially oxidized material in a form of at least one of a metal foil, a metal layer on a substrate, a metal mesh, or a battery electrode that includes plurality of particles on current collector. A layer of an ion exchange material can be positioned between the first and second electrodes, with the ion exchange material capable of acting as an electrolyte in some embodiments.

The present disclosure relates to double layered hydroxide-type compounds comprising both di- and tri-valent nickel ions, and the use of such compounds in electrodes for energy storage device in addition to a previously developed electrode using Fe.sup.2+ and Fe.sup.3+ “green rusts related compounds”.

Methods and systems are provided for iron preformation in a redox flow battery. In one example, a method may include, in a first condition, discharging and then charging the redox flow battery, and in a second condition, charging the redox flow battery including preforming iron metal at a negative electrode of the redox flow battery, and thereafter entering an idle mode of the redox flow battery including adjusting one or more electrolyte conditions. In some examples, each of preforming the iron metal and adjusting the one or more electrolyte conditions may increase a battery charge capacity to greater than a threshold battery charge capacity.

Methods and systems are provided for iron preformation in a redox flow battery. In one example, a method may include, in a first condition, discharging and then charging the redox flow battery, and in a second condition, charging the redox flow battery including preforming iron metal at a negative electrode of the redox flow battery, and thereafter entering an idle mode of the redox flow battery including adjusting one or more electrolyte conditions. In some examples, each of preforming the iron metal and adjusting the one or more electrolyte conditions may increase a battery charge capacity to greater than a threshold battery charge capacity.