The present disclosure relates to an electrolyte for a lithium-sulfur battery including a non-aqueous organic solvent including specific three types of compounds, and a lithium-sulfur battery including the same.

A lithium-sulfur battery includes a casing, a top lid circumferentially welded to the casing, a negative contact surface positioned opposite the top lid, a positive terminal disposed within the casing, welded to the top lid, and configured as a mandrel, a glass insulator circumferentially wound around the mandrel, and a jelly roll including at least an anode and a cathode wound around the mandrel. The jelly roll may also include a top surface not in contact with the top lid, a bottom surface partially in contact with the negative contact surface, and partially in contact with a plurality of non-hollow carbonaceous spherical particles disposed between the bottom surface of the jelly roll and the negative contact surface. At least some of the non-hollow carbonaceous spherical particles may provide one or more electrically-conductive pathways between the bottom surface and the negative contact surface.

A positive electrode active material includes a doped lithium nickel phosphate having an olivine structure comprising distorted NiO.sub.6 octahedra. The dopant is an anion; or a combination of at least two transition metals having different ionic radii; or an anion and a metal cation. The positive electrode active material can be used in a positive electrode for an electrochemical cell.

Provided is a method for the preparation of a porous hollow shell WO.sub.3/WS.sub.2 nanomaterial, comprising: (1) adding a hexavalent tungsten salt to a sol A comprising mesocarbon microbeads, and stirring to obtain a sol B; (2) drying and grinding the sol B, and then heating a resulting powder at 200-500° C. for 0.5-2 hours to obtain a porous hollow shell WO.sub.3 nanocrystalline material; (3) placing the porous hollow shell WO.sub.3 nanocrystalline material obtained by Step 2 and a sulfur powder separately in a vacuum furnace, controlling such that a degree of vacuum is −0.01 to −0.1 MPa and a temperature is 200-500° C., and reacting for 0.5-3 hours to obtain a WO.sub.3/WS.sub.2 porous hollow shell nanocrystalline material. Also provided is a porous hollow shell WO.sub.3/WS.sub.2 nanocrystalline material obtained by the method.

The invention provides a method for delaminating a composite by immersing the composite into a delamination solution; wherein the composite comprises a metal substrate and a coating applied on one side or both sides of the metal substrate, wherein the coating comprises a polymeric binder; and wherein the polymeric binder comprises an aqueous copolymer. The use of delamination solution comprising an alkali metal phosphate salt allows for complete delamination of the composite in a highly efficient and extremely fast manner. Furthermore, the delamination method disclosed herein circumvents complex separation processes, contamination and corrosion of the metal substrate and enables an excellent materials recovery. An application of the method for delaminating an electrode for a battery is disclosed herein.

One or more interfacial layers in contact with a solid-state electrolyte and hybrid electrolyte materials. Interfacial layers comprise inorganic (e.g., metal oxides and soft inorganic materials) or organic materials (e.g., polymer materials, gel materials and ion-conducting liquids). The interfacial layers can improve the electrical properties (e.g., reduce the impedance) of an interface between an a cathode and/or anode and a solid-state electrolyte. The interfacial layers can be used in, for example, solid-state batteries (e.g., solid-state, ion-conducting batteries).

A lithium-sulfur battery comprising an electrolyte including a first solvent containing a fluorine-based ether compound, a second solvent containing a glyme-based compound, and a lithium salt; and a positive electrode including active materials comprising sulfur and a carbon material, the lithium-sulfur battery having a sulfur utilization rate of sulfur included in the positive electrode of 90% or higher based on a theoretical discharge capacity, is provided.

An all-solid-state battery is provided with an intermediate layer containing a metal sulfide.

Methods, apparatuses, and systems may provide for technology used in batteries including an anode particle layer. Such an anode particle layer includes a plurality of silicon particles covered with a coating layer, where the coating layer comprises one or more of a transition metal sulfide and a transition metal chalcogenide.

An all-solid-state lithium battery, thermo-electromechanical activation of Li.sub.2S in sulfide based solid state electrolyte with transition metal sulfides, and electromechanical evolution of a bulk-type all-solid-state iron sulfur cathode, are disclosed. An example all-solid-state lithium battery includes a cathode having a transition metal sulfide mixed with elemental sulfur to increase electrical conductivity. In one example method of in-situ electromechanically synthesis of Pyrite (FeS.sub.2) from Sulfide (FeS) and elemental sulfur (S) precursors for operation of a solid-state lithium battery, FeS+S composite electrodes are cycled at moderately elevated temperatures.