A lithium-sulfur battery includes: a substrate; a composite cathode disposed on the substrate; a solid-state electrolyte disposed on the composite cathode; and a lithium anode disposed on the solid-state electrolyte, such that the composite cathode comprises: active elemental sulfur, conductive carbon, sulfide electrolyte, and ionic liquid.

The present application provides a negative electrode active material, a process for preparing the same, and a secondary battery, a battery module, a battery pack and an apparatus related the same. The negative electrode active material comprises a core material and a polymer-modified coating layer on at least a part of a surface of the core material, the core material is one or more of a silicon-based negative electrode material and a tin-based negative electrode material, the polymer-modified coating layer comprises sulfur element and carbon element, the sulfur element has a mass percentage of from 0.2% to 4% in the negative electrode active material, the carbon element has a mass percentage of from 0.5% to 4% in the negative electrode active material, and the polymer-modified coating layer comprises a —S—C— bond.

The invention relates to a highly reactive, high-purity, free-flowing and dust-free lithium sulfide powder having an average particle size between 250 and 1,500 μm and BET surface areas between 1 and 100 m.sup.2/g. The invention, furthermore, relates to a process for its preparation, wherein in a first step, lithium hydroxide monohydrate is heated in a temperature-controlled unit to a reaction temperature between 150° C. and 450° C. in the absence of air, and an inert gas is passed over or through it, until the residual water of crystallization content of the formed lithium hydroxide is less than 5 wt. % and in a second step, the anhydrous lithium hydroxide formed in the first step is mixed, overflowed or traversed by a gaseous sulfur source from the group consisting of hydrogen sulfide, elemental sulfur, carbon disulfide, mercaptans or sulfur nitrides.

Provided is a lithium sulfur secondary battery excellent in durability. An electrolytic solution to be used for a lithium sulfur secondary battery having a positive electrode containing a sulfur-containing electrode active material containing at least one selected from the group consisting of simple sulfur, lithium polysulfides (Li.sub.2S.sub.n: 1<n<8) and organosulfur compounds, and a negative electrode containing a material that occludes and releases lithium ions, the electrolytic solution containing a nonaqueous electrolyte and a solvent, wherein the solvent contains vinylene carbonate in a proportion of 10 to 100% by weight.

A method of manufacturing a lithium metal negative electrode, a lithium metal negative electrode manufactured thereby, and a lithium-sulfur battery including the same is disclosed. The method of manufacturing a lithium metal negative electrode includes the steps of (a) applying lithium nitride powder on at least one surface of a lithium metal layer including lithium metal; and (b) rolling the applied powder to form a lithium nitride protective layer of a powder bed on at least one surface of the lithium metal layer.

A material of formula Li.sub.aTi.sub.b(A.sub.xS.sub.3-x).sub.c wherein A is a metalloid element chosen from selenium, tellurium and mixtures thereof, and the stoichiometric coefficients a, b, c and x are such that 0<x<2.2; 0.4≤a≤4.5; 0.9≤b≤1.1; and 0.9≤c≤1.1.

This disclosure provides a battery comprising a cathode and an anode positioned opposite the cathode. A hybrid artificial solid-electrolyte interphase (A-SEI) layer is deposited on the anode and includes a plurality of active components. A blended material is interwoven throughout the plurality of active components and configured to inhibit growth of Lithium (Li) dendritic structures from the anode to the cathode. The blended material includes a combination of crystalline sp.sup.2-bound carbon domains of graphene sheets and a plurality of flexible wrinkle areas positioned at joinder points of two of more of the crystalline sp.sup.2-bound carbon domains of graphene sheets and a polymeric matrix configured to bind the plurality of active components and the blended material together. An electrolyte is in contact with the hybrid A-SEI and the cathode and a separator is positioned between the anode and the cathode. The blended material includes curable carboxylate salts of metals.

Provided are sulfide solid electrolyte particles which have sufficient ion conductivity and which are, when used in an all-solid-state battery, configured to suppress a resistance increase rate after charge-discharge cycles, and an all-solid-state battery comprising the sulfide solid electrolyte particles. The sulfide solid electrolyte particles may be sulfide solid electrolyte particles comprising a sulfide solid electrolyte that comprises Li, P, S and a halogen as constituent elements, wherein an oxygen/sulfur element ratio of a particle surface measured by XPS, is 0.79 or more and 1.25 or less, and an oxygen/sulfur element ratio at a depth of 30 nm (in terms of a SiO.sub.2 sputter rate) from the particle surface measured by XPS, is 0.58 or less.

An electrode active material for lithium-ion secondary batteries that has a sufficiently high initial capacity, improved charge-and-discharge cycle characteristics, and improved coulombic efficiency in the mid-term charge-and-discharge cycles can be obtained by a phosphorus-containing low-crystalline vanadium sulfide comprising vanadium, phosphorus, and sulfur as constituent elements, the composition ratio of the phosphorus to the vanadium (P/V) being 0.1 to 1.0 in terms of the molar ratio, the composition ratio of the sulfur to the vanadium (S/V) being 4.00 to 10.00 in terms of the molar ratio.

A lithium-sulfur battery cathode including conductive porous carbon particles vacuum infused with sulfur and a conductive collector substrate to which the sulfur infused porous carbon particles are deposited. The sulfur infused carbon particles are encapsulated by an encapsulation polymer, the encapsulation polymer having ionic conductivity, electronic conductivity, polysulfide affinity, or combinations thereof. A lithium-sulfur battery including the lithium-sulfur battery cathode, a lithium anode and an electrolyte disposed between the sulfur cathode and the lithium anode is also provided. Methods of producing the sulfur cathode for use in a lithium-sulfur battery by a hybrid vacuum-and-melt method are also provided.