H01M4/604

SECONDARY Li ION BATTERY AND Li CAPACITOR ELECTRODE COMPOSITIONS

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

POLYMER BINDERS FOR SILICON OR SILICON-GRAPHITE COMPOSITE ELECTRODES AND THEIR USE IN ELECTROCHEMICAL CELLS

Described are polymers, polymer binders, hydrogel polymer binders, hydrogel polymer binder compositions comprising them, electrode materials comprising them, their methods of production and their use in electrochemical cells, for instance, in silicon-based electrochemical cells.

IMPROVED ORGANIC ELECTRODE MATERIAL

A novel electrode material features improved capacity compared to conventional electrode materials. This electrode material includes an organic redox polymer non-conjugated in the main chain, a conductivity additive, and an ionic liquid. Also, a process is for producing an electrode from this novel electrode material. The electrode obtainable by the process also features improved capacity.

CONDUCTING POLYMER NETWORK-PROTECTED PHOSPHORUS ANODE ACTIVE MATERIAL FOR LITHIUM-ION OR SODIUM-ION BATTERIES
20210351409 · 2021-11-11 ·

Provided is conducting network polymer-encapsulated phosphorus-based anode particulate or multiple particulates for a lithium or sodium ion battery, the particulate comprising: (A) a core comprising one or a plurality of phosphorus material particles or coating (e.g. on surfaces of graphitic material particles) having a diameter or thickness from 0.5 nm to 10 μm and is selected from red phosphorus, black phosphorus (including phosphorene), violet phosphorus, a metal phosphide, MPy, or a combination thereof, wherein M=Mn, V, Sn, Ni, Cu, Fe, Co, Zn, Ge, Se, Mo, Ga, In, or an alloy thereof, and y=1-4; and (B) an encapsulating shell that embraces or encapsulates the core, wherein the encapsulating shell comprises an electron- and/or ion-conducting network (cross-linked) polymer.

Secondary Li ion battery and Li capacitor electrode compositions

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

Ion conductive layer and methods of forming

A solid ion conductive layer can include a foamed matrix and an electrolyte material including a hygroscopic material. In an embodiment, the electrolyte material can include a halide-based material, a sulfide-based material, or any combination thereof. In another embodiment, the solid ion conductive layer can include total porosity of at least 30 vol % for a total volume of the solid ion conductive layer.

Electrode binder slurry composition for lithium ion electrical storage devices

The present invention provides a slurry composition comprising an electrochemically active material and/or an electrically conductive agent, and a binder comprising a polymer comprising a fluoropolymer dispersed in an organic medium; wherein the organic medium has an evaporation rate less than 10 g/min m.sup.2, at the dissolution temperature of the fluoropolymer dispersed in the organic medium. The present invention also provides electrodes and electrical storage devices.

Lithium ion battery electrolyte additive

A quaternary hexahydrotriazine ionic liquid compound additive useful for reducing battery resistance and improving cycle life stability and high-temperature performance; an electrolyte containing the quaternary hexahydrotriazine ionic liquid compound additive suitable for use in electrochemical energy storage devices; and an electrochemical energy storage device incorporating the electrolyte including the quaternary hexahydrotriazine ionic liquid compound additive are described.

Lithium Deposition and Battery Using Inorganic Molten Salts
20220393173 · 2022-12-08 ·

A conformable polymer coated lithium metal electrode provides the negative electrode and the solid electrolyte for a rechargeable lithium metal battery that further includes an inorganic molten salt electrolyte having a melting temperature below 140° C. interposed between the conformable polymer coating and a positive electrode. In some embodiments, the conformable polymer is a block or graft copolymer. Optionally, the positive electrode includes elemental sulfur in a conductive matrix. The conformable polymer coated lithium metal electrode may be manufactured by a process involving electroplating lithium metal through a conformable polymer coated conductive substrate. The conformable polymer coated conductive substrate may be prepared by coating the conductive substrate in a conformable polymer solution followed by evaporating the solvent. Alternatively, a lithium metal electrode may be coated directly with conformable polymer.

Dispersant for electrode coating liquid, electrode coating liquid composition including the dispersant for electrode coating liquid, electrode for power storage device manufactured using the electrode coating liquid composition, and power storage device having the electrode

A composition that includes a dispersion stabilizer for an electrode coating liquid for a power storage device is provided. The composition has superior ability to stably disperse an electrode active material and a conductive material, and makes it possible to manufacture a uniform electrode, even when a dispersion device that has weak shear force is used. A dispersant for an electrode coating liquid for a power storage device, the dispersant being characterized by containing cellulose fibers that satisfy (a)-(c). (a) The number average width of the short widths is 2-200 nm. (b) The aspect ratio is 7.5-250. (c) Cellulose I crystals are included and the crystallinity thereof is 70%-95%.