This application relates to an electrode plate that includes a current collector and an electrode active material layer disposed on at least one surface of the current collector. The current collector includes a support layer and a conductive layer disposed on at least one surface of the support layer. A single-side thickness D2 of the conductive layer satisfies 30 nm≤D2≤3 μm. The electrode active material layer includes an electrode active material, a binder, and a conductive agent unevenly distributed in a thickness direction of the electrode active material layer. A weight percentage of the conductive agent in an interior area of the electrode active material layer is higher than that in an exterior area of the electrode active material layer.

This positive electrode includes a current collector, an intermediate layer which is formed at least on one surface of the current collector, and a composite material layer which is formed on the intermediate layer. The intermediate layer includes metal compound particles, a conductive material, and a binding material. The metal compound particles comprise at least one selected from a sulfated oxide, hydroxide, or oxide of alkali earth metal or alkali metal.

A positive electrode as an example of an embodiment includes a positive electrode current collector, a positive electrode mixture layer which is disposed on at least one surface side of the positive electrode current collector, and an intermediate layer which is interposed between the positive electrode current collector and the positive electrode mixture layer. The intermediate layer contains insulating inorganic particles having a thermal conductivity of less than 50 W/mK, highly thermal conductive particles having a thermal conductivity of 50 W/mK or more, a thermoplastic resin, and polyvinylidene fluoride. The content of the inorganic particles is 50% by mass or more relative to the mass of the intermediate layer.

A positive current collector, a secondary battery, and an electrical device are provided. In some embodiments, the positive current collector includes: a support layer; and a conductive layer located on at least one surface of the support layer, where the conductive layer includes a first metal portion configured to connect to a tab, where, along a thickness direction of the conductive layer, the first metal portion includes at least three sublayers, and melting points of the at least three sublayers rise stepwise in ascending order of distance from the support layer. In the embodiments of this application, the first metal portion includes at least three sublayers, and the melting points of the at least three sublayers rise stepwise in ascending order of distance from the support layer, thereby helping increase a bonding force between the conductive layer and the support layer and reducing the probability of peel-off and delamination between the layers.

A reference electrode assembly for an electrochemical cell includes a separator constructed from an electrically-insulating porous material. The reference electrode assembly also includes a current collector having a sputtered electrically-conducting porous layer arranged directly on the separator and a sputtered lithium iron phosphate (LFP) layer arranged directly on the electrically-conducting porous layer. The reference electrode assembly additionally includes an electrical contact connected to the current collector. A method using successive vacuum deposition of individual layers onto the separator is employed in fabricating the reference electrode assembly.

An embodiment all solid state battery includes a sulfide-based solid electrolyte layer, a negative electrode comprising a negative active material layer stacked on a first surface of the solid electrolyte layer and a negative buffer layer stacked on a first surface of the negative active material layer, and a positive electrode comprising a positive active material layer stacked on a second surface of the solid electrolyte layer and a positive buffer layer stacked on a second surface of the positive active material layer.

The present technology relates to self-standing electrodes, their use in electrochemical cells, and their production processes using a water-based filtration process. For example, the self-standing electrodes may be used in lithium-ion batteries (LIBs). Particularly, the self-standing electrodes comprise a first electronically conductive material serving as a current collector, the surface of the first electronically conductive material being grafted with a hydrophilic group, a binder comprising cellulose fibres, an electrochemically active material, and optionally a second electronically conductive material. A process for the preparation of the self-standing electrodes is also described.

A method of manufacturing an all solid state battery is disclosed. In one embodiment, the method includes forming a negative electrode including a negative active material layer and a negative buffer layer, forming a sulfide-based solid electrolyte layer on a first surface of the negative electrode, forming a positive electrode including a positive active material layer and a positive buffer layer, and bonding the positive electrode to a second surface of the solid electrolyte layer.

A solid-state electrochemical cell is provided including a first electrode connected to a first current collector, a second electrode connected to a second current collector, a separator interconnecting the first electrode and the second electrode, the separator including a solid-state electrolyte, first oriented pores including a first electrode material formed in the first electrode, and second oriented pores including a second electrode material formed in the second electrode, wherein at least one of the first oriented pores and the second oriented pores includes an electronically conducting network extending on sidewall surfaces thereof from a corresponding one of the first and second current collectors to the electrolyte separator. The second electrode includes a filling aperture including a seal configured to isolate the first electrode from cathode material in the second electrode.

A producing method for a positive electrode plate includes a positive electrode paste preparing process of preparing a positive electrode paste including carbon nanotubes, positive active material particles, and a solvent, a coating process of coating the positive electrode paste on a surface of a current collector to form a positive electrode paste layer on the surface of the current collector, and a drying process of drying the positive electrode paste layer to form a positive electrode mixture layer. The carbon nanotubes have the characteristics of being attracted by magnets, and the carbon nanotubes included in the positive electrode paste layer are attracted toward a side of the current collector by the magnets at least any one of directly before the drying process or during the drying process.