A method for manufacturing a substrate for a lead acid battery includes manufacturing a powder mixture by mixing lead powder and carbon powder and manufacturing a substrate by compress-molding the powder mixture. 85 wt % to 95 wt % of the lead powder and 5 wt % to 15 wt % of the carbon powder are mixed, based on 100 wt % of the powder mixture.

Disclosed are electrode plates for a lead acid battery. The electrode plates are formed of an electrode plate having a face, the electrode plate comprising a lead or lead alloy grid coated with an active material and the electrode plates having a porous, non-woven mat comprised of polymer fibers coating on the face of the electrode plate, as well as a method for making the coated electrode plates and lead acid batteries containing the coated electrode plates.

In a bipolar lead-acid storage battery including a main substrate in which cell members are individually accommodated in spaces, a positive electrode current collector plate is disposed on one surface of the main substrate, and a negative electrode current collector plate is disposed on the other surface of the main substrate, the corrosion of the thin-formed positive electrode current collector plate is prevented to extend a life of the bipolar lead-acid storage battery. A thickness (T1) of a positive electrode current collector plate disposed on one surface of a main substrate, which is a substrate disposed between adjacent cell members, ranges from 0.15 mm to 0.75 mm. A ratio (T1/T2) of the thickness (T1) of the positive electrode current collector plate relative to the thickness (T2) of a negative electrode current collector plate disposed on another face of the main substrate ranges from 1.5 to 6.5.

Infiltration of an electrolyte solution into a through hole is prevented or minimized to suppress the occurrence of a liquid junction, so that battery performance is less likely to deteriorate, and the life is prolonged. A cell member includes a positive electrode, a negative electrode, and an electrolyte layer interposed therebetween. The cell member is stacked and disposed at an interval. A space forming member includes a substrate and a frame body. A through hole penetrates between a positive electrode side and a negative electrode side in the space forming member, and a conductor inserted into the through hole electrically connects them. A liquid junction prevention member is provided in a vicinity of an opening on the positive electrode side, a vicinity of an opening on the negative electrode side, or both.

A shoe for dispensing a molten metal such as lead into a mold cavity of a rotating drum to continuously cast a web of a plurality of serially connected grids or battery composite electrodes of a carbon fiber material with a cast metal conductor. The shoe may have at least one elongate orifice slot in a face confronting the drum, a molten metal supply passage communicating with the orifice slot and an excess molten metal return slot opening into the confronting face downstream of the supply slot relative generally to the direction of rotation of the drum.

An objective is to improve the corrosion resistance of a positive electrode grid for lead acid batteries. Provided is a positive electrode grid for lead acid batteries, and a lead acid battery including the grid. The grid includes a lead alloy containing calcium and tin. The lead alloy has a calcium content of 0.10 mass % or less, and a tin content of 2.3 mass % or less, and a lattice constant of 4.9470 or less.

A lead-acid battery includes an electrode plate assembly, a battery case, a positive electrode strap, a negative electrode strap, a positive electrode post, a negative electrode post, a cover, and an electrolyte solution. A negative electrode bushing provided in the cover and the negative electrode post together constitute a negative electrode terminal. A maximum value of a gap between an outer circumferential surface of the negative electrode post and an inner circumferential surface of the negative electrode bushing in the negative electrode terminal is 0.5 mm or more and 2.5 mm or less. A rib is provided in a lower part of the negative electrode bushing, and a minimum value of a protrusion height of the rib is 1.5 mm or more and 4.0 mm or less. A distance between a surface of the electrolyte solution and a lowermost portion of the negative electrode bushing is 15 mm or less.

A lead acid battery including: a positive electrode plate including a positive electrode grid and a positive electrode active material; a negative electrode plate including a negative electrode grid and a negative electrode active material; an electrode plate group including the positive electrode plate, the negative electrode plate, and a separator interposed between the positive electrode plate and the negative electrode plate; a battery container including a plurality of cell chambers each accommodating the electrode plate group and an electrolyte; and a lid sealing an opening of the battery container. A ratio P/N of mass P of the positive electrode active material to mass N of the negative electrode active material is 1.25 or more and 1.65 or less. The negative electrode grid contains bismuth in an amount of 1 ppm or more and 300 ppm or less.

The present disclosure provides a multi-physics engineered multi-material electrode grid plate for improved performance of a battery having uniform current collection and transport. The grid comprises a plurality of vertical grid wires (102, 406), a plurality of horizontal grid wires (104, 404), a plurality of frame grid wires, wherein the vertical grid wires (102, 406) and the horizontal grid wires (104, 404) provided between the frame grid wires for current transport. An active material current collector (108, 408) is provided for current collection and an active material utilization enhancer (601) is configured in a lateral cross-section of the grid wires ((102, 406) (104, 404)) with maximum surface perimeter.

A shoe for dispensing a molten metal such as lead into a mold cavity of a rotating drum to continuously cast a web of a plurality of serially connected grids or battery composite electrodes of a carbon fiber material with a cast metal conductor. The shoe may have at least one elongate orifice slot in a face confronting the drum, a molten metal supply passage communicating with the orifice slot and an excess molten metal return slot opening into the confronting face downstream of the supply slot relative generally to the direction of rotation of the drum.