A secondary battery electrode 100 of the present invention includes: a plurality of metallic porous plates 101 superposed in a thickness direction T; and an electrode mixture 102 with which voids constituting the metallic porous plates 101 are filled, in which adjacent metallic porous plates 101 are press-jointed to each other.

An electrode and a device employing the same are provided. The electrode includes a main body, and an active material. The main body includes a cavity and is made of a conductive network structure. In particular, the active material is disposed in the cavity, wherein the length of the longest side of the particle of the active material is greater than the length of the longest side of the pore of the conductive network structure such that the active material is confined in the conductive network structure.

Disclosed are a porous aluminum macroscopic body, a fabrication system, and a method therefor, where the porous aluminum macroscopic body is a three-dimensional full-through-hole structure formed by connecting hollow aluminum wires, and the wall thickness of the hollow aluminum wires is 7-100 micrometers. The fabrication system comprises a magnetron sputtering subsystem, a high-temperature aluminum vapor subsystem, a low-temperature aluminum deposition subsystem, an aluminum vapor recovery subsystem, and a porous polymer film conveying subsystem. A preparation method therefor comprises first utilizing a magnetron sputtering method to rapidly sputter on a porous polymer film to form an aluminum layer that has a thickness of 1-500 nm, and then continuing to deposit the aluminum layer to a thickness of 7-100 micrometers while decomposing the polymer film in-situ so as to obtain the porous aluminum macroscopic body.

An electrolyte element (10) comprises a perforated sheet (11) of non-reactive metal such as an aluminium-bearing ferritic steel, and a non-permeable ceramic layer (16b) of sodium-ion-conducting ceramic bonded to one face of the perforated sheet (11) by a porous ceramic sub-layer (16a). The perforated sheet (11) may be of thickness in the range 50 m up to 500 m, and the thickness of the non-permeable ceramic layer (16b) may be no more than 50 m, for example 20 m or 10 m. Thus the electrolyte properties are provided by the non-permeable thin layer (16b) of ceramic, while mechanical strength is provided by the perforated sheet (11). The electrolyte element (10) may be used in a rechargeable molten sodium-metal halide cell, in particular a sodium/nickel chloride cell (20). It makes cells with increased power density possible.

The disclosure provides an electrode for solid state battery and a solid state battery, wherein the electrode using a foamed metal as a collector has excellent mechanical strength and can maintain the insulation from a counter electrode when constituting the solid state battery. In the electrode for solid state battery, which uses a collector composed of a foamed porous body that has a mesh structure, a layer that achieves reinforcement and insulation is provided in the boundary between a filled part filled with an electrode mixture and an unfilled part.

The present invention provides a three-dimensional current collector used in a metal secondary battery and the preparation method of said current collector. Said current collector is a three-dimensional porous hollow carbon fiber current collector which has both porous structure and hollow structure and is used to load metal anode, so that lithium dendrites growth can be suppressed and the Coulombic efficiency can be improved. Said current collector is intertwined by micrometer-sized hollow carbon fibers with the diameter of 1 to 50 m, the wall thick of 0.5 to 6 m, and the pore volume of 0.005 to 0.05 cm.sup.3 cm.sup.2.

In a nonaqueous electrolyte secondary battery a separator includes a porous substrate, a first filler layer, and a second filler layer. The first filler layer comprises phosphate particles having a BET specific surface area of 5 to 100 m.sup.2/g and polyvinylidene fluoride and is formed on a first surface that faces the positive electrode side of the substrate and contacts the positive electrode. The second filler comprises inorganic particles which have a melting point higher than that of the phosphate particles and is formed on at least one of a second surface that faces the negative electrode side of the substrate and the area between the substrate and the first filler layer. The content of the polyvinylidene fluoride in the first filler layer is 10 to 50 mass % and is higher in a region on the positive electrode side than in a region on the substrate side.

Electrochemical device using thin micro-porous metal sheets. The porous metal sheet may have a thickness less than 200 m, provides three-dimensional networked pore structures of pore sizes in the range of 2.0 nm to 5.0 m, and is electrically conductive. The micro-porous metal sheet is used for positively and/or negatively-charged electrodes by providing large specific contact surface area of reactants/electron. Nano-sized catalyst or features can be added inside pores of the porous metal sheet of pore sizes at sub- and micrometer scale to enhance the reaction activity and capacity. Micro-porous ceramic materials may be coated on the porous metal sheet at a thickness of less than 40 m to enhance the functionality of the porous metal sheet. The ceramic coating layer of non-electrical conductivity can function as a membrane separator. The electrochemical device may be used for decomposing molecules and for synthesis of molecules such as synthesis of ammonia from water and nitrogen molecules.

The present disclosure discloses a porous structure Si/Cu composite electrode of a lithium ion battery and a preparation method thereof. The composite electrode comprises an active substance, a bulk porous Cu and a current collector, wherein the active substance Si is embedded into the bulk porous Cu, and the bulk porous Cu is in metallurgical bonding with the current collector and plays a dual role of binder and conductive agent, which not only relieves the pulverization and the shedding of the active substance Si particles but also improves electron transmission efficiency; and meanwhile, the porous structure increases the contact area between the active substance Si and electrolyte and increases the reaction efficiency of lithium insertion combination. The method of preparing the composite electrode comprises: with Si, Cu and Al powders as raw materials, preparing a SiCuAl precursor alloy on the Cu current collector by powder metallurgy and diffusion welding technology; and removing Al element in the SiCuAl precursor alloy by using a chemical de-alloying method to obtain a Si/Cu composite electrode with a porous-structure.

A method for manufacturing a lithium secondary battery including (S1) providing a battery frame including a battery casing, the battery casing including a first side and a second side, the first side including a three-dimensional porous positive electrode current collector and the second side including a three-dimensional porous negative electrode current collector; (S2) introducing a positive electrode active material to the pores formed in the positive electrode current collector, and introducing a negative electrode active material to the pores formed in the negative electrode current collector; and (S3) pressing the battery casing to deform the battery casing into a predetermined shape.