Disclosed herein are ceramic selective membranes and methods of forming the ceramic selective membranes by forming a selective silica ceramic on a porous membrane substrate.

A porous membrane material comprising a porous membrane substrate coated with a thin, uniform coating of a metal or metal alloy. The membrane material can have high electrical conductivity. The membrane material can exhibit a very high ratio of electrical conductivity to thermal conductivity. The porous membrane substrate may be removed to form the membrane.

An electrolyte membrane including (i) a porous mat of nanofibres, wherein the nanofibres are composed of a non-ionically conducting heterocyclic-based polymer, the heterocyclic-based polymer comprising basic functional groups and being soluble in organic solvent; and (ii) an ion-conducting polymer which is a partially- or fully-fluorinated sulphonic acid polymer. The porous mat is essentially fully impregnated with ion-conducting polymer, and the thickness of the porous mat in the electrolyte membrane is distributed across at least 80% of the thickness of the electrolyte membrane. Such a membrane is of use in a proton exchange membrane fuel cell or an electrolyser.

A fuel cell membrane electrode assembly includes a substrate and a porous polymer membrane. The substrate includes a woven layer including a yarn of polyvinylidene fluoride (PVDF) fiber. The yarn is 7 to 25 denier. The substrate also includes a nanofiber layer including PVDF nanofibers deposited on the woven layer. The nanofiber layer is 1 to 10 micrometers (μm) thick. The substrate exhibits a porosity of at least 70 percent and is less than 30 μm thick. The porous polymer membrane is deposited on the nanofiber layer. The substrate is a porous support for a fuel cell membrane. A method of forming a fuel cell membrane electrode assembly includes weaving a woven layer of a yarn including fiber of PVDF. The method also includes depositing a nanofiber layer on the woven layer to form a substrate. The method further includes depositing a porous polymer membrane on the nanofiber layer.

A fuel cell membrane electrode assembly includes a substrate and a porous polymer membrane. The substrate includes a woven layer including a yarn of polyvinylidene fluoride (PVDF) fiber. The yarn is 7 to 25 denier. The substrate also includes a nanofiber layer including PVDF nanofibers deposited on the woven layer. The nanofiber layer is 1 to 10 micrometers (μm) thick. The substrate exhibits a porosity of at least 70 percent and is less than 30 μm thick. The porous polymer membrane is deposited on the nanofiber layer. The substrate is a porous support for a fuel cell membrane. A method of forming a fuel cell membrane electrode assembly includes weaving a woven layer of a yarn including fiber of PVDF. The method also includes depositing a nanofiber layer on the woven layer to form a substrate. The method further includes depositing a porous polymer membrane on the nanofiber layer.

An anion exchange membrane is made by mixing 2 trifluoroMethyl Ketone [nominal] (1.12 g, 4.53 mmol), 1 BiPhenyl (0.70 g, 4.53 mmol), methylene chloride (3.0 mL). trifluoromethanesulfonic acid (TFSA) (3.0 mL) to produce a pre-polymer. The pre-polymer is then functionalized to produce an anion exchange polymer. The pre-polymer may be functionalized with trimethylamamine in solution with water. The pre-polymer may be imbibed into a porous scaffold material, such as expanded polytetrafluoroethylene to produce a composite anion exchange membrane.

A substrate for a composite membrane includes a microporous polyolefin membrane for carrying a hydrophilic resin compound within the pores of the microporous membrane wherein: the average pore diameter is 1 nm to 50 nm; the porosity is 50% to 78%; the membrane thickness is 1 μm to 12 μm; and, when a mixed solution of ethanol and water (volume ratio 1/2) is dripped onto a surface of the microporous polyolefin membrane which has not undergone hydrophilization treatment, the contact angle θ1 between the droplet and the surface is 0 to 90 degrees 1 second after the dripping, and the contact angle θ2 between the droplet and the surface is 0 to 70 degrees 10 minutes after the dripping, and the rate of change of the contact angle ((θ1−θ2)/θ1×100) is 10 to 50%.

A substrate for a composite membrane includes a microporous polyolefin membrane for carrying a hydrophilic resin compound within the pores of the microporous membrane wherein: the average pore diameter is 1 nm to 50 nm; the porosity is 50% to 78%; the membrane thickness is 1 μm to 12 μm; and, when a mixed solution of ethanol and water (volume ratio 1/2) is dripped onto a surface of the microporous polyolefin membrane which has not undergone hydrophilization treatment, the contact angle θ1 between the droplet and the surface is 0 to 90 degrees 1 second after the dripping, and the contact angle θ2 between the droplet and the surface is 0 to 70 degrees 10 minutes after the dripping, and the rate of change of the contact angle ((θ1−θ2)/θ1×100) is 10 to 50%.

The present disclosure relates to a method of manufacturing an electrolyte membrane for fuel cells capable of effectively removing hydrogen and/or air crossing over. Specifically, the method includes coating a slurry including at least an ionomer on a substrate to manufacture an ion transfer layer, manufacturing a laminate including the substrate and the ion transfer layer, and providing a pair of laminates to form an electrolyte membrane, wherein the ion transfer layer has a catalyst region formed at one side thereof based on a width-direction center line thereof, the catalyst region including a catalyst.

The present disclosure relates to a method of manufacturing an electrolyte membrane for fuel cells capable of effectively removing hydrogen and/or air crossing over. Specifically, the method includes coating a slurry including at least an ionomer on a substrate to manufacture an ion transfer layer, manufacturing a laminate including the substrate and the ion transfer layer, and providing a pair of laminates to form an electrolyte membrane, wherein the ion transfer layer has a catalyst region formed at one side thereof based on a width-direction center line thereof, the catalyst region including a catalyst.