In various embodiments, a solid oxide fuel cell is fabricated in part by disposing a functional layer between the cathode and the solid electrolyte.

Electrochemical systems for distributed energy generation, comprising protonic ceramic fuel cells (PCFCs), are provided. The systems of the present invention allow for operation at lower stack temperatures than current solid oxide fuel cell (SOFC) systems. These systems can achieve various advantages and benefits over SOFC systems, such as higher fuel utilization, improved cell voltage, and air ratio optimization.

Herein discussed is a method of using an oxide ion conducting membrane comprising exposing the oxide ion conducting membrane to a reducing environment on both sides of the membrane. In an embodiment, the oxide ion conducting membrane also conducts electrons. In various embodiments, the membrane is impermeable to fluid flow (e.g., having a permeability of less than 1 micro darcy). In an embodiment, the oxide ion conducting membrane comprises lanthanum chromite and a material selected from the group consisting of doped ceria, yttria-stabilized zirconia (YSZ), lanthanum strontium gallate magnesite (LSGM), scandia-stabilized zirconia (SSZ), Sc and Ce doped zirconia, and combinations thereof. In an embodiment, the lanthanum chromite comprises undoped lanthanum chromite, strontium doped lanthanum chromite, iron doped lanthanum chromite, strontium and iron doped lanthanum chromite, lanthanum calcium chromite, or combinations thereof. In an embodiment, the membrane is mixed conducting.

Herein discussed is a method of using an oxide ion conducting membrane comprising exposing the oxide ion conducting membrane to a reducing environment on both sides of the membrane. In an embodiment, the oxide ion conducting membrane also conducts electrons. In various embodiments, the membrane is impermeable to fluid flow (e.g., having a permeability of less than 1 micro darcy). In an embodiment, the oxide ion conducting membrane comprises lanthanum chromite and a material selected from the group consisting of doped ceria, yttria-stabilized zirconia (YSZ), lanthanum strontium gallate magnesite (LSGM), scandia-stabilized zirconia (SSZ), Sc and Ce doped zirconia, and combinations thereof. In an embodiment, the lanthanum chromite comprises undoped lanthanum chromite, strontium doped lanthanum chromite, iron doped lanthanum chromite, strontium and iron doped lanthanum chromite, lanthanum calcium chromite, or combinations thereof. In an embodiment, the membrane is mixed conducting.

The invention related to metal-supported solid oxide fuel cells (SOFC), fuel cell stacks containing the same, methods of their manufacture and use thereof. The SOFC of the invention utilizes an extended electrolyte and barrier layers to prevent specific types of corrosion of the metal substrate. This new coating approach reduces the rate of degradation of the fuel cells and improves system reliability when operated over long durations.

The invention related to metal-supported solid oxide fuel cells (SOFC), fuel cell stacks containing the same, methods of their manufacture and use thereof. The SOFC of the invention utilizes an extended electrolyte and barrier layers to prevent specific types of corrosion of the metal substrate. This new coating approach reduces the rate of degradation of the fuel cells and improves system reliability when operated over long durations.

A solid oxide electrochemical cell includes an oxygen electrode containing a strontium-containing perovskite-type composite oxide represented by Ln.sub.1-xSr.sub.xCo.sub.1-y-zFe.sub.yB.sub.zO.sub.3-δ (Ln is a trivalent lanthanide element, B is a tetravalent element, 0<x<1, 0≤y<1, 0<z<1, and 0<z+y<1, and δ is a value that is determined to satisfy charge neutrality conditions), a solid electrolyte containing zirconium oxide, a hydrogen electrode, and an interlayer containing a rare-earth-doped cerium oxide that is provided between the solid electrolyte and the oxygen electrode.

The present specification relates to a sheet laminate for a solid oxide fuel cell, a precursor for a solid oxide fuel cell including the same, an apparatus for manufacturing a sheet laminate for a solid oxide fuel cell, and a method for manufacturing a sheet laminate for a solid oxide fuel cell.

The present specification relates to a sheet laminate for a solid oxide fuel cell, a precursor for a solid oxide fuel cell including the same, an apparatus for manufacturing a sheet laminate for a solid oxide fuel cell, and a method for manufacturing a sheet laminate for a solid oxide fuel cell.

In various embodiments, a solid oxide fuel cell features a functional layer for reducing interfacial resistance between the cathode and the solid electrolyte.