In at least one embodiment, a separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. New or improved mats, separators, batteries, methods, and/or systems are also disclosed, shown, claimed, and/or provided. For example, in at least one possibly preferred embodiment, a composite separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. In at least one possibly particularly preferred embodiment, a PE membrane separator is provided with at least one fibrous mat for retaining the active material on an electrode of a lead-acid battery. In accordance with at least certain embodiments, aspects and/or objects, the present invention, application, or disclosure may provide solutions, new products, improved products, new methods, and/or improved methods, and/or may address issues, needs, and/or problems of PAM shedding, NAM shedding, electrode distortion, active material shedding, active material loss, and/or physical separation, electrode effectiveness, battery performance, battery life, and/or cycle life, and/or may provide new battery separators, new battery technology, and/or new battery methods and/or systems that address the challenges arising from current lead acid batteries or battery systems, especially new battery separators, new battery technology, and/or new battery methods and/or systems adapted to prevent or impede the shedding of active material from the electrodes, preferably or particularly in enhanced flooded lead acid batteries, PSoC batteries, ISS batteries, ESS batteries, and/or the like.

In at least one embodiment, a separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. New or improved mats, separators, batteries, methods, and/or systems are also disclosed, shown, claimed, and/or provided. For example, in at least one possibly preferred embodiment, a composite separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. In at least one possibly particularly preferred embodiment, a PE membrane separator is provided with at least one fibrous mat for retaining the active material on an electrode of a lead-acid battery. In accordance with at least certain embodiments, aspects and/or objects, the present invention, application, or disclosure may provide solutions, new products, improved products, new methods, and/or improved methods, and/or may address issues, needs, and/or problems of PAM shedding, NAM shedding, electrode distortion, active material shedding, active material loss, and/or physical separation, electrode effectiveness, battery performance, battery life, and/or cycle life, and/or may provide new battery separators, new battery technology, and/or new battery methods and/or systems that address the challenges arising from current lead acid batteries or battery systems, especially new battery separators, new battery technology, and/or new battery methods and/or systems adapted to prevent or impede the shedding of active material from the electrodes, preferably or particularly in enhanced flooded lead acid batteries, PSoC batteries, ISS batteries, ESS batteries, and/or the like.

There is provided a method for producing a separator for an electricity storage device that includes a step of contacting a porous body formed from a silane-modified polyolefin-containing molded sheet with a base solution or acid solution, and a separator for an electricity storage device comprising a microporous film with a melted film rupture temperature of 180° C. to 220° C. as measured by thermomechanical analysis (TMA).

Embodiments of this application provide a battery separator, including a polyolefin-based porous separator, where the polyolefin-based porous separator includes polyethylene resin, an elongation rate of the polyolefin-based porous separator in an MD direction is greater than 120%, an elongation rate in a TD direction is greater than 120%, and for the polyolefin-based porous separator, crystallinity at a first-time temperature rise of polyethylene that is measured by using a differential scanning calorimeter is less than 65%, crystallinity at a second-time temperature rise is less than 55%, and a difference between the crystallinity at the first-time temperature rise and the crystallinity at the second-time temperature rise is less than 12%. The battery separator features a high elongation rate and a low temperature of closing a pore.

Embodiments of this application provide a battery separator, including a polyolefin-based porous separator, where the polyolefin-based porous separator includes polyethylene resin, an elongation rate of the polyolefin-based porous separator in an MD direction is greater than 120%, an elongation rate in a TD direction is greater than 120%, and for the polyolefin-based porous separator, crystallinity at a first-time temperature rise of polyethylene that is measured by using a differential scanning calorimeter is less than 65%, crystallinity at a second-time temperature rise is less than 55%, and a difference between the crystallinity at the first-time temperature rise and the crystallinity at the second-time temperature rise is less than 12%. The battery separator features a high elongation rate and a low temperature of closing a pore.

A bipolar lead-acid battery is described in which the electrolyte is less likely to infiltrate the interface between a positive electrode lead layer and an adhesive layer so that deterioration in battery performance is less likely to occur. A positive electrode of a bipolar electrode of the battery includes a positive electrode lead layer disposed on one surface of a substrate. An adhesive layer is disposed between and bonds the one surface and the positive electrode lead layer. The substrate is formed of a thermoplastic resin, and the adhesive layer is a cured product of a reaction-curing type adhesive that is cured by reaction between a main agent containing an epoxy resin and a curing agent containing an amine compound. Even when immersed in sulfuric acid with a concentration of 38% by mass at a temperature of 60° C. for four weeks, the sulfuric acid does not infiltrate the interface.

A bipolar lead-acid battery is described in which the electrolyte is less likely to infiltrate the interface between a positive electrode lead layer and an adhesive layer so that deterioration in battery performance is less likely to occur. A positive electrode of a bipolar electrode of the battery includes a positive electrode lead layer disposed on one surface of a substrate. An adhesive layer is disposed between and bonds the one surface and the positive electrode lead layer. The substrate is formed of a thermoplastic resin, and the adhesive layer is a cured product of a reaction-curing type adhesive that is cured by reaction between a main agent containing an epoxy resin and a curing agent containing an amine compound. Even when immersed in sulfuric acid with a concentration of 38% by mass at a temperature of 60° C. for four weeks, the sulfuric acid does not infiltrate the interface.

An energy storage device according to an aspect of the present invention includes: a negative electrode including a negative substrate made of pure aluminum or an aluminum alloy, a conductive layer directly or indirectly layered on the negative substrate and containing a conductive agent, and a negative active material layer containing a negative active material capable of occluding lithium ions at a potential of 0.05 V vs. Li/Li.sup.+ or lower; and a positive electrode opposed to the negative electrode and including a positive substrate and a positive active material layer directly or indirectly layered on the positive substrate, and the negative active material layer is layered on the negative substrate and the conductive layer so as to include a region in contact with the negative substrate and a region in contact with the conductive layer.

A lithium-ion battery, including a battery cell, an electrolytic solution, and a packaging film. The battery cell is formed by winding a positive electrode plate and a negative electrode plate that are separated by a separator. The lithium-ion battery is half-charged to obtain a half-charged full battery. The half-charged full battery is stripped of the packaging film to obtain a half-charged cell. When a width of the half-charged full battery is w.sub.1, a width of the half-charged cell is w.sub.2, and g=w.sub.2/w.sub.1, the following conditional expression (1) is satisfied: 0.4<g<0.997. A negative active material of the negative electrode plate includes a silicon-based material. When a capacity per unit volume of the negative electrode plate is a, a and g satisfy the following conditional expression (2): 420 mAh/cm.sup.3<g×a<2300 mAh/cm.sup.3, where 619 mAh/cm.sup.3<a<3620 mAh/cm.sup.3. The present invention further provides an electronic device.

A lithium-ion battery, including a battery cell, an electrolytic solution, and a packaging film. The battery cell is formed by winding a positive electrode plate and a negative electrode plate that are separated by a separator. The lithium-ion battery is half-charged to obtain a half-charged full battery. The half-charged full battery is stripped of the packaging film to obtain a half-charged cell. When a width of the half-charged full battery is w.sub.1, a width of the half-charged cell is w.sub.2, and g=w.sub.2/w.sub.1, the following conditional expression (1) is satisfied: 0.4<g<0.997. A negative active material of the negative electrode plate includes a silicon-based material. When a capacity per unit volume of the negative electrode plate is a, a and g satisfy the following conditional expression (2): 420 mAh/cm.sup.3<g×a<2300 mAh/cm.sup.3, where 619 mAh/cm.sup.3<a<3620 mAh/cm.sup.3. The present invention further provides an electronic device.