In a non-aqueous electrolyte secondary battery according to one exemplary embodiment, a separator includes a substrate, a first filler layer containing phosphate particles and formed on at least one surface of the substrate, and a second filler layer containing inorganic particles and formed on a surface of the first filler layer on the side of the at least one surface of the substrate. The phosphate particles have a BET specific surface area of 5 m.sup.2/g or more and 100 m.sup.2/g or less.

A separator for a secondary battery having a separator substrate and a coating layer formed on the separator substrate. The coating layer is on at least one surface of the separator substrate. The coating layer comprises an acrylate-based binder and an additive. The additive is a fluorine-based non-ionic surfactant, and provides a separator for a secondary battery with significantly improved electrolyte impregnation rate.

A separator for a secondary battery having a separator substrate and a coating layer formed on the separator substrate. The coating layer is on at least one surface of the separator substrate. The coating layer comprises an acrylate-based binder and an additive. The additive is a fluorine-based non-ionic surfactant, and provides a separator for a secondary battery with significantly improved electrolyte impregnation rate.

Microporous sheet product and methods of making and using the same. In one embodiment, the microporous sheet product is made by a process that includes melt-extruding a sheet material using an extrusion mixture that includes a thermoplastic polymer, a superabsorbent polymer, and a compatibilizing agent. After extrusion, the compatibilizing agent may be removed from the sheet material. When the sheet product is imbibed with a polar or ion-containing liquid, the superabsorbent polymer swells, causing a reduction in the pore size of the sheet product. The exposure also causes some of the superabsorbent polymer to migrate to the exterior of the microporous sheet product. The microporous sheet product may be used, for example, as a battery separator, as a food packaging material, as a diffusion barrier in the ultrafiltration of colloidal matter, and in disposable garments.

A thin separator for electrochemical elements, which has achieved chemical stability, while maintaining a good balance among short-circuit resistance, resistivity, electrolyte solution impregnability and electrolyte solution retainability of the separator. A separator for electrochemical elements, which is interposed between a pair of electrodes so as to separate the electrodes from each other, and which holds an electrolyte solution. This separator for electrochemical elements is composed of beaten cellulose fibers and thermoplastic synthetic fibers, and has a thickness of 5.0-30.0 μm and a density of 0.50-0.75 g/cm.sup.3; and the thickness X (μm) and the air resistance Y (second/100 ml) of this separator for electrochemical elements satisfy formula 1:
Y≥0.01X.sup.2−0.6X+11.5.

A ceramic-coated battery separator having a microporous polyolefin membrane and a ceramic coating on at least one surface of the microporous polyolefin membrane, wherein the ceramic-coated separator exhibits a strain shrinkage of 0% at temperatures greater than or equal to 120 degrees Celsius is provided.

A lithium ion conducting protective film produced using a layer-by-layer assembly process. The lithium ion conducting protective film is assembled on a substrate by a sequential exposure of the substrate to a first poly(ethylene oxide) (PEO) layer including a cross-linking silane component on the first side of the substrate, a graphene oxide (GO) layer on the first PEO layer, a second poly(ethylene oxide) (PEO) layer including a cross-linking silane component on the GO layer and a poly(acrylic acid) (PAA) layer on the second PEO layer. The film functions as a lithium ion conducting protective film that isolates the lithium anode from the positive electrochemistry of the cathode in a lithium-air battery, thereby preventing undesirable lithium dendrite growth.

A lithium ion conducting protective film produced using a layer-by-layer assembly process. The lithium ion conducting protective film is assembled on a substrate by a sequential exposure of the substrate to a first poly(ethylene oxide) (PEO) layer including a cross-linking silane component on the first side of the substrate, a graphene oxide (GO) layer on the first PEO layer, a second poly(ethylene oxide) (PEO) layer including a cross-linking silane component on the GO layer and a poly(acrylic acid) (PAA) layer on the second PEO layer. The film functions as a lithium ion conducting protective film that isolates the lithium anode from the positive electrochemistry of the cathode in a lithium-air battery, thereby preventing undesirable lithium dendrite growth.

A separator for a rechargeable battery includes a porous substrate and a heat resistance layer on at least one surface of the porous substrate. The heat resistance layer includes an acryl-based copolymer, an alkali metal, and a filler. The acryl-based copolymer includes a unit derived from (meth)acrylate or (meth)acrylic acid, a cyano group-containing unit, and a sulfonate group-containing unit.

A separator for a rechargeable battery includes a porous substrate and a heat resistance layer on at least one surface of the porous substrate. The heat resistance layer includes an acryl-based copolymer, an alkali metal, and a filler. The acryl-based copolymer includes a unit derived from (meth)acrylate or (meth)acrylic acid, a cyano group-containing unit, and a sulfonate group-containing unit.