An energy storage device, such as a silver oxide battery, can include a silver-containing cathode and an electrolyte having an ionic liquid. An anion of the ionic liquid is selected from the group consisting of: methanesulfonate, methylsulfate, acetate, and fluoroacetate. A cation of the ionic liquid can be selected from the group consisting of: imidazolium, pyridinium, ammonium, piperidinium, pyrrolidinium, sulfonium, and phosphonium. The energy storage device may include a printed or non-printed separator. The printed separator can include a gel including dissolved cellulose powder and the electrolyte. The non-printed separator can include a gel including at least partially dissolved regenerate cellulose and the electrolyte. An energy storage device fabrication process can include applying a plasma treatment to a surface of each of a cathode, anode, separator, and current collectors. The plasma treatment process can improve wettability, adhesion, electron and/or ionic transport across the treated surface.

Provided are a separator for a nonaqueous cell that has air permeability and is small in thickness while maintaining strength properties; and a nonaqueous cell having this separator. The separator includes a fiber sheet in which a polyvinyl alcohol fiber is incorporated in a proportion of 30% or more by mass (based on the fiber sheet). The fiber has a fiber breaking temperature in heated water of lower than 100° C. and higher than 85° C.

This invention provides a multi-layer article comprising a first electrode material, a second electrode material, and a porous separator disposed between and in contact with the first and the second electrode materials, wherein the porous separator comprises a nonwoven consisting essentially of a plurality of fibers of a fully aromatic polyimide. Also provided is a method for preparing the multi-layer article, and an electrochemical cell employing the same. A multi-layer article comprising a polyimide nonwoven with enhanced properties is also provided.

The present invention relates to an electrochemical element and a method for producing same, the electrochemical element comprising: electrodes comprising a composite of active material and conductive material having a nanofiber structure; and a cellulose nanofiber separator combined with the electrodes. The electrochemical element according to the present invention obviates the need for separate binder and electrode current collector, has a stable interfacial surface due to the physical union of the separator and electrode, can assure superb mechanical and physical properties, and can maintain stable battery performance even against deformations due to a variety of external impact.

There is disclosed a cartridge for a portable electronic device power system configured as a flat, prismatic, air-breathing zinc-air battery comprising (a) an anode assembly having a structural backbone, current collectors, and a gel solution comprising a mixture of amalgamated zinc powder, aqueous potassium hydroxide and a gelling agent, (b) a porous separator sheet, and (c) an air-breathing cathode having an electrode impregnated with reductive catalyst, and (d) a serialized electrical connectivity path having low ohmic resistance characteristics. More specifically, there is disclosed a prismatic format, flat rectangular disposable primary battery having two or more zinc-air batteries connected in series, wherein each zinc air battery comprises: (a) an anode assembly having a structural backbone, current collectors, and a gel solution comprising a mixture of amalgamated zinc powder, aqueous potassium hydroxide and a gelling agent, (b) a porous separator sheet, and (c) a catalytically active oxygen-reductive cathode.

The present invention relates to a porous sheet comprising cellulose fibers having an average fiber diameter ranging from 20 to 500 nm; cut fibers having an average fiber diameter ranging from 1.5 to 20 μm; and a hydrophilic polymer binder, wherein an amount of the cut fibers is 1% by weight or more and 80% by weight or less based on the total weight of the cellulose fibers and the cut fibers, and an amount of the hydrophilic polymer binder is 5 parts by weight or more and 30 parts by weight or less with respect to 100 parts by weight of the total weight of the cellulose fibers and the cut fibers. The porous sheet of the present invention can exhibit a superior strength (in particular, both tear strength and tensile strength), and exhibits a superior performance as a separator for an electrochemical device.

The present invention relates to an electrochemical element and a method for producing same, the electrochemical element comprising: electrodes comprising a composite of active material and conductive material having a nanofiber structure; and a cellulose nanofiber separator combined with the electrodes. The electrochemical element according to the present invention obviates the need for separate binder and electrode current collector, has a stable interfacial surface due to the physical union of the separator and electrode, can assure superb mechanical and physical properties, and can maintain stable battery performance even against deformations due to a variety of external impact.

Provided is a nonaqueous electrolyte secondary battery in which the generation of gas is suppressed in charge/discharge cycles. The nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator placed therebetween, and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material containing a lithium transition metal oxide. The positive electrode contains tungsten oxide. Tungsten is present in the form of a solid solution in the lithium transition metal oxide. Tungsten oxide is attached to the surface of the lithium transition metal oxide. The separator contains cellulose. Tungsten in tungsten oxide contained in the positive electrode is preferably 0.01 mole percent to 3.0 mole percent with respect to transition metals, excluding lithium, in the lithium transition metal oxide.

Provided are a functional coating material for a lithium ion battery separator and a preparation method therefor. The functional coating material for a lithium ion battery separator comprises 1-15% mass fraction of inorganic nanoparticles, 8-30% mass fraction of nanofibers and 1-5% mass fraction of an adhesive, and the remainder being a solvent. The preparation method therefor comprises the following steps: (1) preparing the nanofibers as a spinning precursor liquid; (2) preparing a dispersion liquid with the inorganic nanoparticles and the spinning precursor liquid; and (3) adding the adhesive to the dispersion liquid, and mixing same until uniform to obtain the functional coating material for a lithium ion battery separator.

Disclosed herein is a separator for an electrochemical element, comprising a fibrous structure, wherein the fibrous structure has a first fibrous layer part in which short fibers and/or pulp-like fibers are intertwined with each other, and a second fibrous layer part; some of the short fibers and/or the pulp-like fibers constituting the first fibrous layer part penetrates the second fibrous layer part; and a pore diameter distribution of the fibrous structure satisfies the following formula: 0 μm<Dmax<18 μm, and 0 μm≤(Dmax−Dave)<13 μm, wherein Dmax is a maximum pore diameter (μm) of the fibrous structure, and Dave is an average pore diameter (μm) of the fibrous structure.