The present embodiments provide a separator, a process for preparing the same, a lithium ion secondary battery, a battery module, a battery pack and an apparatus. The separator provided by the present application comprises a porous base film and a functional coating disposed on at least one surface of the porous base film, wherein the functional coating comprises polyimide nanosheets, and the polyimide nanosheets are stacked irregularly to form a lamellar loose structure; and a thickness ratio of the functional coating to the porous base film is from 0.1 to 1.0. The present application also provides a process for preparing the separator, and a lithium ion secondary battery and an apparatus comprising the separator.

According to one embodiment, an electrode construct including an electrode and a composite membrane is provided. The electrode includes an active material-containing layer and a current collecting layer. The active material-containing layer includes a first principal surface and a second principal surface. The current collecting layer is in contact with the second principal surface. The composite membrane includes a composite layer in contact with the first principal surface. The composite layer contains inorganic solid particles and a polymeric material. A peel strength σ1 at a first interface between the active material-containing layer and the composite layer and a peel strength σ2 at a second interface between the active material-containing layer and the current collecting layer satisfy a relationship of σ1>σ2, and σ2≤1 N/cm.

Rechargeable batteries and corresponding methods are provided, in which zinc dendrite growth to a compartment between a zinc-based anode and a separator of a rechargeable battery is limited, by preventing zincate anions from diffusing outside of the compartment. Separators limiting dendrite growth may comprise ion-selective membrane(s) configured to be permeable to charge transfer cations of the alkaline electrolyte and impermeable to hydrated zincate anions. The membrane(s) may be reinforced and/or support internal compartment(s) with electrolyte lacking zincate ions. More generally, separators are provided, which are permeable to charge transfer ions but impermeable to metal ions, and limit the latter to the anode compartment in which the metal ions may be deposited in a manner that does not form dendrites which can compromise the structural and functional integrity of the battery cell.

An electrospun coated component for a lead acid battery is disclosed. The electrospun coated component includes positive electrode, negative electrode, and separator. The separator may comprise a low-conducting and/or non-conductive material. A method of electrospun coating these components of a LAB is provided. Suitable compositions and conditions for electrospun coating on to LAB components are further provided in this disclosure.

A porous film having favorable characteristics is manufactured. A method of manufacturing the porous film of the present invention includes: (a) a step of modifying a first filler to be hydrophobic by mixture of the first filler and an additive; (b) a step of forming a coating liquid by mixture of the hydrophobic first filler, a second filler and solvent; and (c) a step of forming a coating film (CF) by application of the coating liquid onto a surface of a porous base substance (S). In the step (a), the first filler is a cellulose, and a hydrophilic group of the cellulose is substituted with a hydrophobic group by a reaction between the cellulose and the additive. When the coating film is formed on the surface of the porous base substance as described above, mechanical strength and heat resistance of the porous film (separator) can be improved. For example, thermal deformation of the porous film (separator) can be equal to or lower than 5%.

A positive electrode active material for an electrochemical device has a fiber shape or a grain-aggregate shape. The positive electrode active material includes an inner core part having a fiber shape or a grain-aggregate shape, and a superficial part covering at least part of the inner core part. The inner core part contains a first conductive polymer, and the superficial part contains a second conductive polymer that is different from the first conductive polymer.

The present disclosure is applicable to the technical field related to a secondary battery, and relates to, for example, a separator structure for the secondary battery, a method for preparing the same, and the secondary battery using the same. A separator structure disposed inside a secondary battery includes a porous support body including a first face and a second face, and a cellulose nano fiber subjected to an ionic surface treatment located on at least one of the first face and the second face of the support body.

An electrolyte is disclosed, for example for use in a capacitor or in a battery. An electrolyte comprises a polysaccharide matrix; and carbon nanotubes embedded within the polysaccharide matrix. Further, apparatus comprising the electrolyte is disclosed. A method of manufacturing an electrolyte is disclosed. According to the method a polysaccharide solution is provided; carbon nanotubes are suspended within the polysaccharide solution; and the polysaccharide solution is dehydrated to obtain a gel.

A non-aqueous electrolyte battery of the present invention includes a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte, and the separator contains polyphenylenesulfide fibers, aramid fibers, and cellulose fibers at ratios of 50 to 85 mass %, 10 to 30 mass %, and 5 to 35 mass %, respectively. This makes it possible to provide a non-aqueous electrolyte battery with characteristics that are less likely to deteriorate under a high-temperature environment and in which few defects occur during assembly.

A non-aqueous electrolyte secondary battery includes an electrode array and an electrolyte solution. The electrode array includes a positive electrode that includes a positive electrode current collector and a positive electrode composite material layer; a negative electrode that includes a negative electrode current collector and a negative electrode composite material layer; and a separator. The electrode array includes cellulose nanofibers. At least one of the peel strength between the positive electrode current collector and the positive electrode composite material layer and the peel strength between the negative electrode current collector and the negative electrode composite material layer is smaller than both the peel strength between the separator and the positive electrode composite material layer and the peel strength between the separator and the negative electrode composite material layer. The greater of the two peel strengths is at least 1.5 times greater than the smaller of the two.