Electrolytes and electrolyte additives for energy storage devices comprising phosphazene based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a phosphazene based compound.

The present disclosure discloses a primary lithium battery comprising a reactive solid cathode, a liquid electrolyte, a separator, and a lithium anode. The liquid electrolyte is ionic conductive and is configured to undergo a series coupling reaction after solid phase reaction of the reactive solid cathode and the lithium anode. The liquid electrolyte comprises a solvent and an electrolyte salt, and a concentration of the electrolyte salt in the liquid electrolyte is 0.1-3 mol/L. The solvent comprises a sulfite ester type compound and an organic solvent, and a concentration of the sulfite ester type compound in the organic solvent is 5 wt % to 90 wt %.

[Problem] To provide a separator (AGM separator) for valve-regulated lead acid batteries that does not undergo delamination due to bonding between the separators even under severe conditions (a pressure in winding, a high temperature and a high humidity in transportation and storage).

[Means for Resolution] A separator (AGM separator) for valve-regulated lead acid batteries, containing a microglass fiber and a heat-fusible organic fiber, the separator having a thickness under a pressure of 20 kPa of more than 0.50 mm and less than 1.80 mm and having a bonding strength between the separators after being left for 48 hours under a pressure of 5 to 10 kPa in an environment of a temperature of 70° C. and a humidity of 75′% of less than 0.10 N.
[Selected Drawing] None

[Problem] To provide a separator (AGM separator) for valve-regulated lead acid batteries that does not undergo delamination due to bonding between the separators even under severe conditions (a pressure in winding, a high temperature and a high humidity in transportation and storage).

[Means for Resolution] A separator (AGM separator) for valve-regulated lead acid batteries, containing a microglass fiber and a heat-fusible organic fiber, the separator having a thickness under a pressure of 20 kPa of more than 0.50 mm and less than 1.80 mm and having a bonding strength between the separators after being left for 48 hours under a pressure of 5 to 10 kPa in an environment of a temperature of 70° C. and a humidity of 75′% of less than 0.10 N.
[Selected Drawing] None

[Problem] To provide a nonwoven fabric (pasting mat) that does not undergo bonding between the nonwoven fabrics (pasting mats) even under severe conditions (a pressure in winding and a high temperature and a high humidity in transportation, storage, and production).

[Means for Resolution] A pasting mat for lead acid batteries, containing a microglass fiber and a heat-fusible binder fiber, the pasting mat having a thickness under a pressure of 20 kPa of 0.1 mm or more and 0.5 mm or less, and having a bonding strength between the pasting mats after being left for 48 hours under a pressure of 5 to 10 kPa in an environment of a temperature of 70 to 90° C. and a humidity of 75% of less than 0.05 N.

[Problem] To provide a nonwoven fabric (pasting mat) that does not undergo bonding between the nonwoven fabrics (pasting mats) even under severe conditions (a pressure in winding and a high temperature and a high humidity in transportation, storage, and production).

[Means for Resolution] A pasting mat for lead acid batteries, containing a microglass fiber and a heat-fusible binder fiber, the pasting mat having a thickness under a pressure of 20 kPa of 0.1 mm or more and 0.5 mm or less, and having a bonding strength between the pasting mats after being left for 48 hours under a pressure of 5 to 10 kPa in an environment of a temperature of 70 to 90° C. and a humidity of 75% of less than 0.05 N.

Provided are electrochemical cells including separators permeable to some materials and impermeable to other materials in electrolytes. Also provide are methods of forming such separators. The selective permeability of a separator is achieved by its specific pore diameter and a narrow distribution of this diameter. Specifically, a species responsible for ion transport in an electrochemical cell are allowed to pass through the separator, while another species is blocked thereby preventing degradation of the cell. For example, a species containing lithium ions is allowed to pass in rechargeable cells, while one or more species containing transition metals are blocked. In some embodiments, a separator may include a membrane layer with at least 90% of pores of this having a diameter of between about 0.1 nanometers and 1.0 nanometer. The membrane layer may be a standalone layer or supported by a membrane support.

Provided are electrochemical cells including separators permeable to some materials and impermeable to other materials in electrolytes. Also provide are methods of forming such separators. The selective permeability of a separator is achieved by its specific pore diameter and a narrow distribution of this diameter. Specifically, a species responsible for ion transport in an electrochemical cell are allowed to pass through the separator, while another species is blocked thereby preventing degradation of the cell. For example, a species containing lithium ions is allowed to pass in rechargeable cells, while one or more species containing transition metals are blocked. In some embodiments, a separator may include a membrane layer with at least 90% of pores of this having a diameter of between about 0.1 nanometers and 1.0 nanometer. The membrane layer may be a standalone layer or supported by a membrane support.

Battery separators, and lead-acid batteries comprising battery separators, are generally provided. In some embodiments, the battery separators described herein have one or more features that enhance their suitability for various applications (e.g., lead-acid battery applications). In one embodiment, a battery separator described herein comprises at least two phases. In some cases, each phase may have a one or more features that result in a battery separator having enhanced physical properties. For example, the dual-phase battery separator may exhibit reduced electrical and ionic resistance, enhanced acid filling capacity, reduced acid stratification, and enhanced thermal and oxidative stability compared to conventional battery separators.

Battery separators, and lead-acid batteries comprising battery separators, are generally provided. In some embodiments, the battery separators described herein have one or more features that enhance their suitability for various applications (e.g., lead-acid battery applications). In one embodiment, a battery separator described herein comprises at least two phases. In some cases, each phase may have a one or more features that result in a battery separator having enhanced physical properties. For example, the dual-phase battery separator may exhibit reduced electrical and ionic resistance, enhanced acid filling capacity, reduced acid stratification, and enhanced thermal and oxidative stability compared to conventional battery separators.