A degassing system of a pouch for a secondary battery is provided. In the degassing system, after inhaling gas regardless of the size of a cell pocket, the gas may be processed, and the convenience of work may be increased by setting the period of degassing time or the amount of gas to be discharged according to the size of a pouch, and an abnormality in a suction line for degassing may be automatically detected according to a comparison value by comparing the amount of discharged gas with a reference value preset by each pouch size.

Supplemental lithium can be used to stabilize lithium ion batteries with lithium rich metal oxides as the positive electrode active material. Dramatic improvements in the specific capacity at long cycling have been obtained. The supplemental lithium can be provided with the negative electrode, or alternatively as a sacrificial material that is subsequently driven into the negative electrode active material. The supplemental lithium can be provided to the negative electrode active material prior to assembly of the battery using electrochemical deposition. The positive electrode active materials can comprise a layered-layered structure comprising manganese as well as nickel and/or cobalt.

The present invention relates to a lithium secondary battery manufactured by forming a negative electrode free battery and then forming a lithium metal on the negative electrode current collector by charging.

In the lithium secondary battery, since lithium metal is formed on the negative electrode current collector in the state of being blocked with the atmosphere, the generation of the conventional surface oxide layer (native layer) formed on the negative electrode does not occur inherently, thereby preventing the reduction of the efficiency and lifetime characteristics of the battery.

Disclosed is an anodeless-type all-solid-state battery. The all-solid-state battery includes a plurality of recesses formed in an electrolyte layer and to be depressed from a surface of the electrolyte layer contacting an anode collector and thus serve as spaces for lithium to reversibly precipitate.

One or more trenches in a silicon substrate have an electrically active surface at a trench base and metal layer disposed on the electrically active surface. Precursor materials are disposed and/or formed on the metal layer in the trench. An anode is patterned either exclusively in the 3D trench or in the 3D trench, sidewalls and field of the substrate, where the anode patterning transforms and/or moves the precursor materials in the trench into some novel compositions of matter and other final operational structures for the device, e.g. layers of metallic Lithium for energy storage and different concentrations of Lithium-silicon species in the substrate. A multi-faceted mechanism is disclosed for Al2O3 silicon interfacial additives. When the anode is patterned both in and outside the 3D wells, Al2O3 provides an for electron-conductive Li-metal interface that enables homogenous plating on both the insulated substrate field as well as active silicon trench base where Al2O3 acts as a barrier to Li—Si diffusion. When the anode is patterned only in the 3D trench, Al2O3 additive creates a robust, flexible, Li-permeable interface upon charge cycling, which preserves the 3D textured structure of the porous silicon anode. Additionally, the Al2O3 additive is mobilized deeper into the bulk silicon in parallel with Li+ and a conductive plasticizer upon progressive cycling—where the lithiated Al2O3 particles nucleate at defect sites and prevent mechanical degradation of the silicon anode through a combined bridge and spacer mechanism. By selecting different defined anode patterns to deposit on the 3D substrate, final operational characteristics, properties, structures, and charge storage performance for the device can be predictably designed and manufactured.

A method for managing gas generated during a formation phase of a cell that is a hard-case electrochemical cell, the method may include supplying electrolyte to the cell; initially charging and discharging the cell during a formation phase; and permanently sealing the cell; wherein the method further comprises temporarily sealing the electrolyte during the formation phase.

A battery assembly disclosed herein is a battery assembly before being subjected to initial charge. In the battery assembly, a positive electrode has a positive electrode mixture layer that contains a positive electrode active material and NMP, and an oxalate complex compound and FSO.sub.3Li are contained in a nonaqueous electrolyte solution. In the battery assembly disclosed herein, a NMP content in the positive electrode mixture layer is 50 ppm to 1500 ppm, the DBP oil absorption of the positive electrode active material is 30 ml/100 g to 45 ml/100 g, and a FSO.sub.3Li content in the nonaqueous electrolyte solution is 0.1 wt % to 1.0 wt %. With this, it is possible to prevent a reduction in input-output characteristics caused by formation of a film derived from NMP on the surface of the positive electrode active material, and hence it is possible to prevent an increase in facility cost and a reduction in manufacturing efficiency caused by adjustment of the content of NMP.

The present invention provides a formation capacity-grading equipment with hot- and cold-press clamps for a soft-package lithium battery, which comprises a plurality of sets of capacity grading devices and a maintenance unit for connecting the capacity grading device, wherein the capacity grading devices are superimposed on each other to form a layered structure, and the capacity grading devices are kept to be axially parallel to each other; the maintenance unit is mounted lateral to the capacity grading devices; and the capacity grading device comprises an outer frame, a hot-press formation capacity grading hot-press clamp unit, a cold-press forming clamp unit, a charge and discharge formation control unit, a battery loading and unloading unit, a transplant manipulator unit, a production process control and detection and safety alarm unit, central controller, and a database unit.

A formation capacity-grading equipment for a cylindrical lithium-ion battery comprises a rack, a charge and discharge power box for charging and discharging the cylindrical lithium-ion battery, a battery clamping mechanism for clamping the positive and negative electrodes of the cylindrical lithium-ion battery, a battery tray for placing the cylindrical lithium-ion battery, and a controller, wherein the rack is provided with several layers of work stations for formation and capacity grading of the battery; the charge and discharge power box and the battery clamping mechanisms are provided at each layer of the work stations; a power transmission end of the charge and discharge power box is electrically connected to a power transmission end of the battery clamping mechanism; and a control end of the charge and discharge power box and a control end of the battery clamping mechanism are in signal connection respectively with a signal transmission port of the controller.

A manufacturing method for the formation of lithium, potassium, and/or calcium intercalation compounds on a negative electrode for a battery or capacitor cell is disclosed. The battery or capacitor cell is constructed with a negative electrode that may contain graphitic carbon, silicon, metal oxide, and/or complex metal oxides and a lithium, potassium, and/or calcium ion source supplemental electrode. After construction of the cell, a method of controlled electrical contact is applied between the positive electrode and negative electrode to accelerate and regulate a process of ion exchange between the supplemental metal ion source electrode and the negative electrode which results in the formation of intercalation compounds within the negative electrode, and produces a battery or capacitor with a higher working voltage, high cycle life, and long DC life.