Methods, systems, and techniques are provided for acquiring fuel cell polarization data, obtaining fuel cell polarization parameters from the fuel cell polarization data, and validating the reliability of the obtained data and parameters. In some aspects methods for acquiring and parameterizing proton exchange membrane fuel cell polarization data include measuring at least one current-voltage point for an operating fuel cell, and determining at least one polarization parameter of the fuel cell by evaluating a closed form solution using the at least one current-voltage point.

A fuel cell system for generating power by supplying a reaction gas to a fuel cell includes a wet state detection unit configured to detect a wet state of an electrolyte membrane of the fuel cell, a steady time target wet state setting unit configured to set a steady time target wet state of the electrolyte membrane during a steady operation of the fuel cell system based on an operating condition of the fuel cell system, and a transient time target wet state setting unit configured to set a transient time target wet state so that the wet state of the electrolyte membrane gradually changes from a wet state detected before a transient operation starts to the steady time target wet state during the transient operation in which the operating condition of the fuel cell system changes.

A hydrogen purging device for a fuel cell system includes a humidifier that humidifies dry air supplied from an air blower, using moist air discharged from a cathode of a stack and supplies the humidified air to the cathode. A water trap and a hydrogen recirculation blower are sequentially connected to an outlet of an anode, wherein a hydrogen outlet of the water trap and an inlet of the humidifier are connected by a cathode-hydrogen purging line for purging hydrogen to the cathode so that the hydrogen discharged from the anode of the fuel stack is purged to the cathode during idling or during normal driving.

A fuel cell system, including: an electric power generation control unit; an insulation-resistance measurement signal generation unit configured to generate a voltage-divided AC signal obtained by dividing an amplitude of a measurement AC signal; and an insulation resistance measurement unit configured to measure a resistance value of the insulation resistance, in which when the insulation resistance measurement unit detects, in a state where a voltage is maintained during an intermittent operation of the electric power generation control unit, an excessive noise state indicating a change in which a range of fluctuations of the peak value of the voltage-divided AC signal exceeds a predetermined allowable range of fluctuations, the insulation resistance measurement unit instructs the electric power generation control unit to change a fluctuation frequency of an output voltage of the fuel cell from a current frequency and then measures the resistance value of the insulation resistance.

A fuel cell system comprises a fuel cell; a reactive gas supply mechanism configured to supply a reactive gas to the fuel cell; a discharge flow path configured to discharge an off-gas and water discharged from the fuel cell; a valve provided in the discharge flow path; a remaining water purging controller configured to control a remaining water purging process of the fuel cell by using the reactive gas supply mechanism and the valve; a heating portion configured to heat the valve; and a failure detector configured to detect a failure of the heating portion. When a failure of the heating portion is detected, the remaining water purging controller performs the remaining water purging process and increases a water discharge power in the remaining water purging process than a water discharge power in the remaining water purging process performed when no failure of the heating portion is detected.

Methods and circuits for a device for interrupting concentration-related polarisation phenomenon and for self-cleaning of electromembrane processes by application of asymmetric inverse-polarity pulses with high intensity and variable frequency are described. The device, a bipolar switch, is based on the use of solid-state electronics to carry out polarity inversion in a range of frequencies, intensities and pulse widths to prevent or reduce formation of precipitates on the surfaces of the membranes. The inversion protocol, with a frequency that varies as a function of the appearance of dirt on the membranes, as measured by the decrease in voltage or electrical resistance of the membrane cell during electromembrane processes, is also provided. This device and configuration provides application of modulated and stable high-intensity pulses using a second power source. Electromembrane processes can be updated by replacing electrodes, suitable for polarity inversion, and adding a second power source and the bipolar switch described.

A method is provided for determining a spatial distribution (R.sub.x,y.sup.f) of a parameter of interest (R) representative of the electrical power production of an electrochemical cell, including steps of determining the spatial distribution (R.sub.x,y.sup.f) the parameter of interest (R) depending on a spatial distribution (Q.sub.x,y.sup.e) of a second thermal quantity (Q.sup.e) estimated beforehand from a spatial distribution (T.sub.x,y.sup.c) of a set-point temperature (T.sup.c) and from a spatial distribution (D.sub.x,y.sup.r) of a first thermal quantity (D.sup.r).

A fuel cell system and method, the system including power generating fuel cells disposed in a stack, each power generating fuel cell including an anode, a cathode, and an electrolyte, a sensing fuel cell including an anode, a cathode, and an electrolyte, and a fuel processor configured to purify a fuel provided to the power generating fuel cells and the sensing fuel cell. The anode of the sensing fuel cell is thinner than the anodes of the power generating fuel cells.

A method of operating a redox flow battery, may include maintaining a positive electrode compartment pressure greater than a negative electrode compartment pressure, and maintaining a cross-over pressure less than a membrane break-through pressure, wherein the cross-over pressure equals the negative electrode compartment pressure subtracted from the positive electrode compartment pressure. In this way, ionic resistance across the separator can be maintained at a lower level by reducing gas bubbles trapped therein while reducing separator break-through, thereby increasing performance of the redox flow battery system.

A system and method of controlling water imbalance in an electrochemical cell is provided. The method includes determining a present water imbalance in the electrochemical cell by summing a water.sub.in and a water.sub.created less a water.sub.out. Water.sub.in represents an amount of water introduced into the electrochemical cell by an oxidant feed gas; water.sub.created represents an amount of water created by the electrochemical cell from the electrochemical reaction; and water.sub.out represents an amount of water discharged from the electrochemical cell by an oxidant exhaust gas. The method includes tracking a cumulative water imbalance during operation of the electrochemical cell by repeatedly determining the present water imbalance and continuing to sum the results during operation. And, the method also includes adjusting a flow rate of the oxidant feed gas entering the electrochemical cell based on the cumulative water imbalance.