An electrolyte membrane and method for generating the membrane provide a resistance as low as possible to minimize ohmic losses. The membrane has a low permeability for redox-active species. If redox-active species still cross the membrane, this transport is balanced during charge and discharge preventing a net vanadium flux and associated capacity fading. The membrane is mechanically robust, chemically stable in electrolyte solution, and low cost. A family of ion exchange membranes including a bilayer architecture achieves these requirements. The bilayer membrane includes two polymers, i) a polymer including N-heterocycles with electron lone pairs acting as proton acceptor sites and ii) a mechanically robust polymer acting as a support, which can be a dense cation exchange membrane or porous support layer. This bilayer architecture permits a very thin polymer film on a supporting polymer to minimize ohmic resistance and tune electrolyte transport properties of the membrane.

A membrane electrode assembly includes an electrolyte membrane stacked between different electrodes, wherein an ionomer layer of the electrolyte membrane comprises an adjacent electrode, a first layer having at least a same cross-sectional area as that of the adjacent electrode, a reinforcing layer and a second layer stacked at a side of the first layer, the second layer having at least the same cross-sectional area as that of the reinforcing layer.

A method for bonding together two or more acid-doped polybenzimidazole films is provided. The method includes, in the following order: placing a first acid-doped polybenzimidazole film on a first substrate to form a first film/substrate assembly and placing a second acid-doped polybenzimidazole film on a second substrate to form a second film/substrate assembly; heating the first and second film/substrate assemblies to a temperature sufficient to soften the first and second acid-doped polybenzimidazole films; positioning the second film/substrate assembly atop the first film/substrate assembly, such that polybenzimidazole polymer chains of the first acid-doped polybenzimidazole film interact with polybenzimidazole polymer chains of the second acid-doped polybenzimidazole film; and re-hydrolyzing the first and second acid-doped polybenzimidazole films, such that the polybenzimidazole polymer chains of the first and second acid-doped polybenzimidazole films are therefore reformed and interlocked with each other to bond together the first and second acid-doped polybenzimidazole films.

A press forming method uses a press forming apparatus for forming a film formed product as a formed film of a solid polymer electrolyte fuel cell. The method includes the step of trimming, in the state where a film material is held between a first die and a holder, by moving a second die closer to the first die to cut the film material using a trimming blade provided for the second die. A blade edge of the trimming blade includes two inclined blade edges inclined toward a proximal side of a blade part from the center to both ends of the blade part in the direction in which the blade part extends.

A post-processing method of a polymer electrolyte membrane, which anneals and stretches a polymer electrolyte membrane including a hydrocarbon-based copolymer in a vapor atmosphere of a solvent.

A humidifier comprises hollow shell and humidifier core. The humidifier core includes a transfer sheet, a plurality of first channels, and a plurality of second channels. The transfer sheet comprises a permeable material having a plurality of sections and a plurality of layers of spacing materials. The plurality of first channels are configured to allow air flow in a first direction and to prevent airflow in a second direction that is different from the first direction. The plurality of second channels are configured to allow air flow in the second direction and to prevent airflow in the first direction. The humidifier comprises a stack of alternating first channels and second channels, and the first channels are configured to transfer liquid from air flowing in at least one of the first channels to air flowing in at least one of the second channels. The humidifier is suitable for use in fuel cell stack.

A polymer electrolyte fuel cell (PEFC), comprises a first electrode and a second electrode, wherein the first electrode includes a coaxial nanowire electrode. In some embodiments, the coaxial nanowire electrode comprises a plurality of ionomer nanowires, and a catalyst coating that coats at least part of the ionomer nanowires. Moreover, in some embodiments, a nanowire of the plurality of ionomer nanowires and a section of the catalyst coating that coats the nanowire form two coaxial cylinders.

A manufacturing device of a membrane-electrode assembly for a fuel cell is provided. The manufacturing device includes an electrolyte membrane feeding unit forming a first and second ionomer bases impregnated at both surfaces of a reinforcing layer and unwinding an electrolyte membrane wound in a roll type supplied in a predetermined transporting path. A first patterning unit is disposed at a rear side of the electrolyte membrane feeding unit and patterns a first ionomer protrusion pattern layer on the first ionomer base and a second patterning unit is disposed at the rear side of the first patterning unit and patterns a second ionomer protrusion pattern layer on the second ionomer base. A transfer unit is disposed at the rear side of the second patterning unit and couples a catalyst electrode layer on the first and second ionomer protrusion pattern layers by a roll laminating method.

A heat treatment apparatus of membrane electrode assemblies includes a base, a first member extending from the base in a first direction, and a plurality of second members formed on the base in a radially outward direction of the first member and having inner surfaces facing the first member, where the first member or the second members includes a heat wire member, and membrane electrode assemblies are disposed between the first member and the second members.

There is provided a technique of reducing the possibility of the occurrence of wrinkles in the process of bonding strip-shaped members to each other. A long strip-shaped first member is conveyed in a longitudinal direction of the first member. A width of a long strip-shaped second member in the shorter direction of the second member is larger than a width of the first member in a shorter direction of the first member. The second member is placed such that respective ends in a shorter direction of the second member are freed. The second member is bonded to the first member being conveyed, such that the shorter direction of the first member is aligned with the shorter direction of the second member and that respective ends in the shorter direction of the first member are placed between the respective ends in the shorter direction of the second member. The second member bonded to the first member is then conveyed along with the conveyed first member.