A method of manufacturing a lithium solid electrolyte, the method including: providing a composition including a lithium precursor, a lanthanum precursor, and a zirconium precursor; disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film; and heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.

A solid oxide electrochemical cell includes an oxygen electrode containing a strontium-containing perovskite-type composite oxide represented by Ln.sub.1-xSr.sub.xCo.sub.1-y-zFe.sub.yB.sub.zO.sub.3-δ (Ln is a trivalent lanthanide element, B is a tetravalent element, 0<x<1, 0≤y<1, 0<z<1, and 0<z+y<1, and δ is a value that is determined to satisfy charge neutrality conditions), a solid electrolyte containing zirconium oxide, a hydrogen electrode, and an interlayer containing a rare-earth-doped cerium oxide that is provided between the solid electrolyte and the oxygen electrode.

Provided is a low-cost electrochemical element that has excellent performance, reliability, and durability. Also, provided is a manufacturing method for an electrochemical element including a metal substrate (metal support) and an electrode layer formed on/over the metal substrate. The method includes an electrode layer forming step of forming an electrode layer having a region with a surface roughness of 1.0 μm or less on/over the metal substrate, and an electrolyte layer forming step of forming an electrolyte layer by spraying aerosolized metal oxide powder onto the electrode layer.

Forming a lithium lanthanum zirconate thin film includes disposing zirconium oxide on a substrate to yield a zirconium oxide coating, contacting the zirconium oxide coating with a solution including a lithium salt and a lanthanum salt, heating the substrate to yield a dried salt coating on the zirconium oxide coating, melting the dried salt coating to yield a molten salt mixture, reacting the molten salt mixture with the zirconium oxide coating to yield lithium lanthanum zirconate, and cooling the lithium lanthanum zirconate to yield a lithium lanthanum zirconate coating on the substrate. In some cases, the zirconium oxide coating is contacted with an aqueous molten salt mixture including a lithium salt and a lanthanum salt, the molten salt mixture is reacted with the zirconium oxide coating to yield lithium lanthanum zirconate, and the lithium lanthanum zirconate is cooled to yield a lithium lanthanum zirconate coating on the substrate.

A sintered composite ceramic, including: a lithium-garnet major phase; and a grain growth inhibitor minor phase, such that the grain growth inhibitor minor phase has a metal oxide in a range of 0.1 wt. % to 10 wt. % based on the total weight of the sintered composite ceramic.

A precursor structure is provided. The precursor structure has the following chemical formula: $\left({\mathrm{La}}_2{\mathrm{Zr}}_{2-x}{M}_x{O}_7\right).Math.\frac{1}{2}\left({\mathrm{La}}_{2-y}{M}_y^{\prime }{O}_3\right),$
wherein M is a trivalent ion or a pentavalent ion, M′ is a bivalent ion, x=0-1, y=0-1.5, and the precursor structure includes a pyrochlore phase. Since the pyrochlore phase may be transformed into the garnet phase through a lithiation process and the phase transition temperature is lower (e.g., 500-1000° C.), the precursor structure may be co-fired with the cathode material (e.g., lithium cobalt oxide (LiCoO.sub.2)) to form a thin lamination structure. That is, the thickness of the solid electrolyte may be effectively reduced, thereby improving the ionic conductivity of the solid electrolyte ion battery.

Provided is a complex oxide having high density and high lithium ion conductivity and low activation energy. The complex oxide has a chemical composition represented by Li.sub.4−xSr.sub.2−xLa.sub.xZrO.sub.6 (0≤x≤1.0) and belongs to a monoclinic space group P2.sub.1/n. The relative density of this complex oxide can be made to be 100%. The lithium ion conductivity of this complex oxide can be made to be 6.0×10.sup.−4 S/cm or more. This complex oxide is produced by melting at least a part of a raw material having a chemical composition represented by Li.sub.(4−x)ySr.sub.(2−x)zLa.sub.xZrO.sub.6 (0≤x≤1.0, 1<y and 1<z) to form a molten portion and moving the molten portion at a movement speed of 8 mm/h or faster.

A method for the combined production of electricity and nitric oxide,: comprising the steps of: providing an SOFC comprising an anodic side comprising a solid gas-permeable anode, a gas inlet and a gas outlet, a cathodic side comprising a solid gas-permeable cathode and a gas inlet and a gas outlet, and a fully dense solid electrolyte, separating the cathodic side from the anodic side; introducing an oxygen-containing gas in the inlet of the cathodic side of the SOFC; introducing an ammonia-containing gas stream in the inlet of the anodic side of the SOFC; collecting nitric oxide at the outlet of the anodic side and collecting a current flowing between the anodic side and the cathodic side.

Electrolyte for a solid-state battery includes a body having grains of inorganic material sintered to one another, where the grains include lithium. The body is thin, has little porosity by volume, and has high ionic conductivity.

The present invention relates to a method of preparation of a garnet-type inorganic material. It also relates to the garnet-type inorganic material itself. The process comprises the following steps: (1) bringing an aqueous solution S comprising (i) a salt of zirconium, (ii) a salt of lanthanum and (iii) a salt of the element A or a precursor of an oxide of element A into contact with an aqueous solution of a basic compound, as a result of which a precipitate suspended in the reaction medium is obtained; (2) stirring the reaction medium obtained at the end of step (1) for at least 30 min; (3) bringing the precipitate obtained at the end of step (2) into contact with an additive selected in the group consisting of: anionic surfactants; nonionic surfactants; polyethylene glycols; carboxylic acids and their salts; and surfactants of the carboxymethylated fatty alcohol ethoxylate type; (4) calcining in air the precipitate recovered at the end of the previous step at a temperature which is at least 400° C.; (5) bringing into contact the product obtained at the end of step (4) with a salt of lithium; (6) calcining in air the product obtained at the end of step (5) at a temperature between 700° C. and 1100° C.; 20 the inorganic compound M comprising or consisting essentially of a garnet oxide or garnet-type oxide containing, as constituent elements, the elements Li, La, Zr and at least one element A selected in the group consisting of Al, Ga, Nb, Fe, W, Ta, or a mixture thereof.